Friction method
A rubbing roller and rubbing treatment technology, which is applied in nonlinear optics, instruments, optics, etc., can solve the problems of wrinkles, non-uniform contact between the film and the belt surface, and the inability to completely reduce friction unevenness, etc.
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[0033] The present invention will be specifically described below using examples, but the present invention is not limited by these examples.
[0034] Various analytical methods used in Reference Examples and Examples are as follows.
[0035] (1) Determination of logarithmic viscosity of liquid crystal polymer
[0036] Measurement was carried out at 30°C in a mixed solvent of phenol / tetrachloroethane (60 / 40 by weight) using an Ubbelode viscometer.
[0037] (2) Observation of uneven orientation and defects
[0038] Observation of uneven orientation was performed using a BH2 polarizing microscope manufactured by Olympus Optical Co., Ltd.
[0039] (3) Determination of liquid crystal polymer composition
[0040] Dissolve the liquid crystalline polyester in deuterated chloroform, using a 400MHz 1 H-NMR (JNM-GX400 manufactured by JEOL Ltd.) was measured to determine the composition.
reference example 1
[0042] Synthesize the liquid crystal polymer substance (logarithmic viscosity=0.22dl / g, Tg=61 ℃) of formula (1) and (R)-3-methylhexane-1,6-bis containing formula (2) Optically active liquid crystal polymer substance (logarithmic viscosity=0.17dl / g) of alcohol unit.
[0043] The synthesis of these polymer materials is carried out by reacting acid chlorides corresponding to dicarboxylic acid units with diol compounds in the presence of triethylamine in o-dichlorobenzene solvent.
[0044] The liquid crystalline polymer solution-1 was prepared by dissolving 18.1 g of the obtained liquid crystalline polymer of formula (1) and 1.9 g of the liquid crystalline polymer mixture of formula (2) in 80 g of N-methylpyrrolidone.
[0045] Formula 1)
[0046]
[0047] Formula (2)
[0048]
[0049] *Denotes optically active carbon
[0050] [Example]
[0051] Implemented on 60μm thick polyetheretherketone (PEEK) oriented substrate film figure 2 The friction treatment method shown. T...
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