Non-aqueous electrolyte secondary battery and producing method of electrode
A non-aqueous electrolyte and secondary battery technology, applied in non-aqueous electrolyte battery electrodes, electrolyte battery manufacturing, non-aqueous electrolyte batteries, etc., can solve problems such as unfavorable metal particles, mixing into batteries, and unfavorable return of active materials to electrodes
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no. 1 approach
[0025] (1-1) Structure of secondary battery
[0026] figure 1 is a sectional view showing a structural example of the nonaqueous electrolyte secondary battery according to the first embodiment of the present invention. This nonaqueous electrolyte secondary battery is of a so-called cylindrical type, and has a spirally wound electrode body 20 in a substantially hollow cylindrical battery case 11 . The spirally wound electrode body 20 includes a strip-shaped positive electrode 21 , a strip-shaped negative electrode 22 , and a separator 23 disposed between the positive electrode and the negative electrode, wherein they are spirally wound together. A porous protective film is formed on one or both of the surface of the positive electrode and the surface of the negative electrode. The separator 23 is impregnated with an electrolytic solution as an electrolyte. The battery can 11 is made of, for example, iron (Fe) plated with nickel (Ni), and has one closed end and the other open...
no. 2 approach
[0066] (2-1) Structure of secondary battery
[0067] Figure 4 is a perspective view showing a structural example of a nonaqueous electrolyte secondary battery according to a second embodiment of the present invention. In this nonaqueous electrolyte secondary battery, a spirally wound electrode body 30 on which a positive electrode lead 31 and a negative electrode lead 32 are mounted is housed in a film-like package 40 . Therefore, the size, weight, and thickness of the battery can be easily reduced.
[0068] The positive electrode lead 31 and the negative electrode lead 32 are electrically drawn out in the same direction from the inside to the outside of the package 40 , for example. Both the cathode lead 31 and the anode lead 32 are composed of a metal material such as aluminum (Al), copper (Cu), nickel (Ni) or stainless steel, and are in the form of a thin plate or mesh.
[0069] The package 40 is composed of, for example, a rectangular aluminum laminated film in which a...
Embodiment 1~7
[0083] First, a negative electrode was prepared as follows. 98 parts by mass of soft graphite as a negative electrode active material and 2 parts by mass of styrene-butadiene rubber (SBR) as a binder were mixed together to prepare a negative electrode mixture. The obtained negative electrode mixture was dispersed in ion-exchanged water as a solvent to prepare negative electrode mixture slurry. Next, this anode mixture slurry was applied to both surfaces of a strip-shaped copper foil having a thickness of 8 μm as an anode current collector and dried. Then, the negative electrode active material layer thus formed was press-molded by means of a press to prepare a belt-shaped negative electrode.
[0084] Next, alumina powder having an average particle diameter of about 0.3 μm, PVdF as a binder, lithium dodecyl sulfate as a surfactant, and N-methylpyrrolidone as a solvent were mixed together to obtain Microparticle slurries with viscosities in the range of 0.1 Pa·sec to 3.5 Pa·se...
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Abstract
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