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Thermoplastic resin composition

A thermoplastic resin and composition technology, applied in the field of thermoplastic resin composition, can solve the problems of low bending strength, low impact strength, low tensile strength of ABS resin, etc., and achieve the effect of improving mechanical properties

Inactive Publication Date: 2008-08-27
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The technical problem to be solved by the present invention is that in the prior art, the tensile strength of ABS resin is not high, the bending strength is low and the impact strength is low, and a new thermoplastic composition is provided

Method used

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  • Thermoplastic resin composition
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Experimental program
Comparison scheme
Effect test

Embodiment 1~9 and comparative example 1~2

[0021] Mix the dried SANMA resin, ABS high rubber powder, and antioxidant 1010 in a container according to the mass ratio in Table 1, and then add them to the hopper of the twin-screw extruder for later use. The barrel temperature of the twin-screw extruder (Germany Leistritz company, screw diameter 27 mm, length-to-diameter ratio 36: 1) is controlled at 200-230°C (gradually warming up from the feeding port to the head), and the screw speed is 120 rpm. Extrude the above-mentioned material at a speed of about 10 kg / hour, cool with water, and cut into pellets to obtain the product. Comparative Example SAN resin was used instead of SANMA resin.

[0022] Dry the above product in a hot air oven at 85°C for 3 hours and then inject it into a standard sample with a plastic injection molding machine. The injection temperature is 230-240°C, the injection pressure is 8MPa, and the molding cycle is 52 seconds. After the injection-molded samples were placed in the test environment for 24 ...

Embodiment 10~15 and comparative example 3~4

[0034] Mix the dried SANMA resin, ABS high-grade rubber powder, and antioxidant 1010 in a container according to the mass ratio in Table 1, and then add them to the hopper of the twin-screw extruder for later use. The barrel temperature of the twin-screw extruder is controlled at 210-240°C (the temperature gradually rises from the feeding port to the machine head), and the continuous alkali-free glass fiber treated with the silane coupling agent is introduced from the middle opening of the twin-screw extruder. The rotation speed is 120 rpm, and the above-mentioned materials are extruded at a speed of about 12 kg / hour, cooled by water, and pelletized to obtain glass fiber reinforced products. Comparative example SANMA resin was replaced by SAN resin+ABS high rubber powder or commercially available ABS resin.

[0035] Dry the above products in a hot air oven at 85°C for 3 hours and then inject them into standard samples with a plastic injection molding machine. The injection tem...

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Abstract

The present invention relates to one kind of thermoplastic resin composition and solves the technological problems of raising the tensile strength, bending strength and compact strength of ABS resin. The present invention has technological scheme of adding styrene-acrylonitrile-maleic anhydride copolymer, antioxidant and glass fiber into ABS resin, and may be used in the industrial production of modified ABS resin.

Description

technical field [0001] The present invention relates to a thermoplastic resin composition. Background technique [0002] There are two main production methods of ABS resin: emulsion grafted ABS-SAN blending method and continuous bulk polymerization method, among which emulsion grafted ABS-SAN blending method can be divided into emulsion grafted ABS-emulsion according to the production method of SAN. SAN blending method, emulsion grafted ABS-suspension SAN blending method and emulsion grafted ABS-bulk SAN blending method, emulsion grafted ABS-bulk SAN blending method has become the most popular because of low production cost, many product brands, and stable performance. The most widely used production method at present. [0003] The ABS resin produced by the emulsion grafting ABS-SAN blending method or the continuous bulk method is styrene-acrylonitrile copolymer (SAN) and butadiene (or styrene-butadiene or nitrile) rubber-styrene-propylene The blend of nitrile graft copoly...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L25/08C08K9/06C08K7/14
Inventor 傅荣政王芳
Owner CHINA PETROLEUM & CHEM CORP