94 results about "Helium ionization detector" patented technology

The invention relates to a field gas chromatograph with flame ionization for the analysis of a gaseous mixture of hydrocarbons, extracted, in particular, from oil drilling mud. Said mixture consists of a fraction of heavy hydrocarbons (beyond pentane) dissolved in mud in gaseous form. Said field gas chromatograph is made up of two independent analysis circuits, dephased by half a cycle and synchronised one with the other. Said analysis circuits are comprised of at least one sampling cell in a preferred design layout, at least one capillary separation chromatography column, at least one flame ionization detector, and at least one electrometer for the conversion of an electrical current, collected by the flame ionization detector, into a voltage signal describing a chromatogram.

The invention relates to a method for measuring trace impurity concentration of 7N electronic grade ultrapure ammonia. The method comprises the following steps of: separating trace impurities from the ultrapure ammonia by a pipeline system subjected to corrosion-resistant and adsorption-resistant treatment, by large-flow replacement, sweeping and sampling and a three-valve four-column cutting back-flushing gas channel system; and analyzing impurity gases by using a direct current discharging helium ionization detector (DID). The method has the advantages of capacity of providing a balanced (stable state) analysis value within short time, quantitative accuracy, low detection limit and short analysis period.

The invention provides a helium ionization gas chromatography system for analyzing decomposition products of SF6. The system in characterized by includes a central cutting device and a double helium ionization detector. The central cutting device includes four switching valves, six chromatography columns and seven carrier gas paths. The double helium ionization detector includes two sets of helium ionization detector devices. The helium ionization gas chromatography system for analyzing decomposition products of SF6 also includes a chromatography column box temperature controlling device and a carrier gas cutting and air-insulation device, wherein the chromatography column box temperature controlling device includes a set of programme temperature increasing column box and three sets of individual column sub temperature-controlling column boxes, and the carrier gas cutting and air-insulation device includes a set of four-way valve system and a set of carrier gas path. By means of the system, total analysis of the decomposition products of SF6 can be completed just by one sample-feeding operation.

The invention discloses an analysis system for determining impurity components in highly pure gases, and a determination method thereof. The analysis system comprises a helium ionization detector, a hydrogen flame detector, seven valves, seven columns and three sample quantification rings, and the detection of many impurity components, such as nitrogen, hydrogen, oxygen/argon, carbon monoxide, carbon dioxide, methane, ethane/ethylene, acetylene and C3 hydrocarbon impurities in various highly pure gases, such as highly pure ammonia, highly pure oxygen, highly pure nitrogen and highly pure hydrogen is realized on the analysis system. The method allows impurities in the highly pure gases to be separated through chromatographic columns and to be detected through the helium ionization detector and the hydrogen flame detector by adjusting the opening or closure of the valves to obtain the determination data of the impurities. The analysis system can detect a variety of impurities in highly pure industrial gases, so the determination cost is reduced; and the method can satisfy the sensitivity requirement of highly pure gas analysis and the detection limit requirements of all impurity gases, and greatly increases the analysis efficiency.

A supplemental air system for a portable, intrinsically safe (IS), flame ionization detector (FID) device includes a portable, intrinsically safe, FID device and a supplemental air system coupled to the FID device configured to store compressed air and deliver a flow of regulated air to the FID device as needed.

The invention discloses a photo ionization detector, comprising a vacuum ultraviolet lamp and an ionization chamber, wherein the ionization chamber comprises two electrodes with minor arc radial cross sections, wherein the electrodes are arranged symmetrically, and comprise a polarized electrode and a collecting electrode. The two electrodes insert into the interior of polytetrafluoroethylene tank in the ionization chamber, such that base current and noise of the electrodes caused by irradiation of the vacuum ultraviolet lamp are avoided. The detector contains an automatically cleaning system to prevent decreasing of sensitivity of the detector caused by pollution of light window and electrodes when the detector is in a continuous operation for a long time. The photo ionization detector suits as a detector of a portable gas chromatograph and a rapid gas chromatograph.

A gas chromatography-quadrupole time-of-flight mass spectrometry/flame ionization detection method of flavor components in cigarette mainstream smoke comprises the following steps: collecting the flavor components in the cigarette mainstream smoke through adopting a Cambridge filter, extracting the flavor components with dichloromethane or n-hexane, taking the obtained extract liquid, analyzing the extract liquid, and allowing the obtained sample to undergo chromatographic column separation and to enter a quadrupole time-of-flight mass spectrometer (QTOF MS) and a flame ionization detector (FID) for determination in order to realize accurate qualitative diagnosis and quantification of the flavor components in cigarette mainstream smoke. The gas chromatography-quadrupole time-of-flight mass spectrometry/flame ionization detection method is applied to determination of the flavor components in cigarette mainstream smoke for the first time, and a QTOF MS spectrogram and an FID spectrogram can be simultaneously obtained only through one-shot sample introduction; and the components of a complex sample can be accurately characterized through the QTOF MS, a sample with very wide concentration range can be accurately quantified, and the retention times of the two spectrograms are completely same, so accurate qualitative diagnosis and quantification of the flavor components in cigarette mainstream smoke can be realized.

