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Asphalt modifying agent and preparation thereof

A technology of asphalt modifier and modified asphalt, which is applied in the field of asphalt modifier and its preparation, can solve the problems of high operating cost, poor reaction process safety, high equipment investment cost, etc., and achieve low operating cost and reduce equipment investment , The effect of reducing operating costs

Active Publication Date: 2012-09-05
CHINA NAT OFFSHORE OIL CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The process disclosed in this patent adopts hydrogen atmosphere conditions, high operating costs, large equipment investment costs, and poor reaction process safety

Method used

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  • Asphalt modifying agent and preparation thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Embodiment 1, preparation and application of asphalt modifier

[0023] 1. Preparation of asphalt modifier

[0024] Add 1 mass part of coal and 1.5 mass parts of catalytic cracking oil slurry into the reactor, add ferrous sulfate to react, in terms of metal elements, the quality of ferrous sulfate accounts for 1% of the total mass of coal; the reaction conditions are: nitrogen The pressure was 4 MPa, and the reaction was carried out at 450° C. for 5 hours. After the light products are separated, the heavy residue is bitumen modifier, and the by-products are light oil and hydrocarbon-rich gas.

[0025] After the reaction is completed, the total mass of all products obtained is taken as 100%, including 73.2% of asphalt modifier, 23.7% of light oil and hydrocarbon-rich gas, and 3.1% of water.

[0026] 2. Application of road asphalt modifier

[0027] Grinding the asphalt modifier prepared in step 1 to a size below 5 microns. 15 parts by mass of the pulverized asphalt mod...

Embodiment 2

[0029] Embodiment 2, preparation and application of asphalt modifier

[0030] 1. Preparation of asphalt modifier

[0031] Put 0.5 parts by mass of coal and 1 part by mass of catalytic cracking oil slurry into the reactor, add molybdenum sulfide to react, and the mass of molybdenum sulfide accounts for 0.4% of the total mass of coal in terms of metal elements; the reaction conditions are: nitrogen pressure 10MPa , 400°C for 0.5 hours. After the light products are separated, the heavy residue is bitumen modifier, and the by-products are light oil and hydrocarbon-rich gas.

[0032] After the reaction is completed, the total mass of all products obtained is taken as 100%, including 62.7% of asphalt modifier, 35.8% of light oil and hydrocarbon-rich gas, and 1.5% of water.

[0033] 2. Application of asphalt modifier

[0034] Grinding the asphalt modifier prepared in step 1 to a size below 5 microns. 25 parts by mass of the pulverized asphalt modifier and 75 parts by mass of 90# ...

Embodiment 3

[0036] Embodiment 3, preparation and application of asphalt modifier

[0037] 1. Preparation of asphalt modifier

[0038] Add 1 mass part of coal and 1 mass part of catalytic cracking oil slurry into the reactor, and add pyrite to react. In terms of metal elements, the quality of pyrite accounts for 2% of the total mass of coal; the reaction conditions are: nitrogen The pressure was 8 MPa, and the reaction was carried out at 425°C for 2 hours. After the light products are separated, the heavy residue is bitumen modifier, and the by-products are light oil and hydrocarbon-rich gas.

[0039] After the reaction is completed, the total mass of all products obtained is taken as 100%, including 63.8% of asphalt modifier, 33.4% of light oil and hydrocarbon-rich gas, and 2.8% of water.

[0040] 2. Application of asphalt modifier

[0041] Grinding the asphalt modifier prepared in step 1 to a size below 5 microns. 20 parts by mass of the pulverized asphalt modifier and 80 parts by ma...

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Abstract

The invention discloses an asphalt modifier and a preparation method thereof. The preparation method of the asphalt modifier comprises the following steps: according to the parts by mass, 0.5-9 parts of coal and 1-1.5 parts of catalytic cracking slurry oil are added to a reactor, then added with a catalyst accounting for 0.01-3% of the total mass of the coal based on metallic element, and then the mixture reacts for 0.5-5 hours at the temperature of 370-450 DEG C under the condition that the pressure of inert gas is 4-15MPa, then the asphalt modifier is obtained. Compared with the technique disclosed in patent ZL 02158702.7, the technique of the invention uses the pressure of the inert gas to replace hydrogen pressure, and has the advantages of low device investment, low operating cost and high safety coefficient; meanwhile, the asphalt modifier of the invention has no obvious performance difference compared with the existing asphalt modifier.

Description

technical field [0001] The invention relates to an asphalt modifier and a preparation method thereof. Background technique [0002] Modern traffic has higher and higher requirements for road quality, and road asphalt needs to be modified to meet the requirements of building high-grade roads. Natural asphalt (TLA) produced in Trinidad Lake in South America is recognized as a high-quality road petroleum asphalt modifier. It is used in all countries in the world, mostly for important traffic road surfaces, but the import price is expensive, and the use of products in my country is restricted. [0003] At present, there are few substitutes for TLA modifiers in China. Patent ZL02158702.7 discloses a process in which coal and catalytic cracking oil slurry are treated in a hydrogen atmosphere (5-14MPa) at 370-450°C for 0.5-5 hours, and asphalt modified with a modification effect comparable to TLA can be obtained. The performance of the product can meet the requirements of the Ame...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B24/00
Inventor 张玉贞杨建丽刘延军
Owner CHINA NAT OFFSHORE OIL CORP