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Reactive blue-to-black dye composition and dye product

A technology of black dyes and dye compounds, applied in the field of reactive blue to black dye compositions and dye products, which can solve the problems of high COD of dyeing residue, increased sewage treatment pressure, low dye utilization rate, etc., and achieve extremely high dyeing depth And fixation rate, reduce the amount of dye, excellent effect of color fastness

Pending Publication Date: 2022-03-15
ZHEJIANG KEYONG CHEM CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Conventional blue to black reactive dyes are widely used to compound C.I. reactive black 5 and various reactive oranges. Although the blackness has been improved to a certain extent, the amount of dye is more than 10%, and the utilization rate of dye is low, resulting in increased floating color. The fastness is poor and the COD of the dyeing residue is high, which can not meet the needs of printing and dyeing enterprises for extra dark black, but also increases the pressure of sewage treatment

Method used

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  • Reactive blue-to-black dye composition and dye product
  • Reactive blue-to-black dye composition and dye product
  • Reactive blue-to-black dye composition and dye product

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0132] Component A of 70 parts of formula (I-1) compound, component B of 20 parts of formula (II-1) compound, 5 parts of formula (III-1) and the component of 5 parts of formula (IV-26) compound C and 10 parts of sodium sulfate are mechanically mixed, and the obtained composite dye is dyed black by conventional exhaust dyeing method, and the color fastness to washing is above grade 4 (refer to GB / T 3921-2008), and the color fixation rate is above 75% ( Refer to GB / T2391-2014).

[0133]

[0134]

Embodiment 2

[0136]Component A of 65 parts of formula (I-1) compound, component B of 19 parts of formula (II-1) compound, 2 parts of formula (III-1) and the component of 5 parts of formula (IV-26) compound Component D of C, 9 parts of formula (Ⅴ-1) compound and 10 parts of sodium sulfate are mechanically mixed, and the composite dye obtained adopts the conventional exhaust dyeing method to dye cotton to be black, and the color fastness to washing reaches more than 4 grades (referring to GB / T 3921-2008), the color fixation rate is above 75% (refer to GB / T2391-2014).

[0137]

[0138]

Embodiment 3

[0140] 60 parts of component A of the compound of formula (I-1), 20 parts of component B of the compound of formula (II-1), 10 parts of component C of the compound of formula (III-1), 5 parts of component C of the compound of formula (V-1 ) and 5 parts of (Ⅵ-1) compound component D, and 10 parts of sodium bicarbonate are mechanically mixed, and the obtained composite dye is dyed black by conventional exhaust dyeing method, and the color fastness to washing is above grade 4 (refer to GB / T 3921-2008), the color fixation rate is above 75% (refer to GB / T2391-2014).

[0141]

[0142]

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Abstract

The invention discloses a reactive blue-to-black dye composition and a dye product. The reactive blue-to-black dye composition comprises a component A, a component B and a component C. The component A is selected from at least one of dye compounds shown in a formula (I) and alkali metal salts thereof, and the component B is selected from at least one of dye compounds shown in a formula (II) and alkali metal salts thereof. And the component C is selected from at least one of dye compounds as shown in formulas (III)-(IV) and alkali metal salts thereof. The invention provides a reactive blue to black dye product which comprises the reactive blue to black dye composition. Compared with conventional reactive black, the reactive blue-to-black dye product disclosed by the invention has the advantages that the strength is higher by 60% or above, the dye is extremely high in deep dyeing property and fixation rate, the use amount of the dye can be greatly reduced, various color fastnesses are excellent, particularly the washing fastness is outstanding, and the reactive blue-to-black dye product is suitable for printing and dyeing nitrogen-containing and / or hydroxyl-containing fiber materials and blended fabrics thereof.

Description

(1) Technical field [0001] The invention relates to a reactive dye composition and a dye product, in particular to a reactive blue to black dye composition and a dye product suitable for printing and dyeing nitrogen-containing and / or hydroxyl-containing fiber materials. (2) Background technology [0002] Blue to black is the most important color in reactive dyes, accounting for more than 50% of the total output of reactive dyes. Conventional blue to black reactive dyes are widely used to compound C.I. reactive black 5 and various reactive oranges. Although the blackness has been improved to a certain extent, the amount of dye is more than 10%, and the utilization rate of dye is low, resulting in increased floating color. The fastness is poor and the COD of the dyeing residue is high, which can not meet the needs of printing and dyeing enterprises for extra deep black, and also increases the pressure of sewage treatment. (3) Contents of the invention [0003] In order to s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09B67/22C09B67/24
CPCC09B67/0072C09B67/005
Inventor 阮存凡王小红陈浩兵何耀耀阮香芝宋瑜
Owner ZHEJIANG KEYONG CHEM CO LTD
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