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Water-disintegrable resin film laminated water-disintegrable resin film, water-disintegrable composite laminate and method for production thereof

A hydrolyzable resin, lamination film technology, applied in synthetic resin layered products, chemical instruments and methods, coatings, etc., can solve the problems of mechanical strength decline, failure to take into account, underwear fouling, etc.

Inactive Publication Date: 2004-10-13
SEKISUI CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] However, the above-mentioned laminated film and the above-mentioned disposable article do not take into account the situation that they are used under the conditions that deformation stress is often applied in the above-mentioned high-temperature and humid state, and the outer peripheral end surface of the bottom liner in the sanitary article liner is exposed to the outside. The state is in the state of being directly exposed to the above-mentioned high-temperature and humid environment. Therefore, when the above-mentioned laminated film and the above-mentioned disposable products are used as the backing of the sanitary product liner under high-temperature and humid conditions, the mechanical strength such as tensile strength will be significantly reduced. There is a problem of damage such as cracking due to deformation stress
[0009] In addition, when using the sanitary product liner, it can be worn on the underwear freely through the adhesive layer and peeled off from the underwear after use. The mechanical strength of the laminated film and the above-mentioned disposable products will be greatly reduced in a high-temperature and humid wearing environment
[0010] Therefore, when the sanitary product liner is peeled off from the underwear, the backing (the above-mentioned laminated film and the above-mentioned disposable product) cannot resist the adhesive force of the adhesive that integrates the backing and the underwear, and will be damaged in its thickness direction. If it breaks, a part of the backing will remain on the underwear, that is, so-called delamination will occur, and as a result, there is also a problem of staining the underwear due to the adhesive remaining on the underwear

Method used

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  • Water-disintegrable resin film laminated water-disintegrable resin film, water-disintegrable composite laminate and method for production thereof
  • Water-disintegrable resin film laminated water-disintegrable resin film, water-disintegrable composite laminate and method for production thereof
  • Water-disintegrable resin film laminated water-disintegrable resin film, water-disintegrable composite laminate and method for production thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~3

[0112] A given amount of alkylene oxide-modified polyvinyl alcohol (polyoxyethylene group content: about 23% by weight, degree of saponification: 99% by mole, degree of polymerization: 500), ethylene-vinyl alcohol copolymer (1 ) (ethylene content: 6 mol%, saponification degree: 99 mol%, polymerization degree: 500) and ethylene-vinyl alcohol copolymer (2) (ethylene content: 6 mol%, saponification degree: 99 mol%, polymerization degree: 1000 ) composed of polyvinyl alcohol resin and glycerin as a plasticizer were provided to the extruder, and extruded from the T die after being melted and mixed to obtain a hydrolyzable resin film with a thickness of 20 μm.

[0113] Then, a toluene-methanol mixed solution of ethyl cellulose (trade name "N-100" manufactured by Ha-Kyures Co., Ltd.) was coated on the entire surface of the above-mentioned hydrolyzable resin film by the gravure coating method, and the integrated thickness was laminated. A hydrolyzable resin laminated film was obtained...

Embodiment 4

[0115] A hydrolyzable resin laminated film was obtained in the same manner as in Example 3 except that the thickness of the hydrolyzable resin film was changed to 30 μm.

Embodiment 5

[0117] In addition to coating one side of the hydrolyzable resin film with an ester-type thermoplastic polyurethane resin (trade name "Pandex T-5205" manufactured by Dainippon Ink Chemical Co., Ltd.) instead of ethyl cellulose, a waterproof film with a thickness of 5 μm is laminated and integrated. Except for the layer, a hydrolyzable resin laminated film was obtained in the same manner as in Example 1.

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Abstract

A water-disintegrable resin film, characterized in that it exhibits a tensile strength of 2 N / 25 mm width or more after the surface thereof is pressed by a cotton gauze impregnated with water of 40 DEG C. with a pressure of 1.47 N / cm<2 >for 5 hours under a condition wherein the temperature is 40 DEG C. and the relative humidity is 90%, and exhibits a start time for the disintegration thereof by water, which means the time needed until it starts to lose its form, of 600 seconds or less, in a test nearly according to JIS P 4501 for the capability of being united. The water-disintegrable resin film has a predetermined mechanical strength under a wet and warm or hot condition and also exhibits excellent disintegradability for a large amount of water, and thus can be suitably used as a back sheet of a liner for sanitary goods, which requires the combination of good water resistance and good water-disintegradability.

Description

technical field [0001] The present invention relates to a hydrolyzable resin film, a hydrolyzable resin laminated film, and a hydrolyzable resin film suitable for use as a back sheet of sanitary product liners such as physiological liners, fabric liners, and incontinence liners. Composite laminate and method of making the same. Background technique [0002] At present, liners for sanitary products are being widely used. Generally speaking, the liner for sanitary products is made by superimposing a liquid-permeable top sheet and a liquid-impermeable backing, and making the opposing peripheral parts It is integrally formed, and a liquid absorber is stored between the upper cover sheet and the opposite inner side of the above-mentioned base liner. In addition, there is formed on the outer surface of the above-mentioned base liner for fixing the sanitary product liner to the underwear freely. Adhesive layer. [0003] The above sanitary product liners will be discarded after us...

Claims

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Application Information

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IPC IPC(8): A61F5/44A61F5/445A61F13/15B32B9/02B32B9/04B32B27/08B32B27/30C08J5/18C08J7/04
CPCB32B27/08C08J2329/04B32B9/04A61F13/15211C08J5/18B32B9/02Y10T428/3158
Inventor 中川弘章佐藤和博重光贵裕深谷三治贯洞慎一桥本阳世
Owner SEKISUI CHEM CO LTD
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