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48results about How to "Specific performance" patented technology

Polysiloxane, glycidol and quaternary ammonium salt-containing multifunctional gelatin leather finishing agent and preparation method

The invention relates to a polysiloxane, glycidol and quaternary ammonium salt-containing multifunctional gelatin leather finishing agent and a preparation method. The preparation method comprises the following steps: dissolving gelatin in water to prepare aqueous solution with mass concentration of 2-20 percent; adding epoxy quaternary ammonium salt into a first reaction flask under the conditions of temperature of 40-70 DEG C and pH of 6-12 to obtain solution 1; adding glycidol into a second reaction flask to obtain solution 2; adding a surfactant into a third reaction flask, and meanwhile adding Si-O-Si repetitive unit-containing epoxypolysiloxane in batches or continuously to obtain solution 3; mixing the solution 1, the solution 2 and the solution 3 in different proportions, weighing 15-20 g of the mixed solution to be placed in a mold of polytetrafluoroethylene, adding 5-10 mL of one or three or four of ethanol, tetrahydrofuran, acetone and methanol and drying in a normal pressure drying oven at the temperature of 40-80 DEG C to obtain the multifunctional gelatin leather finishing agent. The finishing agent has the characteristics of strong hydrophobicity, flexible film, antibacterial property, high heat stability, organic solvent resistance, wet scrubbing resistance and the like.
Owner:山东山科美谷科技发展有限公司

Polysiloxane and glycidol-containing strong-hydrophobicity gelatin leather finishing agent and preparation method

The invention relates to a polysiloxane and glycidol-containing strong-hydrophobicity gelatin leather finishing agent and a preparation method. The preparation method comprises the following steps: dissolving gelatin in water to prepare aqueous solution with mass concentration of 2-20 percent; adding glycidol into a first reaction flask under the conditions of temperature of 40-70 DEG C and pH of 6-12 to obtain solution 1; adding a surfactant into a second reaction flask, continuously stirring, and meanwhile adding Si-O-Si repetitive unit-containing epoxypolysiloxane in batches or continuously to obtain solution 2, wherein the using amount of the surfactant is 0.5-20 percent of the mass of the gelatin; mixing the solution 1 and the solution 2 in different proportions, weighing 15-20 g of the mixed solution to be placed in a mold of polytetrafluoroethylene, adding 5-10 mL of one or two or three of ethanol, tetrahydrofuran and methanol and drying in a normal pressure drying oven at the temperature of 40-80 DEG C to obtain the gelatin leather finishing agent with a superior function. The finishing agent has the characteristics of strong hydrophobicity, super extensibility, heat resistance, oxidation resistance, wet scrubbing resistance and the like.
Owner:QILU UNIV OF TECH

Polysiloxane and quaternary ammonium salt-containing antibacterial gelatin leather finishing agent and preparation method

The invention relates to a polysiloxane and quaternary ammonium salt-containing antibacterial gelatin leather finishing agent and a preparation method thereof. The preparation method comprises the following steps: dissolving gelatin in water to prepare aqueous solution with mass concentration of 2-20 percent; adding epoxy quaternary ammonium salt into a first reaction flask under the conditions of temperature of 40-70 DEG C and pH of 6-12 to obtain solution 1; adding a surfactant into a second reaction flask, continuously stirring, and meanwhile adding Si-O-Si repetitive unit-containing epoxypolysiloxane in batches or continuously to obtain solution 2, wherein the using amount of the surfactant is 2-20 percent of the mass of the gelatin; mixing the solution 1 and the solution 2 in different proportions, weighing 15-20 g of the mixed solution to be placed in a mold of polytetrafluoroethylene, adding 5-10 mL of one or two or three of ethanol, tetrahydrofuran and methanol and drying in a normal pressure drying oven at the temperature of 40-80 DEG C to obtain the multifunctional gelatin leather finishing agent. The finishing agent has the characteristics of antibacterial property, adjustable hydrophilia and hydrophobicity, flexible film, strong anti-oxidant capacity and the like.
Owner:QILU UNIV OF TECH

Low-density polyethylene (LDPE) resin for cable insulant having voltage level of above 110kV, and preparation method thereof

