Graffiti-proof and easy-cleaning acrylate flatting agent modified by fluorine and silicon and production method thereof
An acrylate, fluorosilicon modification technology, applied in the direction of coating, can solve the problems of no anti-graffiti and easy cleaning functions, limited use range, etc., to achieve the effect of improving hydrophobicity and oleophobicity and reducing production costs
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[0019] First, 15-60% by weight (eg 25%, 45%, 65%) of solvent propylene glycol methyl ether (or butyl acetate or propylene glycol methyl ether acetate) is poured into the reactor, and the temperature is raised to 115-150 ° C, and the solvent Reflux 30 minutes; Simultaneously the acrylate monomer lauryl methacrylate (or stearyl methacrylate or butyl acrylate or isooctyl acrylate of 5-30% (example 5%, 15%, 30%) weight percent ), 1-15% (1%, 5%, 15%) by weight of fluoroacrylate monomer nonadecafluoroheptyl acrylate (or trifluorobutyl acrylate or dodecafluoroheptyl methacrylate or hexafluorobutyl acrylate ester or perfluoroalkyl acrylate), 20-70% (eg 20%, 50%, 70%) weight percentage of silicone monomer (Dow Corning products, such as: Dow Coming32#, 6502#, 81#) and After the initiator benzoyl peroxide (or azobisisobutyronitrile) of 0.5-20% (eg 0.5%, 10%, 20%) by weight is mixed uniformly, at a temperature of 115-150° C., 3-5 Add dropwise to the reaction kettle within 1 hour to carry...
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