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Method of drying biodegradable polymers

A technology for degrading polymers and polymers, applied in the direction of drying solid materials, solid waste removal, heating to dry solid materials, etc., can solve problems such as molecular weight reduction

Inactive Publication Date: 2005-07-20
BIOMATERA INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Polyesters are very sensitive to hydrolysis when they are thermoformed, resulting in a reduction in their molecular weight

Method used

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  • Method of drying biodegradable polymers
  • Method of drying biodegradable polymers
  • Method of drying biodegradable polymers

Examples

Experimental program
Comparison scheme
Effect test

Embodiment I

[0062] Biomass was dried using a low microwave power level (10%)

[0063] According to our protocol, biomass containing PHBV (93% hydroxybutyrate-7% hydroxyvalerate) was prepared in the laboratory. During drying, a Sylvania microwave oven (SM81004, 1 cubic foot volume, 1600W power consumption and 1100W maximum microwave power) was used. 82.2 g of biomass were placed in a microwave oven, dried at 10% power level for a short time (2 minutes), then removed from the microwave, mixed and weighed. Repeat these steps until a constant sample weight is obtained. Short-term microwave exposure is required to avoid spillage of the solution. The biomass was mixed after each short-term microwave irradiation, thereby obtaining a uniform drying of the samples. Under these microwave conditions, 52 minutes were required to dry 82.2 g of biomass containing 46.5% w / w water (Figure 1).

Embodiment II

[0065] Dry PHBV emulsions with a low microwave power level (10%)

[0066] During drying, an emulsion containing PHBV (93% hydroxybutyrate-7% hydroxyvalerate) was used. The emulsion contained 15% w / w PHBV in water.

[0067] During drying, a Sylvania microwave oven (SM81004, 1 cubic foot volume, 1600W power consumption and 1100W maximum microwave power) was used. 18.49 g of the PHBV emulsion were placed in a microwave oven, dried at 10% power level for a short time (2 minutes), then removed from the microwave, mixed and weighed. Repeat these steps until a constant sample weight is obtained.

[0068] Short-term microwave exposure is required to avoid spillage of the solution. The biomass was mixed after each short-term microwave irradiation, thereby obtaining a uniform drying of the samples. To confirm the effect of microwave power level on the efficiency of the drying process, samples were subjected to microwave irradiation for 2 minutes at the maximum microwave power level....

Embodiment III

[0071] Dry PHBV emulsion with high microwave power level (50%)

[0072]In the drying process, an emulsion containing PHBV (93% hydroxybutyrate-7% hydroxyvalerate) was used. The emulsion contained 15% w / w PHBV in water.

[0073] During drying, a Sylvania microwave oven (SM81004, 1 cubic foot volume, 1600W power consumption and 1100W maximum microwave power) was used. 23.09 g of the PHBV emulsion were placed in a microwave oven, dried at 50% power level for a short time (30 seconds to 2 minutes), then removed from the microwave, mixed and weighed. If the microwave drying process is performed at a power level higher than 10%, it is necessary to reduce the microwave irradiation time (minutes to seconds) to avoid overflow of the solution. Repeat these steps until a constant sample weight is obtained. The biomass was mixed after each short-term microwave irradiation, thereby obtaining a uniform drying of the samples. Under these microwave conditions, it took 40 minutes to dry th...

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Abstract

The present invention relates to a process for reducing the solvent content from a biodegradable polymer in a composition or a preparation. The process comprises drying the biopolymer composition by submitting it to microwaves for a time to achieve removal of the solvent at desired levels.

Description

technical field [0001] The present invention relates to a method of drying or concentration of solutions. In particular, the present invention relates to a method of drying polar solutions of biodegradable polymers or biomass, and a method of concentrating polar solutions comprising biodegradable polymers or biomass. Background of the invention [0002] Biodegradable polymers such as polyhydroxyalkanoates (PHAs) have received much attention and have become an interesting new source of commodity polymers. Until recently, the focus has been on the production of PHAs because their physical properties are similar to those of polymers derived from petrochemical sources (polyethylene, polypropylene), but unlike petrochemical-based polymers, PHAs are biocompatible and biodegradable. The worldwide potential market for biodegradable and biocompatible polymers is enormous. Polyhydroxyalkanoate (PHA) is a chemical term for a specific class of polyester family. PHAs are biopolymers ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12P7/62B09B3/00C08B3/22C08B5/04C08B11/20C08B30/06C08B30/08C08G63/06C08G63/08C08G63/88C08G63/90F26B3/34F26B3/347
CPCC08G63/90C08G63/06C08B30/08C08B30/06C08B3/22C08B11/20F26B3/347C08G63/08C08B5/04
Inventor 萨班·布瓦伊朱莉·戈代马尔科·布卢安劳伦特·马萨罗帕特里克·拉普安特
Owner BIOMATERA INC