The invention discloses a low-density polyethylene (LDPE) resin for a cable insulant having a voltage level of above 110kV, and a preparation method thereof, and belongs to the field of LDPE resins. The LDPE resin is the characterized in that a melt flow rate is in a range of 0.1 to 10g/10min; density is in a range of 0.910 to 0.940kg/cm<3>; a degree of crystallization is in a range of 30 to 60%; molecular weight distribution Mw/Mn determined by a gel permeation chromatography is in a range of 2 to 7; fracture elongation is above 500%; a dielectric constant is below 4; a dielectric loss factor is below 6*10<-4>; volume resistivity is above 1.0*10<15>Omega.cm; and a maximum impurity size representing cleanliness is below 0.5mm. The preparation method of the LDPE resin comprises the following steps that 1, raw materials and a conditioning agent are subjected to compression boosting; 2, an initiator-peroxide solution is injected into the mixture obtained by the step 1 and undergoes a polymerization reaction; and 3, the polymerization system obtained by the step 2 is controlled and adjusted. The LDPE resin has specific performances, stable processing performances and physicochemical performances, and high cleanliness, and thus satisfying ultrahigh voltage cable insulation layer production requirements. The preparation method has relatively simple processes and adopts LDPE production equipment. Reaction conditions needed by the preparation method are easy to be satisfied.
Owner:BASF YPC

Preparation of mono-epoxy-terminated polysiloxane-modified gelatin gradient membrane by freeze-drying method

The present invention relates to preparation of a mono-epoxy-terminated polysiloxane-modified gelatin gradient membrane by a freeze-drying method. Surfactant sodium alkyl sulfate is dissolved in water and formulated into an aqueous solution, the aqueous solution is stirred for 1-2h at 40-60 DEG C under the condition of pH of 8 to 11, gelatin is added, stirring is performed for 4-8h, and mono-epoxy-terminated polysiloxane with the molecular weight of 500 is added to obtain a mono-epoxy-terminated polysiloxane-modified gelatin solution. The mono-epoxy-terminated polysiloxane-modified gelatin solution is centrifuged at a low temperature, after layering, water is added into an intermediate layer for even mixing, ethanol is added, after even mixing, 0.5-0.8ml of the mixture is measured and dropwise added into a gelatin substrate, standing is performed for 12-18h, liquid nitrogen is used for freezing, and the freeze-drying method is used for drying to obtain the mono-epoxy-terminated polysiloxane-modified gelatin gradient membrane. The mono-epoxy-terminated polysiloxane-modified gelatin gradient membrane has the characteristics that component concentration change is gradient in longitudinal section, and the mono-epoxy-terminated polysiloxane-modified gelatin gradient membrane is high in tensile strength, good in hydrophobicity and soft, and so on.
Owner:山东山科美谷科技发展有限公司

Modified gelatin gradient film prepared from mixed glycidol and single-epoxy-terminated polysiloxane

The invention relates to a modified gelatin gradient film prepared from mixed glycidol and single-epoxy-terminated polysiloxane. A method for preparing the modified gelatin gradient film includes dissolving surfactants in water to prepare aqueous solution; adding gelatin into the aqueous solution under the conditions of the temperatures of 40-60 DEG C and the pH (potential of hydrogen) of 8-11; stirring the gelatin and the aqueous solution for 4-8 h and then adding the single-epoxy-terminated polysiloxane into the gelatin and the aqueous solution continuously or in batches to obtain mixtures; carrying out reaction for 12-30 h and then adding glycidol into the mixtures; continuing to carry out reaction at the temperatures of 40-60 DEG C for 6-12 h to obtain milk white turbid liquid; adding ethyl alcohol into the milk white turbid liquid and uniformly mixing the ethyl alcohol with the milk white turbid liquid to obtain mixed liquid; dripping 0.5-0.8 ml of the measured mixed liquid on gelatin substrates; allowing the gelatin substrates to stand still for 12-18 h and then freezing the gelatin substrates by the aid of liquid nitrogen; drying the gelatin substrates by the aid of a freeze dryer to obtain the gradient film. The dosage of the gelatin is 1-10% of the mass of the aqueous solution. The dosage of the single-epoxy-terminated polysiloxane is 0.2-1.0 times the molar weight of the gelatin. The dosage of the glycidol is 0-1 times the mass of the single-epoxy-terminated polysiloxane. A volume ratio of the ethyl alcohol to reaction liquid is (3-5):1. The modified gelatin gradient film has the advantages that the concentration of components of the modified gelatin gradient film changes in longitudinal sections in a gradient manner, the modified gelatin gradient film is high in tensile strength and good in hydrophobic property and is soft, and the like.
Owner:山东山科美谷科技发展有限公司
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