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Nano-level ultra-high heat-conducting titanium-carbon composite material and preparation method thereof

A composite material and a manufacturing method technology, which are applied in the field of nano-scale ultra-high thermal conductivity titanium-carbon composite material and its manufacturing field, can solve the problems of high price of diamonds and difficult to obtain, and achieve low production cost, enhanced physical structure strength, and simple process. Effect

Inactive Publication Date: 2011-07-20
晟茂(青岛)先进材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] At present, the representative of heat dissipation materials higher than the thermal conductivity of copper (380W / mK) and aluminum (240W / mK) is diamond, which has a thermal conductivity of up to 2000W / mK, but diamonds are expensive and difficult to obtain. The most important issue is to replace copper and aluminum. Therefore, how to increase the thermal conductivity, facilitate production and reduce costs to meet the needs of different thermal management systems has become an urgent issue to be solved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Weigh 60Kg of acidified expanded graphite with a carbon content of 90%, 20Kg of flake graphite nanopowder with a carbon content of 90%, 10Kg of titanium metal nanopowder and 10Kg of mesophase nanocarbon powder, and gradually put them into a high-temperature reaction furnace. Under the protection of gas, the temperature is gradually increased from 350°C to 500°C and mixed for 3 hours to obtain a thick high-temperature mixed carbon-making mixed liquid, and then the thick high-temperature mixed carbon-made mixed liquid is hot-molded, and the molding temperature is 450°C. The pressure is 300MPa and molded into a sheet, and finally the molded material is carbonized at 1000°C for 1 hour, and then graphitized at 3000°C for 1 hour. The resulting material has a thermal conductivity of 517W / mK and a density of 1.81g / cm 3 .

Embodiment 2

[0016] Weigh 65Kg of acidified expanded graphite with a carbon content of 92%, 10Kg of flake graphite nanopowder with a carbon content of 91%, 15Kg of titanium metal nanopowder and 10Kg of mesophase nanocarbon powder, and gradually put them into a high-temperature reaction furnace under the protection of an inert gas Gradually increase the temperature and mix at a temperature of 300°C-500°C for 2 hours to obtain a thick high-temperature mixed carbon-making mixed liquid. Then the thick carbon mixed liquid is rolled into a sheet at a rolling temperature of 400°C and a pressure of 180 MPa. Finally, the rolled material is carbonized at 900°C for 4 hours and graphitized at 2500°C for 4 hours. The resulting material has a thermal conductivity of 563W / mK and a density of 1.89g / cm 3 .

Embodiment 3

[0018] Weigh 70Kg of acidified expanded graphite with a carbon content of 90%, 15Kg of flake graphite nanopowder with a carbon content of 90%, 7Kg of titanium metal nanopowder and 8Kg of mesophase nanocarbon powder, and gradually put them into a high-temperature reaction furnace under the protection of an inert gas. Gradually heat up and mix at a temperature of 350°C-450°C for 3 hours to obtain a thick high-temperature mixed carbon-making mixed liquid, and then hot-mold the thick high-temperature mixed carbon-making mixed liquid at a molding temperature of 325°C and a pressure of 230MPa. Formed into sheets, and finally the molded material was carbonized at 920°C for 6 hours, and graphitized at 2900°C for 6 hours. The resulting material has a thermal conductivity of 610W / mK and a density of 1.93g / cm 3 .

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Abstract

The invention discloses nano-titanium carbon composite material with ultra-high thermal conductivity, which is characterized in that: the invention has the components by weight percentage: 40 - 85 percent of acidized expansive graphite, 5 - 40 percent of flake graphite nano power, 5 - 30 percent of mesophase nano carbon power and 5 - 30 percent of metal titanium nano powder. The production process is that: the four components are weighted and mixed under temperature of 300 to 500 DEG C in a high-temperature reaction furnace for 2 - 5 hours so as to obtain concentrated mixture solution used for making carbon at high temperature; the concentrated mixture experiences molding, rolling or ejaculating under pressure of 120 - 300MPa and at temperature of 300 - 500 DEG C, so as to form; then the formed material is carbonized under temperature 900 - 1000 DEG C for 1 - 12 hours, and graphitized under temperature of 2500 to 3000 DEG C for 1 - 12 hours. The invention has simple technique and low production cost; the thermal conductivity of the invention can be lifted to above 700W / mK.

Description

technical field [0001] The invention relates to a heat exchange material, in particular to a nanoscale ultra-high thermal conductivity titanium-carbon composite material and a manufacturing method thereof. Background technique [0002] With the development of more and more electronic equipment, including some electronic equipment that can increase processing speed and frequency, have smaller size and more complex power requirements, and display other technical advantages, such as electronic and electrical components and other devices such as high Microprocessors and integrated circuits in power optics can generate relatively high temperatures. However, microprocessors, integrated circuits, and other complex electronic components typically only operate efficiently within a certain temperature range, and the heat generated during the operation of these devices can not only impair their performance, but can also degrade overall system performance and reliability, and can even ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K5/14
Inventor 耿世达
Owner 晟茂(青岛)先进材料有限公司