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Heavy oil suspension bed hydro-upgrading method

A hydro-upgrading and suspended-bed technology, which is used in hydrocarbon oil cracking, petroleum industry, etc., to reduce operating costs, increase yield, and ensure the effect of hydrogenation.

Inactive Publication Date: 2011-01-12
FUSHUN RES INST OF PETROLEUM & PETROCHEMICALS SINOPEC CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the deficiencies of the prior art, the present invention provides a heavy oil suspension bed hydrogenation upgrading method, the method of the present invention overcomes the gap between catalyst dispersion and hydrogenation effect, preparation and cost brought by the existing suspension bed conventional catalyst usage method Contradictory problems, a new combination of dispersed catalysts is proposed, which can simplify the operation process and reduce costs as much as possible while achieving ideal dispersion effects and hydrogenation effects

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A certain amount of molybdenum naphthenate is directly added in the heavy oil raw material, then adopts the mode of magnetic stirring, catalyst is dispersed in the heavy oil raw material (main properties see table 1); Metal weight calculation) aqueous solution of nickel phosphomolybdate, surfactant Tween-85 and co-surfactant n-hexanol are fully mixed and then added to the above-mentioned heavy oil raw material, and the catalyst aqueous solution is uniformly dispersed in the heavy oil by high-shear stirring method In the raw material, the obtained mixed raw material is then mixed with hydrogen into a high-temperature and high-pressure reactor for hydrogenation reaction. After the reaction, the product is distilled under normal pressure to obtain gasoline fraction, diesel fraction and hydrogenated tail oil. The operating conditions and test results are listed in the table. 2 and Table 3.

Embodiment 2~4

[0030] According to the process described in Example 1, using the conditions described in Table 4, the reaction results are shown in Table 5.

[0031] Table 1 Properties of heavy oil raw materials

[0032]

[0033]Table 2 Embodiment 1 and comparative example operating conditions

[0034]

[0035] Table 3 embodiment 1 and comparative example test result

[0036]

[0037] Table 4 Embodiment 2~4 operating conditions

[0038]

[0039] Table 5 Example 2~4 test results

[0040]

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Abstract

The invention discloses a heavy oil suspension bed hydro-upgrading method, in particular to a suspension bed heavy oil hydro-upgrading technology of a dispersive catalyst. The method comprises the following steps: firstly dispersing the dispersive oil-soluble catalyst into the heavy oil raw material, then mixing the dispersive water-soluble catalyst with emulsifier, adding the mixture to the heavy oil raw material, mixing the raw material containing the catalyst with hydrogen and then feeding into a suspension bed hydrogenation reactor; and performing hydrocracking reaction under the reaction condition. In the process of the method of the invention, the catalyst can be evenly dispersed in the heavy oil raw material, so that alkane, aromatic hydrocarbon, colloid and asphaltene which form the heavy oil, can fully contact with the catalyst, thereby improving effects of the hydro-upgrading reaction, inhibiting coke generation, and enhancing yield of middle distillate.

Description

technical field [0001] The invention relates to a heavy oil suspension bed hydrogenation upgrading method, in particular to a suspension bed hydrogenation upgrading method for processing low-quality heavy oil raw materials with a dispersed catalyst. Background technique [0002] Suspension bed hydrogenation is an important chemical reaction process, which has broad application prospects in petroleum processing and chemical industry, especially in the process of lightening heavy oil, suspension bed hydrogenation technology has unique advantages. In the suspension bed hydrogenation process, the dispersion of the catalyst in the heavy oil is particularly important. If the catalyst can be evenly and stably distributed in the feedstock oil and fully contact with the components that make up the heavy oil feedstock, the effective contact area between the feedstock oil and the catalyst can be increased. Give full play to the hydrogenation activity of the catalyst and suppress the fo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G47/02
Inventor 贾丽刘建锟胡长禄
Owner FUSHUN RES INST OF PETROLEUM & PETROCHEMICALS SINOPEC CORP
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