SAPO molecular sieve catalyst for chloromethane conversion to produce low carbon olefin
A technology of low-carbon olefins and catalysts, applied in the application field of the above-mentioned catalysts
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Embodiment 1
[0011] Carry out the conversion reaction of methyl chloride on the fixed-bed reactor, take the SAPO-34 molecular sieve that silicon content is 10.3wt% as catalyst, reaction conditions: temperature 450 ℃, feed space velocity of methyl chloride 3.2, adopt online gas chromatography to complete product distribution According to the analysis, the conversion rate of methyl chloride is 85%, the selectivity of ethylene in the reaction product is 41.5%, the selectivity of propylene is 29.0%, and the selectivity of butene is 9.1%.
Embodiment 2
[0013] Carry out the conversion reaction of methyl chloride on the fixed-bed reactor, be the SAPO-34 of 6.6wt% with silicon content as catalyzer, reaction condition is the same as embodiment 1, adopt online gas chromatography to complete product distribution analysis, the conversion rate of methyl chloride 50.4% , The selectivity of ethylene in the reaction product is 39.5%, the selectivity of propylene is 30.6%, and the selectivity of butene is 11.0%.
Embodiment 3
[0015] Carry out the conversion reaction of methyl chloride on the fixed-bed reactor, be 8.5wt% SAPO-34 with silicon content as catalyst, reaction condition is the same as embodiment 1, adopt online gas chromatography to complete product distribution analysis, the conversion rate of methyl chloride is 77.8% , The selectivity of ethylene in the reaction product is 40.9%, the selectivity of propylene is 29.5%, and the selectivity of butene is 11.8%.
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