Garlic processing
A technology of adding allicin and sulfur, which is used as a crop protection agent and therapeutic preparation, in the field of concentration and spectrum of polysulfides, and can solve problems such as complex chemical synthesis
Active Publication Date: 2012-12-12
ECOSPRAY LTD
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Moreover, the chemical synthesis of these compounds is complex and involves the handling of important hazardous substances
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[0017] As an illustration of various embodiments of the present invention, an example of a method of processing the polysulfide composition of a garlic extract will be described:
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Diallylic polysulfides (polysulfanes) are provided with sulfur chain lengths of 9 to 22. Also provided are bis(2-methyl-2-propenyl) polysulfides with sulfur chain lengths of 3 to 22. Also provided are 2-substituted bis(2-propenyl) polysulfides with sulfur chain lengths of 3 to 20. Also provided are the 2-cycloalken-1-yl polysulfides, 2-cyclohexen-1-yl polysulfides and 2-cyclopenten-1-yl polysulfides, with sulfur chain lengths of 3 to 20. Also provided are processes for extending the sulfur chain length of diallylic polysulfides and 2-substituted analogues thereof and allyl methyl polysulfides by bringing such compounds into contact with elemental sulfur and heating, or by mixing with molten sulfur.
Description
technical field [0001] The present invention relates to a method of processing extracts from the genus Allium, especially garlic, to manipulate the concentration and spectrum of polysulfides contained therein. The invention also relates to the products thus prepared and their industrial use, in particular as crop protection and therapeutic preparations. Background technique [0002] Alliums, particularly garlic, have evolved to use various sulfur-containing molecules as defense agents against tissue damage by microorganisms and feeding damage by herbivores. The main chemical defense of the garlic plant requires the conversion of alliin, a sulfur-containing plant component, by allinase. The result of this interaction is the release of allicin, an unstable biologically active molecule comprising two sulfur molecules. Allicin is sequentially converted to further reduced forms of sulfur, such as polysulfides with methyl or allyl functional groups attached to both ends of the s...
Claims
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IPC IPC(8): C07C319/24C07C321/18
Inventor 埃里克·布洛克默里·格鲁姆
Owner ECOSPRAY LTD
