Method and device for intermittently removing heavy metals in wastewater

A heavy metal, intermittent technology, applied in chemical instruments and methods, water pollutants, water/sewage treatment, etc., can solve problems such as difficult solid-liquid separation, high equipment requirements, high price, etc., and achieve low operation and maintenance costs , The structure of the device is simple and the effect of easy industrial application

Inactive Publication Date: 2021-06-18
DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current existing methods have various deficiencies and areas to be improved. For example, the ion exchange resin method with the best effect is not only expensive for the resin, but also requires high equipment requirements, and the cost of construction and maintenance is also extremely high.
Some powdery adsorbents such as bentonite, due to their high suspensibility in water, are not easy to precipitate after the adsorption is completed, so solid-liquid separation has become a problem; most of the existing methods will have a solid-liquid separation step, and will There are fixed requirements for the materials used, such as the need for shaped adsorbents, certain mechanical strength, fixed particle size, etc.

Method used

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  • Method and device for intermittently removing heavy metals in wastewater

Examples

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Comparison scheme
Effect test

Embodiment 1

[0074] Add 40g of B-type silica gel (granular) into the adsorption tank 100, add 40L of aqueous solution with a copper ion concentration of 100mg / L to it, stir and adsorb for 1h, after the adsorption is completed, discharge the solid-liquid mixture to a plate and frame filter for solid-liquid separation , the hole diameter of the plate and frame porous metal support net used is 4-8mm, and the copper ion concentration of the filtrate is detected after filtration, and the concentration is 0.2mg / L, which reaches the emission standard (the emission standard is 0.5mg / L), and can be directly emission.

Embodiment 2

[0076] 40g of coconut shell charcoal powder (powder) is added in the adsorption tank 100, and 40L of cadmium ion concentration is added therein to be the aqueous solution of 100mg / L, stirring and adsorbing for 1h, after the adsorption finishes, the solid-liquid mixture is discharged to the plate-and-frame filter for solidification. Liquid-liquid separation, the hole diameter of the plate and frame porous metal support net used is 0.2-0.5mm, after filtering, the cadmium ion concentration of the filtrate is detected, the concentration is 0.3mg / L, which fails to meet the discharge standard (the discharge standard is 0.1mg / L ), the filtrate is sent back to the adsorption tank 100 with the return pump, and at the same time, 20g of coconut shell carbon powder is added again for adsorption again. After the second adsorption, the solid-liquid mixture is discharged to the plate and frame filter for solid-liquid separation. The used plate and frame The pore diameter of the porous metal s...

Embodiment 3

[0078] Add 40g of CH-97 ion exchange resin (granular) in the adsorption tank 100, add 40L of mercury ion concentration to it and be the aqueous solution of 100mg / L, stir and adsorb for 1h, after the adsorption finishes, the solid-liquid mixture is discharged to the plate and frame filter For solid-liquid separation, the pore size of the plate and frame porous metal support net used is 10-50 μm. After filtration, the mercury ion concentration of the filtrate is detected, and the concentration is 0.003mg / L, which meets the emission standard (the emission standard is 0.005mg / L), can be discharged directly.

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Abstract

The invention discloses a method and a device for intermittently removing heavy metals in wastewater. The method comprises the following steps: a) contacting heavy metal-containing wastewater with an adsorbent, and adsorbing to obtain a solid-liquid mixture; b) carrying out plate frame filtration on the solid-liquid mixture to realize solid-liquid separation to obtain filtrate and a filtering cake containing heavy metals; and c) monitoring the concentration of heavy metals in the filtrate, and directly discharging the filtrate if the concentration of the heavy metals in the filtrate meets a preset standard; and if the heavy metal concentration in the filtrate does not meet the preset standard, repeating the step a) until the heavy metal concentration in the filtrate meets the preset standard. According to the method, through the intermittent circulation process of adsorption, filtration, detection and discharge/readsorption, the universality of the adsorbent is perfectly solved by skillfully applying the plate-and-frame filtering, so that the method can be widely applied to the field of removal of heavy metals in industrial wastewater.

Description

technical field [0001] The application relates to a method and a device for intermittently removing heavy metals in wastewater, which belong to the technical field of wastewater treatment. Background technique [0002] In recent years, with the continuous development of my country's industry and economy, the discharge of heavy metal-containing wastewater in the production process has gradually increased, and heavy metal pollution has become one of the main pollution problems of my country's water pollution. Heavy metal pollutants cannot be biodegraded, and they are also highly toxic at low concentrations. Under the action of microorganisms, they will even be transformed into other more toxic valence states. Heavy metal wastewater will not only cause harm to aquatic plants and animals, but also have a bad impact on human health. [0003] Common treatment methods for wastewater containing heavy metals include biological methods, physical methods, physicochemical methods, and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F101/20
CPCC02F9/00C02F2101/20C02F1/001C02F1/281C02F1/283C02F1/286C02F1/42
Inventor 刘亚男刘广业徐云鹏刘中民
Owner DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI
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