Unlock instant, AI-driven research and patent intelligence for your innovation.

Method for detecting constant gram volume of carbon fluoride material

A detection method and gram-capacity technology, applied in the direction of material electrochemical variables, color/spectral characteristics measurement, etc., can solve the problems of failure to meet conventional tests, difficulty in fluorination test, expensive equipment, etc., easy to master and cheap instruments The effect of easy operation and process

Pending Publication Date: 2022-06-03
XIAMEN UNIV
View PDF0 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is difficult to test the degree of fluorination. The results of the oxygen bomb combustion method and the fluorine ion selective electrode are usually significantly lower; there are national standards for the determination of the fluorine content in graphite plates, but they are only applicable to the ppm level of fluorine content. The test cannot be applied to the determination of various constant-level fluorine content of fluorinated carbon materials; EDAX is not accurate for the analysis of low atomic number elements such as C and F; use 13 C and 19 F solid-state NMR spectrum analysis to determine the fluorine content of fluorocarbons, the equipment is expensive and cannot meet the routine testing

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for detecting constant gram volume of carbon fluoride material
  • Method for detecting constant gram volume of carbon fluoride material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] After the above four samples were sieved with a 600-mesh sieve, the samples were prepared in a pressing box, and the whiteness of the samples was tested with a powder colorimeter.

[0025] The test results are shown in Table 1 and figure 1 shown:

[0026] Table 1 Relationship between whiteness value and gram capacity of carbon fluoride samples

[0027] sample Whiteness value Gram capacity mAh / g A 6.9 775 B 8.8 792 C 11.5 821 D 19.8 869

Embodiment 2

[0029] After the above four samples were sieved with a 1000-mesh sieve, the samples were prepared in a pressing box, and the whiteness of the samples was tested with a powder colorimeter.

[0030] The test results are shown in Table 2 and figure 2 shown:

[0031] Table 2 Relationship between whiteness value and gram capacity of carbon fluoride samples

[0032] sample Whiteness value Gram capacity mAh / g A 6.7 775 B 8.9 792 C 11.4 821 D 19.9 869

[0033] It can be seen from the results of Example 1 above that there is a good linear relationship between the gram capacity of the carbon fluoride material and the whiteness value. The greater the whiteness value of the material, the greater the gram capacity of the material. This is because the gram capacity of fluorocarbon materials depends on the degree of fluorination of the material, and the color of the material is also related to the degree of fluorination. The higher the degree of f...

Embodiment 3

[0035] Take a sample to be tested, sieve it with a 600-mesh sieve, make a sample from the sieved powder in a sample pressing box, and test the whiteness of the sample with a powder colorimeter. According to the linear curve calculation, its specific capacity at a current density of 10 mA / g is 790 mAh / g.

[0036] The sieved powder sample was made into a button battery, and the specific capacity at a current density of 10 mA / g was 784 mAh / g, and the deviation from the specific capacity calculated by the whiteness value was 6 mAh / g.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a carbon fluoride material constant gram volume detection method, which comprises: (1) screening a carbon fluoride material through a 100-1000 mesh sieve, preparing a sample by using a sample pressing box, and testing the whiteness value of the sample by using a powder colorimeter; and (2) substituting the whiteness value obtained in the step (1) as x into y = kx + b of R2 = 0.98 to obtain a y value which is the constant-magnitude gram volume of the carbon fluoride material. According to the method, the constant gram volume of the carbon fluoride material is judged through the whiteness of the carbon fluoride material, the experiment steps are simple, the process is easy to control, an operator can easily master the process, the result is not easily influenced by human factors, the used instrument is cheap and easy to operate, the progress of material process development can be greatly improved, and the method is suitable for popularization and application. The method is especially suitable for optimizing the synthesis process of the carbon fluoride material in the initial research and development stage.

Description

technical field [0001] The invention belongs to the technical field of primary lithium batteries, and in particular relates to a method for detecting the constant-level gram capacity of carbon fluoride materials. Background technique [0002] Fluorocarbon material is an indispensable functional material in the world today, mainly used in metallurgy, chemical industry, military and other fields. The use of carbon fluoride material as the active material of the positive electrode of the battery can increase the storage life of the battery, and form a lithium-fluorine battery with high electric capacity, high output power and high energy density, and the discharge voltage can reach 3V. [0003] The gram capacity of carbon fluoride material is the most critical indicator of cathode materials, and the gram capacity of the detection material is very important for battery design. At present, the traditional detection method for the gram capacity of carbon fluoride materials mainly...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): G01N27/26G01N21/25
CPCG01N27/26G01N21/25Y02E60/10
Inventor 张忠如陈勋鑫闫俊美杨勇
Owner XIAMEN UNIV