A pulsed discharge helium ionization detector for gas chromatography with multiple combined bias/collecting electrodes.

The invention relates to a hydrogen flame ionization detector and working method thereof. The hydrogen flame ionization detector comprises an outer cover, a chromatographic column, a collector, a polarization electrode, a conductive nozzle and a detection circuit. The collector is connected with the detection circuit after being connected with a polarization power source in series. The collector is connected with the negative pole of the polarization power source. The conductive nozzle is a ground potential. According to the hydrogen flame ionization detector, polarization voltage is connected to a signal outgoing line of the collector in series, meanwhile, the traditional polarization electrode and the nozzle are combined into a whole, the ground potential is kept, the normal function of the detector is ensured, and the equipment complexity and production technology are simplified.

The invention discloses a cooling oil content measuring method. The cooling oil content measuring method comprises a step of qualitative and quantitative analysis on one or more ingredients of menthol, camphor, eucalyptol and eugenol. The method comprises the following specific steps: (1) taking the menthol, the camphor, the eucalyptol and the eugenol as reference objects; (2) treating a cooling oil sample by using a solvent, and then detecting the cooling oil sample by using a GC (Gas Chromatography) method; (3) a GC measuring method is as follows: a chromatographic column and a detector are used, wherein the chromatographic column is an HP-INNO WAX capillary column; the detector is a flame ionization detector; the temperature of the detector is 250-300 DEG C, the temperature of a sample inlet is 220-270 DEG C, the temperature of the column is increased in a programmed manner from an initial temperature of 60-110 DEG C to 220-280 DEG C, the temperature is increased by 5-15 DEG C every minute and kept for 8-20 minutes; sampling mode: split sampling is adopted, and the split ratio is 20:1. The method is scientific, reasonable, simple, convenient, easy to implement and suitable for quality control of volatile components including the menthol, the camphor and the like of the cooling oil and relevant extractives.

The flame ionization detector consists of sample port, hydrogen port, nozzle, air port, igniting coil and collector electrode, as well as nozzle cap, spring and shaft. Of the flame ionization detector, the shaft with flange is connected to the negative high voltage power source, the nozzle with nozzle cap possessing through hole constitutes the polarizing electrode, the spring has one end contacting the nozzle cap and the other end contacting the flange, and the igniting coil is mounted over the collector electrode. The present invention has high signal collecting efficiency of the collector electrode, lowered noise interference, and high sensitivity.

Disclosed is a gas chromatography-quadrupole time-of-flight mass spectrometry/ flame ionization detection method for tobacco essence perfume. The method includes subjecting the tobacco essence perfume to organic solvent extraction and centrifugation, taking an organic solvent layer to analyze, regulating tail-end distribution of a chromatographic column through a capillary flow technology after the sample is subjected to chromatographic column separation, and determining by a QTOF MS (quadrupole time-of-flight mass spectrometer) and FID (flame ionization detector) to achieve accurate qualitativeness and quantitativeness of the tobacco essence perfume. The gas chromatography-quadrupole time-of-flight mass spectrometry/ flame ionization detection method is put forward for the first time and is applied to determination of the tobacco essence perfume, QTOF MS and FID spectrograms can be obtained simultaneously only by one-needle sample injection, QTOF MS can determine components of complicated samples accurately, the FID is capable of qualifying the sample with wide concentration range accurately, and the retention time of the QTOF MS spectrogram and the retention time of the FID spectrogram are the same, so that accurate qualitativeness and quantitativeness of complicated tobacco essence perfume samples can be achieved.

