Silver halide color photosensitive material

a color photosensitive material and silver halide technology, applied in the field of silver halide color photosensitive materials, can solve the problems of difficult to obtain satisfactory image quality, inability to achieve excellent graininess on their own, and large amount of low activity couplers, etc., and achieve the effect of high image quality

Inactive Publication Date: 2006-10-03
FUJIFILM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0011]The task of the present invention is to provide a silver halide color photosensitive material capable of realizing an extremely high image quality excelling in graininess and in bright acuity.
[0015]Compound (A): heterocyclic compound having one or more heteroatoms, which heterocyclic compound is capable of substantially increasing the sensitivity of silver halide color photosensitive material by addition thereof as compared with that exhibited when the compound is not added.
[0032]The present invention has enabled obtaining a silver halide color photosensitive material capable of realizing an extremely high image quality excelling in graininess and in bright acuity.

Problems solved by technology

However, with respect to such photosensitive materials of high photographic speed, it is difficult to obtain satisfactory image quality when the print size is large.
These however on their own cannot attain excellent graininess.
However, the use of couplers of low activity in large amounts is attended by harmful effects, such as strong influence of variations of processing solution composition.
The use of DIR compounds leads to a change of the level of interlayer effect, making compatibility with color reproduction difficult.
The reduction of the dimension of silver halide grains leads to an intensification of light scattering, making it difficult to attain an enhancement of image quality involving bright acuity.
However, improvement of graininess cannot be attained thereby.

Method used

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  • Silver halide color photosensitive material
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  • Silver halide color photosensitive material

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0450]The silver halide emulsions Em-A to Em-O listed in Table 1 were prepared with reference to the process for preparing emulsions Em-A to Em-O as described in Example 1 of JP-A-2001-281815.

[0451]

TABLE 1AverageAveragesilverequivalent-iodidesphereEmulsioncontentdiametername(mol %)(μm)ShapeEm-A40.75TabularEm-B50.54TabularEm-C4.70.40TabularEm-D10.37TabularEm-E50.70TabularEm-F5.50.50TabularEm-G4.70.40TabularEm-H2.50.37TabularEm-I1.50.27TabularEm-J50.87TabularEm-K3.70.44TabularEm-L5.50.87TabularEm-M8.80.64TabularEm-N3.70.37TabularEm-O1.80.19Cubic

[0452]In the tabular grains of Table 1, dislocation lines as described in JP-A-3-237450 are observed through a high-voltage electron microscope.

1) Superimposition of Light-Sensitive Layers

(Preparation of Sample 001)

[0453]Multilayer coating of a cellulose triacetate support was effected with the following compositions, thereby obtaining a color negative film (sample 001).

(Compositions of Light-Sensitive Layers)

[0454]The main materials used in th...

example 2

[0504]Samples 201, 202, 205, 210 and 212 were prepared by respectively changing the supports of the samples 101, 102, 105, 110 and 112 to a triacetylcellulose film support furnished with a 7 μm thick back layer consisting of a hydrophilic colloid layer. The samples were wrought into Brownie-format, used in the same photographing as in Example 1 and developed with the use of automatic processor FP-232B manufactured by Fuji Photo Film Co., Ltd. Thereafter, the same evaluation as in Example 1 was carried out. As demonstrated in Example 1, the photosensitive materials of the present invention produced favorable results.

[0505]At the observation of these samples after processing, although slight abrasion was observed on the samples 201 and 202, there was no abrasion on the other samples.

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Abstract

A silver halide color photosensitive material of less than 320 ISO speed, comprising at least two red-sensitive emulsion layers, at least two green-sensitive emulsion layers, at least one blue-sensitive emulsion layer and at least one nonsensitive layer, wherein silver halide tabular grains of 0.15 μm or less grain thickness are contained in an amount of 50% or more in respective layers with the highest speed among the green- and red-sensitive emulsion layers; wherein the total dry film thickness of the material on the emulsion layer side thereof is 24 μm or less; and wherein the compound (A) is contained in at least one silver halide emulsion layer or the nonsensitive layer.Compound (A): heterocyclic compound having one or more heteroatoms, which heterocyclic compound is capable of substantially increasing the sensitivity of silver halide color photosensitive material by addition thereof as compared with that exhibited when the compound is not added.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2003-331819, filed Sep. 24, 2003, the entire contents of which are incorporated herein by reference.BACKGROUND OF THE INVENTION[0002]1. Field of the Invention[0003]The present invention relates to a silver halide color photosensitive material capable of realizing an extremely high image quality excelling in graininess and in bright acuity.[0004]2. Description of the Related Art[0005]In recent years, photosensitive materials of high photographic speed are placed on the market in quick succession in accordance with the progress of technology relating to photosensitive materials for photographing. Accordingly, the photographed areas are expanding to night scenes, dark indoor space, etc.[0006]However, with respect to such photosensitive materials of high photographic speed, it is difficult to obtain satisfactory image quality when the ...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): G03C1/46G03C1/005G03C1/494G03C1/00G03C1/035G03C7/20G03C1/10G03C1/74G03C7/00G03C7/30G03C7/38G03C7/392
CPCG03C7/3924G03C7/3022G03C7/3029G03C7/3041G03C7/3825G03C2007/3025G03C1/0051G03C2007/3027G03C2007/3034Y10S430/156G03C1/46
Inventor TOYODA, MASAYOSHIHOSOKAWA, JUNICHIROHIOKI, TAKANORI
Owner FUJIFILM CORP
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