Hydrocarbon fuel production method
a hydrocarbon fuel and production method technology, applied in the direction of fatty acid chemical modification, fatty-oil/fat separation, biomass after-treatment, etc., can solve the problems of low quality of aliphatic compound as fuel, adversely affecting the material of engine, and high content of oxygen, so as to achieve commercial stably the effect of production
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example 1
[0106]Hydrodeoxygenation treatment was performed by an operation similar to that of Comparative Example 1 except that instead of the hexane-extracted oil in Comparative Example 1, a propane-soluble portion was used that was obtained by repeating propane extraction under the condition (temperature 111° C.) in which the solubility of the hexane-extracted oil in propane under a pressure of 6 MPa was 13.7 g per 100 g of propane, shown in the above-described Table 1, until the recovery rate reached 90% or more. Catalyst deterioration was reduced compared with Comparative Example 1 and Comparative Example 2, and the catalyst deterioration rate indicator was 0.7° C. / day.
example 2
[0107]An operation similar to that of Comparative Example 1 was performed except that instead of the hexane-extracted oil in Comparative Example 1, a propane-soluble portion was used that was obtained by repeating propane extraction under the condition (temperature 112° C.) in which the solubility of the hexane-extracted oil in propane under a pressure of 6 MPa was 8.0 g per 100 g of propane, shown in the above-described Table 1, until the recovery rate reached 90% or more. Catalyst deterioration was further reduced, and the catalyst deterioration rate indicator was 0.5° C. / day.
example 3
[0108]Hydrodeoxygenation treatment was performed by an operation similar to that of Comparative Example 1 except that instead of the hexane-extracted oil in Comparative Example 1, a propane-soluble portion was used that was obtained by repeating propane extraction under the condition (temperature 114° C.) in which the solubility of the hexane-extracted oil in propane under a pressure of 6 MPa was 5.5 g per 100 g of propane, shown in the above-described Table 1, until the recovery rate reached 90% or more. Catalyst deterioration was further reduced, and the catalyst deterioration rate indicator was 0.3° C. / day.
[0109]The results of the Comparative Examples and the Examples described above are collectively shown in Table 4. In addition, impurity concentration in the hexane-extracted oil and the propane-soluble portions obtained by performing propane extraction under the respective conditions, subjected to hydrodeoxygenation treatment, is shown together in Table 4. From the results show...
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