The invention discloses a method and system for measuring the content of gas components in fuel hydrogen, a gas sample is quantitatively sampled through a first quantitative loop, then a first chromatographic column and a first exhaust valve are conducted, the front main components of hydrogen are emptied through the first exhaust valve, and when oxygen and argon are separated from the first chromatographic column, the first chromatographic column is communicated with a second chromatographic column, oxygen and argon are carried into the second chromatographic column, when oxygen and argon completely enter the second chromatographic column, the first chromatographic column is switched to be communicated with the first exhaust valve, and main components after hydrogen are discharged. When nitrogen is separated from the first chromatographic column, the first chromatographic column is switched to be communicated with the second chromatographic column, the nitrogen, methane and carbon monoxide are carried to the second chromatographic column, and the content of the nitrogen, methane and carbon monoxide is detected by the pulse discharge helium ionization detector, so that a gas sample can be prevented from being separated at one time, and the fuel hydrogen content is high; the separated permanent gas is easily separated from the first chromatographic column, so that the detection result is inaccurate, the detection efficiency can be improved as much as possible through twice completion, and the separation time is prevented from being prolonged.

The invention discloses a hydrogen flame ionization detector, which is characterized by comprising a detector cavity, an ignition filament, a collection electrode, a signal output end, an oxidant gasinput channel, a nozzle, a high-pressure component and a carrier gas input channel; the detector cavity is a vertical channel, the ignition filament is arranged in an ignition filament pipeline whichis communicated with the detector cavity, the signal output end is connected with the collection electrode, the oxidant gas input channel is communicated with the vertical channel, the high-pressure component extends into the vertical channel and is connected with the nozzle, the carrier gas and fuel/make-up gas input channel is communicated with the vertical channel, and the detector further comprises an electronic flow controller for controlling the input of gas; and the electronic flow controller is adopted to precisely control the gas flow, and is capable of automatically detecting the status of interior of the cavity and controlling automatic ignition and the cut-off of three ways of gas flow in the failure of ignition, so that not only can safety be achieved, but also the gas can besaved, in addition, the hydrogen flame ionization detector also has the characteristics of being simple in structure, stable and reliable, and convenient to operate.

The invention discloses a gas chromatograph for gas analysis in production field, comprising a sampling unit, a gas path control unit, a circuit control unit, a separation unit, a detection unit and a data processing unit. The gas chromatograph for gas analysis in production field is characterized in that the sampling unit is a sampling and automatic sample injection unit, and is composed of a fixed volume sampling tube, a flow meter and a ten-way valve with blowing function; the gas path control unit is composed of a solid filter, a stainless steel diaphragm pressure stabilization valve and a helium purifier, and provides high-purity carrier gas for the separation unit; the circuit control unit is composed of a temperature control circuit, a signal amplification circuit and a detector pulse high-voltage circuit; the separation unit is provided with three diaphragm valves with blowing function, wherein one is the ten-way valve with blowing function in the sampling unit, the other two are four-way valves with blowing function, and complete separation of constituents is completed through a three-valve and four-column switching flow; the detection unit is a pulse helium ionization detector; and the data processing unit is composed of an embedded industrial control computer and a data uploading module. The gas chromatograph for gas analysis in production field has the advantages of high detection sensitivity, good stability and strong operability.

To suppress baseline current other than baseline current derived from the ionization of impurities, and to achieve the enhancement of the SN ratio of a detection signal and the improvement of the lower limit of detection, the inner diameter of a bias electrode for collecting an ion derived from a sample component is made smaller than the inner diameter of an insulating member separating the bias electrode and a collector electrode. Light emitted from plasma formed by dielectric barrier discharge is shielded by the bias electrode, so that the light is not cast directly on the surface of the insulating member. Therefore, the photoelectric effect caused by casting light of high energy does not occur on the surface of the insulating member, whereby a decrease in electric resistance of the surface can be prevented.

The present invention discloses a photoionization detector (PID) system that can perform calibrations automatically. The PID system comprises a measurement gas chamber and one or more calibration gas chambers. The one or more calibration gas chambers each hold a type of calibration gas. In one embodiment, a volatile organic compounds (VOCs) measurement and a calibration measurement are conducted in the same gas chamber. In another embodiment, VOCs and calibration measurements are conducted in different gas chambers either simultaneously or at different times.

The flame ionization detector, which comprises a supply and an ignition device (7) for the combustible gas, a supply for the sample gas, a combustion chamber (4) in which the sample gas is ionized by the flame, and electrodes (8, 1) to which a voltage is applied in order to generate and measure the ion current, is distinguished in that it is constructed as an integrated planar system of at least three parallel platelet-like substrates (1, 2, 3) which are connected to one another and are processed by microsystem technology methods, with a central substrate (1) comprising nozzles (5, 6) for the gases and the ignition device (7) and a recess which forms a part of the combustion chamber (4), is completed by recesses in the neighboring substrates (2, 3) and is essentially closed together with the nozzle region by these substrates (2, 3), and the neighboring substrates (2, 3) comprise supply channels (10, 11) for the gases.