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Antistatic film, polyester film for surface-protecting film, and polyester film for protecting surface of optical member

A surface protective film, anti-static technology, applied in chemical instruments and methods, coatings, layered products, etc., can solve the problems of surface layer damage, inspection obstacles, and lack of durability of protective films, and achieve high industrial value. , excellent antistatic properties and durability, the effect of excellent characteristics

Active Publication Date: 2012-07-18
MITSUBISHI CHEM CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, for the surface protection film, the appearance that does not hinder the inspection is required, so there is also a problem when using such a compound
[0010] In addition, in the processing process of optical components, due to contact with processing machines or conveying rollers, etc., scratches are generated on the surface layer of the protective film, which hinders inspection. Therefore, it is necessary to have durability against this.
However, most of the existing antistatic resins do not have sufficient durability

Method used

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  • Antistatic film, polyester film for surface-protecting film, and polyester film for protecting surface of optical member
  • Antistatic film, polyester film for surface-protecting film, and polyester film for protecting surface of optical member
  • Antistatic film, polyester film for surface-protecting film, and polyester film for protecting surface of optical member

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0115] Polyester 1 and polyester 2 are mixed in a weight ratio of 80 / 20. After they are fully dried, they are heated and melted at 280-300°C. They are extruded from a T-shaped tube head into a sheet shape and adhered to each other by electrostatic adhesion. On a mirror-surface cooling drum with a surface temperature of 40-50°C, cooling and solidification were performed to form an unstretched polyethylene terephthalate film. The film was stretched 3.7 times in the longitudinal direction while passing through a heating roll group at 85°C to obtain a uniaxially oriented film. The coating composition shown in Table 1 below was applied to one side of the uniaxially oriented film. Next, the film was introduced into a tenter stretcher, and the coating composition was stretched 4.0 times in the width direction at 100°C while drying the coating composition with its heat, and then heat-treated at 230°C to obtain a double film with a thickness of 38μm. 0.03g / m on the axis-oriented polyet...

Embodiment 2~6

[0117] In the same process as in Example 1, the coating liquid was changed as shown in Table 1 to obtain a coating film in which an antistatic coating layer of the amount shown in Table 1 was laminated on a base film having a film thickness of 38 μm. Table 2 shows the characteristics of the film.

Embodiment 7

[0126] Polyester 1 and polyester 2 are mixed in a weight ratio of 80 / 20. After they are fully dried, they are heated and melted at 280-300°C. They are extruded from a T-shaped tube head into a sheet shape and adhered to each other by electrostatic adhesion. On a mirror-surface cooling drum with a surface temperature of 40-50°C, cooling and solidification were performed to form an unstretched polyethylene terephthalate film. The film was stretched 3.7 times in the longitudinal direction while passing through a heating roll group at 85°C to obtain a uniaxially oriented film. The coating composition shown in Table 3 below was applied to one side of the uniaxially oriented film. Next, the film was introduced into a tenter stretcher, and the coating composition was stretched 4.0 times in the width direction at 100°C while drying the coating composition with its heat, and then heat-treated at 230°C to obtain a double film with a thickness of 38μm. 0.03g / m on the axis-oriented polyet...

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Abstract

An antistatic film excellent in antistatic properties, water resistance, and durability. The antistatic film is characterized by comprising a polyester film and, formed on one side thereof, a coating layer comprising an antistatic polymer having constituent elements represented by the following structural formulae (1) and (2) as repeating units. (In the formula, R<1> and R<2> each independently is hydrogen or C1-3 alkyl, and X<-> is a monovalent anion).

Description

Technical field [0001] The present invention relates to an antistatic film. In more detail, the present invention relates to an antistatic polyester film having excellent antistatic performance and excellent water resistance. The present invention also relates to a film suitable as a surface protective film of a polarizing plate, a retardation plate, or a viewing angle widening film, and relates to a film that is less charged during rubbing or peeling and has an excellent appearance. Background technique [0002] Polyester films represented by polyethylene terephthalate or polyethylene naphthalate are excellent in mechanical strength, dimensional stability, flatness, heat resistance, chemical resistance, and optical properties. It is also excellent in cost performance, so it is used as a substrate in various applications such as platemaking films, packaging films, and optical films. [0003] However, the common problem of plastic films is that they tend to generate static electri...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08J7/04B32B27/36
Inventor 神田俊宏藤田真人
Owner MITSUBISHI CHEM CORP