Lubricating compositions with enhanced deposit performance

a technology of lubricating compositions and deposits, applied in the field of lubricating compositions, can solve the problems of complex chemistry used in the formulation of engine oils, limited solubility of polar additives, and high non-polarity, and achieve the effects of reducing the potential damage of ash, improving overall fuel economy, and reducing the formation of deposits

Inactive Publication Date: 2019-01-24
EXXON RES & ENG CO
View PDF3 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0015]Accordingly, the claimed invention includes a dispersant-stabilized, borated CRFM that provides a much larger amount of friction modifier in the lubricating oil composition, which results in improved overall fuel economy. Additionally, the CRFM is a low-ash composition, which reduces potential damage from ash to ash particulate filters.
[0016]Adding the above CRFM to a lubricating oil composition offers a number of challenges, including CRFM deposit formation. The composition of the present invention has surprisingly mitigated the formation of deposits from the CRFM by also including a combination of additives that include a synergistic use of dispersant, viscosity modifier and cleanliness booster. Thus, the present invention provides a lubricating oil composition that not only improves overall fuel economy but does so while meeting other performance specifications that require the VW TDi2 (CEC L-78-99).

Problems solved by technology

Because there are many requirements, the chemistry used to formulate engine oils is complex.
Often a particular additive that can improve one aspect of a lubricant's performance works against the performance enabled by other additives.
Such oils are highly non-polar and, as a result, have a limited amount of solubility for polar additives.
Additionally, the use of highly paraffinic base oils can increase the amount of unwanted deposit formation.
Specifically, most fuel economy additives, including the friction modifiers detailed above, are highly polar and, as such, are challenged to remain soluble in the lubricating oil.
With limited solubility and availability of the additives, improvements in fuel economy are similarly limited.
In addition, many of the additives degrade or are consumed in service with the result that fuel economy is more difficult to maintain for extended times. Additionally, conventional friction modifiers typically cause increased deposit formation as they have limited solubility and are rapidly oxidized in-service.
These documents, however, do not describe compositions that have been formulated to provide increased fuel economy while also reducing deposit formation and friction in an engine.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Lubricating compositions with enhanced deposit performance
  • Lubricating compositions with enhanced deposit performance
  • Lubricating compositions with enhanced deposit performance

Examples

Experimental program
Comparison scheme
Effect test

examples

[0101]As noted above, creating engine oil compositions including a CRFM presented certain challenges to the present inventors. Particularly, the addition of a CRFM to the lubricating oil composition can result in unmanageable deposit formation from the CRFM.

[0102]FIG. 1 illustrates a graph of TDi2 piston deposit merits for initial CRFM formulations. The piston deposit merit is a cleanliness grade for an engine oil. A merit score of 65 indicates a passing grade with 70 indicating an exceptionally clean formulation. As is illustrated in FIG. 1, an initial lubricating oil (comparative example 2A), which did not include any CRFM, had a deposit merit score of 65. When CRFM was added to this initial oil, the deposit merit score drop significantly to 54 (comparative example 2B) and 50 (comparative example 2C), respectively. Thus, with merely adding CRFM to an existing engine oil, the deposit merit score dropped to well below passing. Similarly, another initial lubricating oil (comparative ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
viscosity indexaaaaaaaaaa
viscosity indexaaaaaaaaaa
viscosity indicesaaaaaaaaaa
Login to view more

Abstract

A lubricant composition includes a lubricating base oil, a controlled release friction modifier, a dispersant, a viscosity modifier and a cleanliness booster. The controlled release friction modifier is an ashless, dispersant-stabilized, borated controlled release friction modifier including an ionic tetrahedral borate compound including a cation and a tetrahedral borate anion, wherein the tetrahedral borate anion includes a boron atom having two bidentate di-oxo ligands of C18 tartrimide.

Description

[0001]This nonprovisional application claims priority to U.S. Provisional Application No. 62 / 535,527, which was filed on Jul. 21, 2017, and is herein incorporated by reference.BACKGROUND OF THE INVENTIONField of the Invention[0002]The present invention relates to a lubricant composition, in particular, a lubricant composition, suitable for use in, for example, internal combustion engines, which reduces deposit formation and friction in an engine.Description of the Background Art[0003]Engine oils are formulated for the purpose of reducing friction in the engine, engine cleanliness (e.g., deposit control), control of wear, corrosion and rust in the engine. To accomplish this goal, engine oils contain numerous and various additives including friction modifiers, detergents, dispersants, viscosity modifiers and antioxidants.[0004]Of significant concern is the reduction of friction in engines so as to improve fuel economy necessitating the use of lower viscosity lubricating base stocks wh...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(United States)
IPC IPC(8): C10M143/12C10M143/06C10M101/02
CPCC10M143/12C10M143/06C10M101/025C10N2230/02C10N2230/06C10N2230/04C10M169/04C10M2203/1025C10M2205/0285C10M2205/08C10M2207/262C10M2215/086C10M2215/28C10M2219/046C10M2227/061C10N2020/04C10N2020/02C10N2030/04C10N2030/06C10N2030/52C10N2040/25C10N2060/14C10N2030/02
Inventor BLUMENFELD, MICHAEL L.DECKMAN, DOUGLAS E.DANCE, SMRUTI A.BAKER, JR., CHARLES L.BURRINGTON, JAMES DAVIDPRISTIC, DAVID PAULDELBRIDGE, EWAN E
Owner EXXON RES & ENG CO
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products