Method for preparing viscosity depressant for drilling fluid

A technology of viscosity reducer and drilling fluid, which is applied in the field of preparation of a viscosity reducer, can solve the problems of rare successful application cases, stagnation of research work, and less research, and achieve good application effect and environmental protection effect. The effect of low cost and simple synthetic route

Active Publication Date: 2010-06-02
北京奥凯立科技发展股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, after the 1990s, due to the strengthening of environmental protection awareness in various countries around the world, the application of FCLS, which seriously pollutes the human body and the environment, was restricted. People began to develop chromium-free lignosulfonate and tannin-based viscosity reducers.
Afterwards, research mainly focused on anionic polymer viscosity reducers based on maleic anhydride (MA), sodium allylsulfonate (AS) and 2-acrylamido-2-methylpropanesulfonic acid (AMPS) , and zwitterionic polymer viscosity reducers with cationic groups, but there are relatively few studies, especially in recent years, the research work in this area has almost stagnated, and there are even fewer examples of successful field applications, and there is a lack of applicable Viscosity reducer under special conditions (such as ultra-high temperature, anti-saturated brine, etc.)

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Dissolve 600g of calcium lignosulfonate in 1200g of water, add a 20% sulfuric acid solution to adjust the pH to 6, and heat the solution to 70°C. Add 300g ferrous sulfate in solution then, react 2 hours. Then the solution was heated up to 80°C, 90g of AMPS and 0.27g of potassium persulfate were added under the condition of stirring, and the reaction was carried out for 2 hours. After the reaction, the solution was dried and pulverized at 100°C to obtain the product. The viscosity reduction rate is 90% at 190°C, and the viscosity reduction rate in saturated saline is 85%.

Embodiment 2

[0022] The difference from Example 1 is that ferrous sulfate, AMPS and initiator are added together to the solution of lignosulfonate for reaction. specifically is:

[0023] Dissolve 600g of calcium lignosulfonate in 2400g of water, add 20% sulfuric acid solution to adjust the pH value to 7, and heat up the solution to 80°C. Add 300g ferrous sulfate, 90g AMPS, 0.27g potassium persulfate to the solution, and react for 2 hours. After the reaction, the solution was dried and pulverized at 100°C to obtain the product. The viscosity reduction rate is 85% at 195°C, and the viscosity reduction rate in saturated saline is 90%.

[0024] The specific parameters of preparing drilling fluid viscosity reducer in other embodiments are shown in the following table:

[0025] Reality

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PUM

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Abstract

The invention discloses a method for preparing a viscosity depressant for a drilling fluid, comprising the following steps of: mixing lignosulphonate and water in the mass ratio of 1: (1.5-4) to obtain a solution A and adjusting the pH value of the solution A to be 6-7; (2) adding ferrous sulphate into the mixture obtained in the step (1) and reacting for 1-4 hours at 60-80 DEG C; (3) heating themixture obtained in the step (2) to 60-90 DEG C and then adding an organic monomer AMPS and an evocating agent and reacting for 1-4 hours; and (4) drying and crushing the mixture obtained in the step(3) at 80-100 DEG C to obtain the viscosity depressant for the drilling fluid, wherein the mass ratio of the lignosulphonate to the ferrous sulphate to the organic monomer AMPS to the evocating agentis 1:(0.3-0.5):(0.1-0.15):(0.01-0.02). The prepared viscosity depressant is suitable for drilling fluids under the conditions of extraordinarily high temperature and antisaturation saline water.

Description

technical field [0001] The invention relates to a preparation method of a viscosity reducer for drilling fluid, in particular to a preparation method of a viscosity reducer added to drilling fluid used in oil exploration and drilling. Background technique [0002] With the increase of world energy demand and the development of drilling technology, the number of deep wells and ultra-deep wells in my country is also increasing. During drilling, the deeper the wellbore, the higher the temperature inside the wellbore. Due to the automatic dispersion of clay particles in drilling fluid under high temperature conditions, the particle concentration increases and the specific surface area increases. The problem of high temperature thickening of drilling fluid becomes more and more prominent. The viscosity reducer is one of the indispensable drilling fluid treatment agents in the drilling process, and it plays a very important role in adjusting the rheology of the drilling fluid. A...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/035
Inventor 卢甲举王铁林顾新波卢艳丽张亮亮张洪奎王文瑞
Owner 北京奥凯立科技发展股份有限公司
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