By providing a polyol-based component and an isocyanate-based component, along with one or more flame retardant and/or smoke suppressant additives, in a reactive, injection molding process, rigid, polyurethane, foam products are achieved which are capable of exceeding all applicable standards for flame retardancy, while also comprising a density ranging between about 2 lbs. per cubic foot and 50 lbs. per cubic foot. In achieving a desired rigid polyurethane products of the present invention, the flame retardant and/or smoke suppressant additives may comprise one or more selected from the group consisting of organic additives, inorganic additives, halogenated additives, and non-halogenated additives. Furthermore, in the preferred embodiment, the three-dimensional rigid, polyurethane, foam products of the present invention comprises a thickness ranging between about 0.1 inches and 6 inches, a width ranging between about 0.1 inches and 96 inches, and an overall length ranging between about 0.1 inches and 288 inches.