Treatment of mainstream smoke constituents by use of oxygen storage and donor metal oxide oxidation catalyst
a technology of oxygen storage and metal oxide oxidation, which is applied in the direction of physical/chemical process catalysts, tobacco, separation processes, etc., can solve problems such as flare ups, achieve the effects of enhancing the activity of oxygen donor materials, reducing sidestream smoke, and reducing toxic constituents in mainstream smok
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example 1
[0097] This example is directed to analysis of carbon monoxide in mainstream smoke with respect to a cigarette sample control (100) in comparison to a cigarette sample (101) with treatment composition incorporated into the cigarette paper / wrapper.
[0098] In carrying out the above analysis, sidestream smoke production was also analysed. The amount of sidestream smoke was quantified visually on a scale of 0 to 8, 0 being no sidestream smoke and 8 being sidestream smoke as generated by a conventional cigarette. Considerable experimentation in this area has revealed that there is an essentially linear relationship between sidestream smoke visual reading and the amount of tar remaining in the sidestream. Generally, when it comes to sidestream smoke control, a visual reading of about 2 or less is preferred. Although it is understood that there may be circumstances where a visual reading greater than 2 may be justified, for example, where the mainstream smoke reduction is the primary focus...
example 2
[0100] This example is directed to analysis of the groups of carbonyl and phenol analytes in mainstream smoke with respect to a cigarette sample control (100) of Example 1 in comparison to a cigarette sample (101) of Example 1 with treatment composition incorporated into the cigarette paper / wrapper.
TABLE 2100 (Control)101Analyte(μg per cigarette)(μg per cigarette)Group of Carbonyl AnalytesFormaldehyde24.767.65Acetaldehyde292.96146.75Acetone129.7570.70Acrolein29.709.02Propionaldehyde23.4111.60Crotonaldehyde23.587.74MEK29.0811.13Butyraldehyde12.547.72Total Carbonyls565.79272.30Tar5.73.6Group of Phenol AnalytesHydroquinone44.0227.82Resorcinol3.150.82Catechol57.3029.52Phenol12.533.85o-Cresol3.401.17m + p-Cresol5.051.92Total Phenols125.4565.09Tar5.73.6
[0101] The above results show that the treatment composition in the cigarette paper / wrapper substantially resuces selected Hoffman analytes in the mainstream smoke. Although the mechanism for the treatment of carbon monoxide in mainstream...
example 3
[0102] This example is directed to analysis of carbon monoxide and the groups of carbonyl and phenol analytes in mainstream smoke with respect to a cigarette sample control (100) in comparison to a cigarette sample (102) with treatment composition coated on the tobacco and a cigarette sample (103) having tobacco incorporated with the treatment composition (e.g. treatment composition intermixed with the tobacco).
[0103] In carrying out the above analysis, sidestream smoke production was also analysed in the same manner as outlined in Example 1.
TABLE 3Mainstream Smoke ConstituentsCarbon100 (Control)102103Monoxide(mg per cigarette)(mg per cigarette)(mg per cigarette)Tar5.74.34.5Nicotine0.670.550.62Carbon4.94.94.9MonoxideGroup of Carbonyl Analytes100 (Control)102103Analyte(μg per cigarette)(μg per cigarette)(μg per cigarette)Formaldehyde24.7623.7518.34Acetaldehyde292.96277.71241.32Acetone129.75112.12130.71Acrolein29.7029.7535.12Propion-23.4120.9421.90aldehydeCrotonaldehyde23.5823.8120...
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