Treatment of mainstream smoke constituents by use of oxygen storage and donor metal oxide oxidation catalyst

a technology of oxygen storage and metal oxide oxidation, which is applied in the direction of physical/chemical process catalysts, tobacco, separation processes, etc., can solve problems such as flare ups, achieve the effects of enhancing the activity of oxygen donor materials, reducing sidestream smoke, and reducing toxic constituents in mainstream smok

Inactive Publication Date: 2005-06-09
ROTHMANS BENSON & HEDGES INC CA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0010] The same benefit is also achievable with the compositions and cigarette structures defined in Applicant's International Patent Applications: WO 02 / 24006 and WO 03 / 077687. This treatment of mainstream smoke may also be carried out with the reduction of sidestream smoke. Quite surprisingly, the use of the treatment composition in the paper, with or without sidestream smoke control, is capable of treating and reducing toxic constituents in the mainstream smoke.
[0011] To further enhance the activity of the oxygen donor material in the treatment composition, precious metals may also be used with the smoke treatment materials to enhance this action particularly when the treatment material is used in the paper or wrapper.
[0016] In another aspect of the present invention, the method for reducing at least one constituent of mainstream smoke emitted from a burning cigarette, the method comprising a step of using a treatment composition for cigarette tobacco and / or a cigarette filter, the treatment composition comprising, in combination, an oxygen storage and donor metal oxide oxidation catalyst, an essentially non-combustible finely divided porous particulate adjunct, and a precious metal.
[0019] In another aspect of the present invention, the use of a treatment composition in the manufacture of a cigarette paper / wrapper for a cigarette to reduce at least one constituent from a group of carbonyls and at least one constituent from a group of phenols of mainstream smoke from a burning cigarette, the treatment composition comprising, in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct.

Problems solved by technology

When using a very active oxygen donor oxidation catalyst, such as cerium oxide, flare ups can be a problem when puffing on the cigarette and on lighting the cigarette.

Method used

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  • Treatment of mainstream smoke constituents by use of oxygen storage and donor metal oxide oxidation catalyst

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0097] This example is directed to analysis of carbon monoxide in mainstream smoke with respect to a cigarette sample control (100) in comparison to a cigarette sample (101) with treatment composition incorporated into the cigarette paper / wrapper.

[0098] In carrying out the above analysis, sidestream smoke production was also analysed. The amount of sidestream smoke was quantified visually on a scale of 0 to 8, 0 being no sidestream smoke and 8 being sidestream smoke as generated by a conventional cigarette. Considerable experimentation in this area has revealed that there is an essentially linear relationship between sidestream smoke visual reading and the amount of tar remaining in the sidestream. Generally, when it comes to sidestream smoke control, a visual reading of about 2 or less is preferred. Although it is understood that there may be circumstances where a visual reading greater than 2 may be justified, for example, where the mainstream smoke reduction is the primary focus...

example 2

[0100] This example is directed to analysis of the groups of carbonyl and phenol analytes in mainstream smoke with respect to a cigarette sample control (100) of Example 1 in comparison to a cigarette sample (101) of Example 1 with treatment composition incorporated into the cigarette paper / wrapper.

TABLE 2100 (Control)101Analyte(μg per cigarette)(μg per cigarette)Group of Carbonyl AnalytesFormaldehyde24.767.65Acetaldehyde292.96146.75Acetone129.7570.70Acrolein29.709.02Propionaldehyde23.4111.60Crotonaldehyde23.587.74MEK29.0811.13Butyraldehyde12.547.72Total Carbonyls565.79272.30Tar5.73.6Group of Phenol AnalytesHydroquinone44.0227.82Resorcinol3.150.82Catechol57.3029.52Phenol12.533.85o-Cresol3.401.17m + p-Cresol5.051.92Total Phenols125.4565.09Tar5.73.6

[0101] The above results show that the treatment composition in the cigarette paper / wrapper substantially resuces selected Hoffman analytes in the mainstream smoke. Although the mechanism for the treatment of carbon monoxide in mainstream...

example 3

[0102] This example is directed to analysis of carbon monoxide and the groups of carbonyl and phenol analytes in mainstream smoke with respect to a cigarette sample control (100) in comparison to a cigarette sample (102) with treatment composition coated on the tobacco and a cigarette sample (103) having tobacco incorporated with the treatment composition (e.g. treatment composition intermixed with the tobacco).

[0103] In carrying out the above analysis, sidestream smoke production was also analysed in the same manner as outlined in Example 1.

TABLE 3Mainstream Smoke ConstituentsCarbon100 (Control)102103Monoxide(mg per cigarette)(mg per cigarette)(mg per cigarette)Tar5.74.34.5Nicotine0.670.550.62Carbon4.94.94.9MonoxideGroup of Carbonyl Analytes100 (Control)102103Analyte(μg per cigarette)(μg per cigarette)(μg per cigarette)Formaldehyde24.7623.7518.34Acetaldehyde292.96277.71241.32Acetone129.75112.12130.71Acrolein29.7029.7535.12Propion-23.4120.9421.90aldehydeCrotonaldehyde23.5823.8120...

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Abstract

The use of a treatment composition for a cigarette to reduce at least one constituent of mainstream smoke from a burning cigarette, the treatment composition comprising, in combination, an oxygen storage and donor metal oxide oxidation catalyst and an essentially non-combustible finely divided porous particulate adjunct.

Description

RELATED INVENTION [0001] This application claims benefit under 37 C.F.R. Section 1.78 of provisional application Ser. No. 60 / 502,665 filed Sep. 15, 2003. The full disclosure of the application is incorporated herein by reference.FIELD OF THE INVENTION [0002] This invention relates to the use of an oxygen storage and donor metal oxide oxidation catalyst to treat at least one constituent in mainstream smoke and more particularly, to reduce the amount of at least one constituent in the mainstream smoke. BACKGROUND OF THE INVENTION [0003] Work has been conducted to reduce sidestream smoke emissions from a burning cigarette. Oxygen storage and donor metal oxide oxidation catalysts have been used for reduction of sidestream smoke as described in various cigarette configurations of Applicant's published International Patent Applications: WO 98 / 16125 (U.S. Pat. No. 6,371,127); WO 99 / 53778 (U.S. Pat. No. 6,286,516); WO 02 / 24005 (U.S. patent application Ser. No. 09 / 954,432); WO 02 / 24006 (U.S....

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A24B15/28A24D1/02A24F1/20B01D53/86B01J23/63B01J29/06B01J29/08B01J29/12B01J37/00B01J37/02D21H21/14
CPCA24B15/28D21H21/14A24B15/286A24B15/287A24B15/288A24D1/02B01D53/8634B01D53/8668B01J23/63B01J29/06B01J29/088B01J29/126B01J37/0045B01J37/0221B01J2229/18B01J2229/20B01J2229/42A24B15/282
Inventor FINLAY, WARRENSNAIDR, STANISLAV M.AYRES, GEORGECHAPMAN, STEVE G.KACZMAREK, PETER P.BECKER, E. ROBERTHUNSICKER, ROBERT A.
Owner ROTHMANS BENSON & HEDGES INC CA
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