Method of preparing an anisotropic polymer film on a substrate with a structured surface

a polymer film and structured surface technology, applied in the field of preparing anisotropic polymer films on structured surfaces, can solve the problems of increasing costs, increasing methods of the prior art, and difficulty in forming patterned films comprising regions of different orientation

Inactive Publication Date: 2003-10-09
MERCK PATENT GMBH
View PDF15 Cites 92 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the methods of the prior art have several drawbacks.
The use of alignment layers or additives in the liquid crystal material leads to increased costs.
The formation of patterned films comprising regions of different orientation is difficult with these methods.
Rubbing of a substrate also implies several drawbacks when used in mass production of liquid crystal polymer films.
Whereas rubbing and thus alignment of the liquid crystal molecules can easily be achieved by conveying the substrate over a rubbing r...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method of preparing an anisotropic polymer film on a substrate with a structured surface
  • Method of preparing an anisotropic polymer film on a substrate with a structured surface
  • Method of preparing an anisotropic polymer film on a substrate with a structured surface

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0086]

1 The following polymerisable mixture is formulated Toluene 70.0% compound A 6.9% compound B 3.6% compound C 9.1% compound D 8.5% Fluorad FC-171 .RTM. 0.1% Irgacure 907 .RTM. 1.8% (A) 4 (B) 5 (C) 6 (D) 7

[0087] Compound (A) and its preparation are described in GB 2,280,445. Compounds (B), (C) and (D) can be prepared according to or in analogy to the methods described in D. J. Broer et al., Makromol. Chem. 190, 3201-3215 (1989). Irgacure 907 is a commercially available photoinitiator (Ciba Geigy). Fluorad FC 171 is a commercially available surfactant (3M).

[0088] This solution is coated on to an embossed film, where the embossing is in a single direction, using for example a wire wound bar to give a 6 micron wet film. This coating is then dried at 60.degree. C. for one minute and cured by exposing to the light from a medium pressure mercury lamp for one minute. When viewed through a linear polariser against a reflective background a dark blue colour is seen.

example 2

[0089] The solution of Example 1 is coated on to an embossed film where the embossing is in domains having differing directions using a wire wound bar to give a 6 micron wet film. This coating is then dried at 60.degree. C. for one minute and cured by exposure to the light from a medium pressure mercury lamp for one minute. When viewed through a rotating linear polariser against a reflective background a dark blue colour is seen only in regions having the appropriate alignment.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
Fractionaaaaaaaaaa
Fractionaaaaaaaaaa
Fractionaaaaaaaaaa
Login to view more

Abstract

An anisotropic polymer film with improved alignmentis prepared by coating onto a substrate with a structured surface. The polymer films thereby obtained are useful in optical and electrooptical devices for decorative and security applications.

Description

[0001] The invention relates to a method of preparing an anisotropic polymer film with improved alignment on a substrate with a structured surface, to polymer films thereby obtained and their use in optical and electrooptical devices, and for decorative and security applications.BACKGROUND AND PRIOR ART[0002] Anisotropic polymer films comprising a polymerized liquid crystal material with uniform orientation are known in prior art. They are usually prepared by coating a thin layer of a polymerizable liquid crystal mixture onto a substrate, aligning the mixture into uniform orientation and polymerizing the mixture.[0003] For specific applications it is required to induce planar alignment in the liquid crystal layer, i.e., where the liquid crystal molecules are oriented substantially parallel to the layer. The alignment is then frozen in by polymerizing the liquid crystal mixture in situ. For example, oriented films or layers of polymerized nematic liquid crystal material with planar a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): B29C41/08B29K105/14B29L7/00C08F2/00G02B5/30G02F1/13363
CPCB42D2033/26B42D2035/24B44F1/10G02B5/3016G02F1/13363Y10T428/1041B42D25/29Y10T428/1036Y10T428/10Y10T428/1005Y10S428/916C09K2323/03C09K2323/02C09K2323/031C09K2323/00B42D25/364B42D25/425
Inventor KUNTZ, MATTHIASPATRICK, JOHNGREGORY, GUYBLEASDALE, TONYRIDDLE, RODNEYHAMMOND-SMITH, ROBERTHOWARTH, PETERMARSHALL, ALLAN
Owner MERCK PATENT GMBH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products