Oxygen scavengers with reduced oxidation products for use in plastic films and beverage and food containers
A technology of oxygen scavenger and compound, applied in the field of rigid polymer food or beverage container, oxygen scavenger for plastic film, oxygen scavenging packaging material, and oxygen scavenging composition, can solve the problem of weakening the physical integrity of multilayer container structure , bad smell and/or taste, uncontrolled oxidative splitting of chain scission, etc.
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Embodiment 1
[0319] Preferred embodiments of the present invention include polymers and oligomers containing cyclohexene groups that are readily accessible to free oxygen molecules. These polymers or oligomers can be prepared from any of a number of methods, although a preferred reaction involves 1,2,3,6-tetrahydrophthalic anhydride. The anhydride is a low-cost monomer derived from butadiene, which makes it particularly attractive on an industrial scale. The anhydrides can be used to make polyester resins such as by reaction with diols. It can also react with hydroxyl or polyol compounds to produce half-esters suitable for subsequent use in the manufacture of plastic films and materials.
Embodiment 2
[0321] Non-aromatic alkenyl benzyl alcohols such as tetrahydrobenzyl alcohol can also react with certain compounds to produce useful scavengers. For example tetrahydrobenzyl alcohol can be reacted with compounds containing carboxylic acid, acid halide, ester, anhydride and / or isocyanate functional groups. These compounds can be small molecules or oligomers or polymers. For example, tetrahydrobenzyl alcohol can be reacted with styrene / maleic anhydride copolymers or with polyfunctional isocyanates.
Embodiment 3
[0323] Cyclohexene dimethanol compounds can be used to prepare oxygen-absorbing polyesters and polyurethanes.
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Abstract
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