Zirconium based amorphous alloy and manufacture method thereof

A technology of zirconium-based amorphous alloy and amorphous alloy, applied in the field of amorphous alloy and its preparation, can solve the problem of high requirements for high temperature resistance performance of casting equipment, low requirements for high temperature resistance performance of casting equipment, and high liquefaction temperature of zirconium-based amorphous alloy. problems, to achieve the requirements of improving casting conditions and equipment, low casting conditions, and the effect of reducing liquefaction temperature

Active Publication Date: 2010-11-03
BYD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The purpose of the present invention is to provide a zirconium-based amorphous alloy with a low liquefaction temperature and low requirements on the high-temperature resistance of casting equipment in order to overcome the shortcomings of the prior art that the liquefaction temperature of the zirconium-based amorphous alloy is high and the requirements for high-temperature resistance of casting equipment are high. Crystal alloy and its preparation method

Method used

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  • Zirconium based amorphous alloy and manufacture method thereof
  • Zirconium based amorphous alloy and manufacture method thereof
  • Zirconium based amorphous alloy and manufacture method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0022] The molten alloy sample was then subjected to 10 2 The cooling rate of K / s is cooled by water-cooled copper mold, and cast into an amorphous alloy sample D1 with a size of 3 mm × 10 mm × 100 mm. The composition of the amorphous alloy sample D1 is Zr 40 La 15 Ti 8 Cu 7 Ni 7 be 23 .

[0023] Example 2

[0024] This example is used to illustrate the zirconium-based amorphous alloy provided by the present invention and its preparation method.

Embodiment 2

[0026] The molten alloy sample was then subjected to 10 5The cooling rate of K / s is cooled by water-cooled copper mold, and cast into an amorphous alloy sample D2 with a size of 3 mm × 10 mm × 100 mm. The composition of the amorphous alloy sample D2 is Zr 35 La 20 Ti 7 Cu 15 Ni 8 be 15 .

[0027] Example 3

[0028] This example is used to illustrate the zirconium-based amorphous alloy provided by the present invention and its preparation method.

Embodiment 3

[0030] The molten alloy sample was then subjected to 10 3 The cooling rate of K / s is used to cool the copper mold, and cast into an amorphous alloy sample D3 with a size of 3 mm × 10 mm × 100 mm. The composition of the amorphous alloy sample D3 is Zr 35 La 10 Ce 5 Ti 7 Cu 15 Ni 8 be 20 .

[0031] Comparative example 1

[0032] Put 23 grams of amorphous alloy raw material into an electric arc melting furnace (Shenyang Scientific Instrument Factory), evacuate the electric arc melting furnace (at a pressure of 100%), use argon with a purity of 99.0% by volume as the protective gas, and melt at 2000°C For 1 minute, the amorphous alloy raw material is fully melted, and the composition of the amorphous alloy raw material is 50 mol % Zr, 7 mol % Ti, 15 mol % Cu, 8 mol % Ni and 20 mol % Be.

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Abstract

The invention provides a zirconium-based amorphous alloy. The components of the amorphous alloy adopt ZraREbTMcBed, wherein, a is larger than or equal to 30 and less than and equal to 45, b is larger than or equal to 15 and less than and equal to 25, c is larger than or equal to 15 and less than and equal to 30, d is larger than or equal to 19 and less than and equal to 25, a, b, c and d are mol percentages, and a plus b, c and d is equal to 100; RE is selected from one or more of the rare earth metals; and TM is selected from one or more metal(s) of the IB group metals, the, IIB group metals, the IVB group metals, the VB group metals, the VIIB group metals and the VIII group metals. The invention has the advantages that the liquefaction temperature (Tl) of the amorphous alloy is greatly reduced, the high temperature resistance requirements of casing devices during the amorphous alloy casting process are greatly reduced, and the production cost is also greatly reduced. In addition, the hardness, the impact toughness and the anti-bending strength of the amorphous alloy can also meet the requirements, and when the liquefaction temperature (Tl) of the amorphous alloy is greatly reduced, other properties of the amorphous alloy can also meet the requirements.

Description

technical field [0001] The invention relates to an amorphous alloy and a preparation method thereof, more specifically to a zirconium-based amorphous alloy and a preparation method thereof. Background technique [0002] Zirconium-based amorphous alloys have extremely high strength, hardness, wear resistance, corrosion resistance and high electrical resistance, and also exhibit excellent superconductivity and low magnetic loss. They are widely used in IT electronics, machinery, chemical industries and other industries. It has broad application prospects. [0003] For example, US5288344A1 discloses a zirconium-based amorphous alloy, the composition of which is: (Zr 1-x Ti x ) a1 ETM a2 (Cu 1-y Ni y ) b1 LTM b2 be c , where, x and y are atomic fractions, a1, a2, b1, b2 and c are atomic percentages, wherein ETM is at least one early transition metal selected from the group consisting of V, Nb, Hf and Cr, wherein The atomic percentage of Cr is not higher than 0.2a1; LTM...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C45/10C22C1/00B22D27/04
Inventor 李梅张法亮宫清
Owner BYD CO LTD
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