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Ozone producing system

a technology of ozone producing system and ozone production, which is applied in the direction of electrolysis components, electrolysis processes, cells, etc., can solve the problems of reducing the current efficiency of ozone production or shortening the life of various structural members of the system, large size of the ozone producing system, and high temperature, so as to achieve high current efficiency and high efficiency. , the effect of high efficiency

Inactive Publication Date: 2008-03-13
CHLORINE ENGINEERS CORP LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Benefits of technology

[0009] Then, the subject of the present invention to solve said problems is to provide an ozone producing system to generate ozone gas by water electrolysis wherein the shape of the electrolytic cells is discussed to enlarge electrolytic area through effective utilization of the volume shared by electrolytic cell for ozone production, so that ozone can be obtained at a high current efficiency under a small current density operation and lives of various structural members of the electrolytic cell for ozone production are prolonged; ozone is produced at a high efficiency in an economical space area; and ozone gas is generated at a high efficiency through uniform temperature within the electrolytic cell; and lives of various structural members of the electrolytic cell for ozone production are prolonged.

Problems solved by technology

The system described in JP 9-095791 A, however, has a weak point in that the size of the ozone producing system becomes large because the round shape of the electrolytic cell for ozone production presents a large volume in the ozone producing system to be installed.
On the other hand, if the electrolytic area is reduced, the cell must be operated at a higher current density to compensate for the reduced area, possibly leading to a lower current efficiency of ozone production or shorter lives of various structural members of the system.
In the system described in JP 11-315389 A, the temperature rise in the anode compartment can be suppressed and the temperature of the electrolytic cells can be reduced, but as no cathode cooling is applied, the temperature remains high, and then, lowering temperatures inside the electrolytic cells, especially at the interfaces between the ion exchange membrane and the anode and between the ion exchange membrane and the cathode, where electrolysis reaction is being performed, is not sufficient.
Because of these reasons, temperature distribution occurs within the electrolytic. cell; ozone gas concentration or current efficiency tend to be deteriorated due to degraded structural members with lapse of time; and frequent replacement of structural members is required to maintain satisfactory performance level, which are problematic to this system.

Method used

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example

[0030] The following explain examples of the present invention. The present invention, however, is not limited to these examples.

[0031] As Examples 1 and 2 of the present invention, electrolysis was conducted at a current density 200 A / dm2 using the ozone producing system shown in FIGS. 1-3. In this. experiment, the anode 8 is that supported with ozone generation catalyst on the electrically conductive porous material, the membrane 9 is a perfluorocarbon sulfuric acid polymer ion exchange membrane, the cathode 10 is that supported with platinum catalyst. The applied anode and cathode in Example 1 were 112.5 mm square or rectangular type electrodes and those in Example 2 were 100 mm square or rectangular type electrodes.

[0032] Anolyte and catholyte were circulated between the anode compartment 1 and the anolyte gas-liquid separation tower 4, and between the cathode compartment 2 and the catholyte gas-liquid separation tower 5, respectively. The externals of the anode compartment fr...

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Abstract

In an ozone producing electrolytic cell for producing ozone gas by water electrolysis, said anode compartment 1, said cathode compartment 2, said anode compartment frame 6, said anode 8, said ion exchange membrane 9, said cathode 10, said current collector 11, and said cathode compartment frame 12 constituting the electrolytic cell for ozone production 3 are all in the same shape of square or rectangular; and multiple numbers of grooves 13 are formed on the internal surfaces of said anode compartment frame 6 and said cathode compartment frame 12, thereby reducing current density to suppress load on the electrolytic cell for ozone production, even under a given current value supplied to the electrolytic cells for producing ozone.

Description

BACKGROUND OF THE INVENTION [0001] 1. Field of the Invention [0002] The present invention relates to an ozone producing system to produce ozone gas by means of water electrolysis in which the current density is kept smaller for a given electric current value applied to the electrolytic cell for ozone production, thus the load imposed on the electrolytic cell for ozone production being suppressed and the temperature in the electrolytic cell is kept lower in order to achieve ozone production at a higher efficiency and longer lives of structural members of the electrolytic cell for ozone production. [0003] 2. Description of the Related Art [0004] The method of producing ozone gas by means of water electrolysis is among those of publicly known technology, in which a conventional way has been the method by the electrolytic cell for ozone production with an anode supported with ozone generation catalyst on an electrically conductive porous material and a cathode supported with platinum ca...

Claims

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Application Information

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IPC IPC(8): C25B9/10C25B9/23
CPCC25B9/08C25B1/13C25B9/19
Inventor HASHIMOTO, TERUMIKATO, MASAAKIMANABE, AKIYOSHI
Owner CHLORINE ENGINEERS CORP LTD