Anticorrosive nanometer aqueous architectural coating and preparation method thereof
A water-based paint, nano-pigment technology, applied in anti-corrosion paint, coating and other directions, to achieve the effect of strong corrosion resistance, smooth coating, easy to use
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Embodiment 1
[0012] 1. Preparation of modified nano-zirconia
[0013] And the modified nano zirconium dioxide is prepared by the following method: Weigh 10g of zirconium carbonate, add excess sulfuric acid and stir to obtain zirconium sulfate; prepare 1N ammonium bicarbonate solution, add dropwise to zirconium sulfate at a speed of 10-15ml / min solution; keep stirring until the precipitation is complete, after standing still, filter with suction, wash, then extract with absolute ethanol, dry the obtained solid, then burn at a high temperature above 350°C, cool and grind, after measurement, more than 90% The particle size of the particles is less than 100nm to obtain nano zirconium dioxide; put 10g of the above-prepared nano zirconium dioxide in 300mL of absolute ethanol, stir and reflux for 30min, stop the reflux, keep the temperature at 70°C, add stearic acid, and continue stirring 1h, cooling, filtering and drying to obtain modified nano zirconia.
[0014] 2. Preparation of Coatings
[...
Embodiment 2
[0017] 1. Preparation of modified nano-zirconia
[0018] Preparation method is the same as above embodiment 1
[0019] 2. Preparation of Coatings
[0020] Take each raw material according to the following weight ratio: modified nano-zirconia 55, water 30, water-soluble acrylic resin 40, commercially available P-1001, commercially available PS-6302, polyurethane 5, commercially available Sell DH-1700
[0021] 3. Hydroxypropyl methylcellulose 1, commercially available DH-3040.5, commercially available SPG-100.2, titanate 5, AMP-950.15; modified nano-zirconia, water-soluble acrylic resin, P-100, DH -304 and stir evenly, then add water, PS-630, polyurethane, DH-1700, hydroxypropyl methylcellulose, SPG-10 and titanate, stir again, and then emulsify for 30 minutes using a high-speed shear emulsifier , and finally add AMP-95 and stir evenly.
Embodiment 3
[0023] 1. Preparation of modified nano-zirconia
[0024] Preparation method is the same as above embodiment 1
[0025] 2. Preparation of Coatings
[0026] Take each raw material according to the following weight ratio: modified nano-zirconia 35, water 10, water-soluble acrylic resin 25, commercially available P-1000.05, commercially available PS-6300.5, polyurethane 3, commercially available Selling DH-17002, hydroxypropyl methylcellulose 0.5, commercially available DH-3040.1, commercially available SPG-100.01, titanate 3, AMP-950.05; modified nano zirconium dioxide, water-soluble acrylic resin, P- 100. Stir DH-304 evenly, then add water, PS-630, polyurethane, DH-1700, hydroxypropyl methylcellulose, SPG-10 and titanate, stir evenly again, and then use a high-speed shear emulsifier, Emulsify for 30 minutes, finally add AMP-95 and stir evenly.
[0027] The anti-corrosion nano water-based paint of the present invention has the following advantages: all water-soluble components...
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