Liquid gelling agent concentrates and methods of treating wells therewith

a concentrate and concentrate technology, applied in the direction of fluid removal, chemistry apparatus and processes, borehole/well accessories, etc., can solve the problems of unfavorable agglomeration of gelling agent in the polymer, fish eyes, feeders and adductors often fail to prevent the formation of fish eyes, etc., to improve storage, pour ability and settle properties

Inactive Publication Date: 2005-04-28
HALLIBURTON ENERGY SERVICES INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0009] The present invention provides storable liquid gelling agent concentrates that have improved storage, pour abilities and settling properties and methods of treating wells using the concentrates. A liquid gelling agent concentrate of this invention basically comprises an environmentally safe hydrocarbon carrier liquid, an organophillic clay suspending agent, a surfactant for dispersing the organophillic clay suspending agent in the hydrocarbon carrier liquid, and a particulate aqueous fluid gelling agent suspended in the carrier liquid.

Problems solved by technology

This procedure has very often resulted in undesirable agglomerations of the gelling agent in the polymer which are called “fish eyes.” Fish eyes are polymer masses wetted on the outside but with dry, unhydrated material inside.
While mechanical gelling agent feeders and adductors have been utilized to more efficiently wet the gelling agent, the feeders and adductors often fail to prevent the formation of fish eyes.
A problem with the liquid gelling agent concentrates utilized heretofore which include a hydrocarbon carrier fluid such as diesel oil is that the hydrocarbon carrier fluid contains compounds such as benzene, ethylbenzene, toluene, xylene and / or other compounds which are prohibited by the Environmental Protection Agency primary drinking water standards, i.e, Section 1429 of the Safe Drinking Water Act.
Another problem with such gelling agent concentrates is that they can not be stored for long periods of time and they often do not have good pour abilities or non-settling properties.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0029] A liquid gelling agent concentrate of this invention (referred to herein as “Inventive Concentrate”) was prepared in the laboratory comprising 43% by weight of diesel oil, 1% by weight of a quaternary ammonium bentonite clay suspending agent, 1% by weight of an ethoxylated alcohol surfactant for dispersing the suspending agent, and a 55% by weight of a guar particulate gelling agent.

[0030] A prior art gelling agent concentrate (referred to herein as “Concentrate A”) published by Union Carbide Corporation was also prepared comprising 53.83% by weight diesel oil, 1.39% by weight organophillic clay, 0.28% by weight methanol, 42.5% by weight hydroxyethylcellulose and 2.0% nonylphenol surfactant.

[0031] Each of the above described liquid gelling agent concentrates was placed in an 80° F. water bath and after time intervals of 24 hours, 48 hours, 72 hours and 168 hours, the percent of free liquid separation and the settling of solids in the concentrates were observed.

[0032] The r...

example 2

[0035] Samples of the Inventive Concentrate and Concentrate A described in Example 1 as well as two other prior art concentrates designated “Concentrate B” and “Concentrate C” were tested for viscosity using a Brookfield viscometer equipped with a number 3 spindle at 20 rpm and at a temperature of 80° F.

[0036] Concentrate B was prepared comprising 49% by weight of diesel oil, 5% by weight of an aqueous emulsion of a suspending agent comprising water insoluble polymer particles that swell when contacted with diesel oil and 46% by weight of polysaccharide water soluble gelling agent. This concentrate is described in detail in U.S. Pat. No. 4,772,646 issued to Harms, et al. on Sep. 20, 1988 which is incorporated herein by reference thereto.

[0037] Concentrate C published by Hercules, Inc. was prepared comprising 37% by weight of hydroxyethylcellulose, 40.1% by weight of an ethyl hexanol premix containing 1% hydroxypropylcellulose, 21.1% by weight of mineral oil and 1.8% by weight of a...

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Abstract

The present invention provides liquid gelling agent concentrates and methods of treating wells therewith. A liquid gelling agent concentrate of this invention comprises an environmentally safe hydrocarbon carrier liquid, an organophillic clay suspending agent, a surfactant for dispersing the organophillic clay suspending agent in the carrier liquid and a particulate aqueous fluid gelling agent suspended in the carrier liquid.

Description

BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention [0002] The present invention relates to liquid gelling agent concentrates and methods of treating wells using the concentrates. [0003] 2. Description of the Prior Art [0004] Viscous gelled aqueous treating fluids are used in a variety of treatments in oil and gas wells including well completions and production stimulation treatments. An example of a well completion treatment which utilizes a viscous gelled aqueous fluid is known in the art as gravel packing. In gravel packing treatments, solid gravel particles such as sand are carried by way of the well bore to a subterranean zone in which a gravel pack is to be placed by a viscous gelled aqueous carrier fluid. That is, particulate solids (referred to in the art as gravel) are suspended in the viscous gelled aqueous carrier fluid at the surface and are carried to the subterranean zone in which the gravel pack is to be placed. Once the gravel is placed in the zone, the visc...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C09K8/64E21B43/04E21B43/26
CPCC09K8/64
Inventor MCCABE, MICHAEL A.SLABAUGH, BILLYBLAUCH, MATTHEW
Owner HALLIBURTON ENERGY SERVICES INC
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