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High negative potential magnesium base alloy sacrificial anode material and application thereof

A sacrificial anode, magnesium-based alloy technology, applied in the field of magnesium alloy materials, can solve the problems of narrow application range, difficult to exceed 55%, open circuit potential and closed circuit potential are not negative enough, etc., to achieve a wide range of effects

Active Publication Date: 2012-04-04
SHANDONG DERUI ANTI-CORROSION MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the downside is that their current efficiency is low, only about 50%
[0005] 1. The open circuit potential and closed circuit potential are not negative enough,
[0006] 2. The current efficiency is low, it is difficult to exceed 55%, and it has not been reported that it is greater than 60%
[0007] 3. Narrow scope of application

Method used

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  • High negative potential magnesium base alloy sacrificial anode material and application thereof
  • High negative potential magnesium base alloy sacrificial anode material and application thereof
  • High negative potential magnesium base alloy sacrificial anode material and application thereof

Examples

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Effect test

Embodiment 1

[0038] In 100 parts by weight of the high negative potential magnesium-based alloy sacrificial anode material of the present invention, it contains 0.85 parts by weight of Mn, 0.12 parts by weight of Ga, 0.008 parts by weight of Al, Fe≤0.01 parts by weight, Cu≤0.01 parts by weight, and Ni≤0.001 parts by weight parts, Si≤parts by weight, and the balance is magnesium. A high negative potential magnesium-based alloy sacrificial anode manufactured by a rapid water-cooled casting process. Install and use in a water heater at 60-100 degrees Celsius. After testing, the protection effect is very good, there is no potential drop or even reversal phenomenon, and there is no intergranular corrosion and grain shedding phenomenon, the anode corrosion is uniform, the corrosion product is loose, and can fall off automatically. The product sample has been extended to the field of heat exchange equipment.

Embodiment 2

[0040] In 100 parts by weight of the high negative potential magnesium-based alloy sacrificial anode material of the present invention, it contains 1.2 parts by weight of Mn, 0.14 parts by weight of Ga, 0.007 parts by weight of Al, Fe≤0.01 parts by weight, Cu≤0.01 parts by weight, and Ni≤0.001 parts by weight parts, SiO≤0.05 parts by weight, and the balance is magnesium. A high negative potential magnesium-based alloy sacrificial anode manufactured by a rapid water-cooled casting process. It is installed and used in boilers above 100 degrees Celsius. After testing, the protection effect is very good, there is no potential drop or even reversal phenomenon, and there is no intergranular corrosion and grain shedding phenomenon, the anode corrosion is uniform, the corrosion product is loose, and can fall off automatically.

Embodiment 3

[0042] In 100 parts by weight of the high negative potential magnesium-based alloy sacrificial anode material of the present invention, it contains 1.2 parts by weight of Mn, 0.12 parts by weight of Ga, 0.007 parts by weight of Al, Fe≤0.005 parts by weight, Cu≤0.01 parts by weight, and Ni≤0.001 parts by weight parts, SiO≤0.05 parts by weight, and the balance is magnesium. A high negative potential magnesium-based alloy sacrificial anode block manufactured by a rapid water-cooled casting process. In the soil with high resistivity, installing the high negative potential magnesium-based alloy sacrificial anode block to protect the tap water pipeline has a good effect.

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Abstract

The invention discloses a high negative potential magnesium base alloy sacrificial anode material and application thereof, and belongs to magnesium alloy materials for sacrificial anodes. The high negative potential magnesium base alloy sacrificial anode material is characterized in that: 100 weight parts of sacrificial anode material comprises the following metal element components in part by weight: 0.50 to 1.3 parts of Mn, 0.01 to 0.2 part of Ga, less than or equal to 0.01 part of Al, less than or equal to 0.01 part of Fe, less than or equal to 0.01 part of Cu, less than or equal to 0.001 part of Ni, less than or equal to 0.05 part of Si and the balance of Mg. The invention provides the high negative potential magnesium base alloy sacrificial anode material, which has enough negative and stable open circuit potential and closed circuit potential, high current efficiency and wide application range. The open circuit potential is -1.82 to -1.85V, the closed circuit potential is -1.75 to -1.76V, the current efficiency is over 55 percent and reaches 65 percent, and the actual electric capacity is more than 1,285A.h / kg. The sacrificial anode material is widely used for manufacturing anode protecting sacrificial anodes of metal pipes for supplying water, gas, natural gas and heat, ships, offshore drilling platforms, docks and harbors, crossing sea bridges, pipelines under the ocean, water heaters, steam boilers and heat exchanges in petrochemical industry and pharmacy.

Description

technical field [0001] The invention relates to a high negative potential magnesium-based alloy sacrificial anode material and its application, which belongs to the corrosion inhibition of metal materials, and particularly relates to a magnesium alloy material used for a sacrificial anode. Background technique [0002] The chemical corrosion of metal materials, especially iron and steel materials, not only causes a serious waste of resources, but also poses a threat to the environment on which human beings depend. Cathodic protection is implemented on metal components by sacrificial anodes to slow down the corrosion rate of metal materials. It is a metal corrosion inhibition method widely used in recent years. [0003] Metal magnesium has high chemical activity, low electrode potential and high driving voltage. Moreover, in the aqueous medium, the microscopic corrosion potential driving force on the surface of metal magnesium is large, the protective film is easy to dissol...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F13/14C22C23/00
Inventor 逯纪德赵尊生逯彦伟逯彦国逯彦军
Owner SHANDONG DERUI ANTI-CORROSION MATERIAL CO LTD
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