Method of producing powdered styrene-butadiene carbon black masterbatch
A technology of powdered styrene-butadiene carbon black and its production method, which is applied in the field of masterbatch preparation, can solve the problems of high energy consumption, achieve narrow distribution, reduce the process of adding polymer coating agents or other release agents, and achieve good results. The effect of stability
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example 1
[0031] 1) Surface modification and dispersion of carbon black
[0032] Add carbon black, desalinated water accounting for 50% of the total water, emulsifying dispersant, and surface modifier in sequence in proportion, and heat up to 80-90°C. During the stirring process, slowly add potassium hydroxide solution (dissolve hydrogen with 50% desalinated water) Potassium oxide obtains), after adding potassium hydroxide solution, continue to stir for 30 minutes.
[0033] Component ratio: 400 parts of desalted water, 100 parts of carbon black (N330), 8 parts of surface modifier {isopropyl-tri(ethoxy)silane}, 4 parts of emulsifying dispersant (fatty acid), 1 part of potassium hydroxide share.
[0034] The resulting carbon black dispersion: dry matter 21%, pH 9.8, stability (floating / sedimentation after standing for 24 hours) 0.6%.
[0035] 2) Mixing of carbon black dispersion-rubber emulsion / solution and separation of blends
[0036] Mix the rubber emulsion, carbon black dispersion ...
example 2
[0041] During the dispersion process of carbon black, change N330 to N110, and other formulations and conditions are as in Example 1. The carbon black dispersion is mixed with the styrene-butadiene mortar for coagulation and drying, and the performance of the obtained powdered styrene-butadiene carbon black masterbatch product is still within the control range.
example 3
[0043] The fatty acid in example 1 is changed into abietic acid, and other conditions are unchanged and carry out emulsification dispersion, can obtain the carbon black dispersion liquid that satisfies the requirement equally: dry matter is 20%, pH value 10.1, stability (after leaving standstill 24 hours, floating / sedimentation) 0.5%. The carbon black dispersion is mixed with the styrene-butadiene mortar, and coagulated and dried, and the index of the obtained product still meets the requirements.
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Abstract
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