Main compounds in cathode electrochromic material and electrochromic component thereof
An electrochromic material and electrochromic technology, which can be used in color-changing fluorescent materials, chemical instruments and methods, optics, etc., can solve the problems of high cost and limited use fields, and achieve the effect of cost reduction and easy synthesis.
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[0041] Below in conjunction with embodiment the present invention is described in further detail.
[0042] Synthesis of color-changing material and preparation of its solution
[0043] 1) Reflux 1.56g (0.01mol) 4,4'-bipyridine and 4.06g (0.02mol) 2,4-dinitrochlorobenzene in 30ml acetonitrile for 24 hours, then cool, filter under vacuum, and dry The resulting solid gave 1-(2,4-dinitrophenyl)-4,4'-bipyridinium chloride (3.82 g). Then 1,1-bis(2,4-dinitrophenyl)-4,4'-bipyridinium chloride (1.46g, 0.004mol) and p-methoxyaniline (0.492g, 0.004mol) in Reflux in ethanol (30ml) for 6 hours, cool, remove ethanol in vacuo, add water (50ml) and stir. The precipitate was filtered, the filtrate was decolorized with activated carbon, and dried in vacuo to give the crude product 1,1-di-p-methoxyphenyl-4,4'-bipyridinium chloride salt, which was recrystallized to give the pure crystalline product (0.98 g) .
[0044] Take out 0.5 g of the obtained product, 1 g of the compound of general stru...
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