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Biodegradable anti-static macromolecule composite material and preparation method of the same

A technology of biodegradation and composite materials, which is applied in the field of antistatic polymer composite materials and their preparation, and polymer composite materials, can solve the problems of not having the advantages of general promotion, narrow application range, and inability to produce large-scale production, and achieve good results. Anti-static performance and mechanical properties, good molding performance, suitable for industrial production

Inactive Publication Date: 2012-03-28
WUHAN HUALI ENVIRONMENT PROTECTION SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some existing heat-resistant polylactic acid and other biomass plastics are expensive, do not have the advantages of daily application, and cannot be mass-produced
Patent CN101967271A discloses a short carbon fiber reinforced antistatic polylactic acid composite material, which is prepared by mixing polylactic acid, short carbon fiber, coupling agent, antioxidant, and lubricant in proportion, and then pelletizing short carbon fiber through twin-screw melt extrusion Strengthen the antistatic polylactic acid composite material, so that polylactic acid has antistatic properties, but due to the high price of polylactic acid as a matrix material, it does not have the advantage of general promotion
Patent CN1013128301A discloses a polylactic acid multilayer film composed of a base layer and at least one covering layer composed of aliphatic hydroxycarboxylic acid, wherein the covering layer contains starch-based particles in a weight ratio of 0.002 to 20 by weight of the covering layer, Although the polylactic acid multilayer film has good antistatic properties, as a film, it cannot be formed by injection molding, hot pressing, etc., and cannot be prepared into products such as food trays, electromagnetic trays, medical trays, cutlery, and spoons, and its application range is narrow.

Method used

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  • Biodegradable anti-static macromolecule composite material and preparation method of the same
  • Biodegradable anti-static macromolecule composite material and preparation method of the same

Examples

Experimental program
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Effect test

Embodiment 1

[0032] 1) Mix tapioca starch, 10% by weight relative to tapioca starch, and 10% NaOH solution in a beaker, then move the mixed material into a reaction flask, and install the flask into a MAS-I atmospheric pressure microwave In the auxiliary synthesis reactor, after stirring at 75°C and 250r / min for 3 minutes, add 3% acetic anhydride relative to the weight of tapioca starch into the separatory funnel, keep the temperature and rotation speed constant, and carry out the esterification reaction inside. After the end, wash the reaction product repeatedly with distilled water to pH 6-7. After cooling down and discharging the material, dry it at room temperature to constant weight. Grind the dried sample into powder to obtain modified tapioca starch for use (in this step, react The temperature should not be too high or too low, the side reaction will be accelerated if the temperature is too high, and the starch esterification reaction will be insufficient if the temperature is too lo...

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Abstract

The invention relates to a biodegradable anti-static macromolecule composite material which is prepared by mixing the following components by weight: 20-80% of polylactic acid; 10-70% of modified starch; 1-10% of anti-static agent; 1-5% of plasticizer and 1-5% compatilizer. The biodegradable anti-static macromolecule composite material achieves surface resistance of being lower than or equal to 106 ohm, tensile strength of 20-35Mpa and breaking elongation percent of 10-20% and has excellent anti-static and mechanical properties; simultaneously the biodegradable anti-static macromolecule composite material has good environmental degradation property and after 12-week composting, the biological decomposition is above 90%; and the forming processing property is remarkable, therefore the biodegradable anti-static macromolecule composite material can form various products by methods of extrusion, injection molding, hot pressing and the like on processing equipment of common plastics.

Description

technical field [0001] The invention relates to a biodegradable polymer composite material, in particular to a biodegradable antistatic polymer composite material and a preparation method thereof, belonging to the technical field of polymer materials. Background technique [0002] Plastic packaging materials are widely used in the fields of food, electronics, aerospace, weapons industry, and textiles. In daily life and production, many plastic packaging materials are prone to static electricity accumulation during use, causing vicious accidents such as vacuuming, electric shock, and even explosion after sparks are generated. At present, the most common and effective method is to use antistatic agent to reduce the surface resistivity of the material, so that it has been widely used. [0003] However, the main components of traditional anti-static plastic packaging materials are generally petroleum-based polymer materials, such as polyolefin, polyvinyl chloride, polystyrene, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L3/06C08L51/00C08L71/02C08K5/521C08K5/05C08K3/22C08K3/36C08K7/24C08B31/04
Inventor 王淑敏张立斌危伟白娟
Owner WUHAN HUALI ENVIRONMENT PROTECTION SCI & TECH
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