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Preparation method of calamine cellulose fiber

A cellulose fiber, calamine technology, applied in the direction of rayon, single-component cellulose rayon, fiber processing and other directions in cellulose solution, can solve the problem of reducing the content of calamine in the finished fiber and affecting the acid bath. The content of zinc sulfate in the middle, the loss of active ingredients of calamine, etc., can improve the spinnability, improve the functional index, and avoid damage.

Active Publication Date: 2012-03-28
潍坊欣龙生物材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the disclosed patents and documents all produce viscose fiber by directly adding micron-sized calamine powder into the viscose liquid. The bath is generally a mixture of sulfuric acid, sodium sulfate, and zinc sulfate, because the active ingredients of calamine are zinc carbonate and its oxides, and zinc carbonate and oxides react with sulfuric acid to eventually form zinc sulfate, which causes the loss of active ingredients of calamine , so as to reduce the content of calamine in the finished fiber. In addition, the operator will work in an acidic environment for a long time, which will cause harm to the body; It affects the content of zinc sulfate in the acid bath. In the actual forming reaction, how much calamine produces zinc sulfate is unknown and cannot be quantified. It affects the deployment of zinc sulfate in the acid bath. will pollute the environment

Method used

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  • Preparation method of calamine cellulose fiber

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Embodiment 1: the preparation method of calamine cellulose fiber, comprises the following steps:

[0030] (1) calamine slurry preparation process: get the calamine that particle diameter is 125nm, add relative calamine weight and be 0.3% dispersant dialkyl dimethyl ammonium chloride and relative calamine in calamine weight Calamine weight is the dispersant polysiloxane quaternary ammonium salt of 0.5%, adds deionized water again, is configured into the calamine slurry that weight percentage concentration is 25%, puts calamine slurry in ball mill, ball milling 100min to make uniform nano calamine slurry;

[0031] (2) Preparation process of spinning stock solution: pulverize cotton pulp with a degree of polymerization of 330 and then mix it evenly with 1-allyl, 3-methylclomidazolium salt solution, dissolve at 90°C to form a uniform and stable spinning stock solution , the concentration by weight of cellulose in the spinning dope is 5%;

[0032] (3) Preparation process o...

Embodiment 2

[0038] Embodiment 2: the preparation method of calamine cellulose fiber, comprises the following steps:

[0039] (1) calamine slurry preparation process: get the calamine that particle diameter is 80nm, add relative calamine weight and be 0.5% dispersant dialkyl dimethyl ammonium chloride and relative calamine in calamine weight Calamine weight is 1.5% dispersant sodium tripolyphosphate, then add deionized water to configure calamine slurry with a concentration of 22% by weight, put the calamine slurry in a ball mill, and ball mill for 120min to make Uniform nano calamine slurry;

[0040] (2) Spinning stock solution preparation process: the wood pulp with a degree of polymerization of about 800 and the cotton pulp with a degree of polymerization of 700 are mixed and pulverized at a weight ratio of 1:3, and then mixed with 1-butyl, 3-methylclomidazolium salt solution Mix evenly, dissolve at 110°C to form a uniform and stable spinning stock solution, and the concentration of ce...

Embodiment 3

[0047] Embodiment 3: the preparation method of calamine cellulose fiber, comprises the following steps:

[0048] (1) calamine slurry preparation process: get the calamine that particle diameter is 160nm, add relative calamine weight to be 0.6% dispersant polyalkyl trimethyl ammonium chloride and relative calamine in calamine weight Calamine weight is 0.9% dispersant sodium tripolyphosphate, and then add deionized water to configure calamine slurry with a concentration of 26% by weight, put the calamine slurry in a ball mill, and ball mill for 100 minutes to prepare Uniform nano calamine slurry;

[0049] (2) Spinning dope preparation process: the wood pulp with a degree of polymerization of 1000 and the bamboo pulp with a degree of polymerization of 900 are mixed and pulverized in a weight ratio of 5:1, and then mixed with chlorinated 1-(2-hydroxyethyl)-3- The methylimidazole solution is uniformly mixed, dissolved at 80°C to form a uniform and stable spinning stock solution, a...

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Abstract

The invention relates to a calamine cellulose fiber, which is characterized in that the formed calamine cellulose fiber is obtained through the following processes: preparing calamine slurry, preparing a spinning solution, preparing a denatured spinning solution and spinning; the weight percentage of the calamine in the finished product calamine cellulose fiber is 5% to 25%; the yarn is dissolvedby adopting ionic liquid so as to increase the dissolubility of the yarn and enhance the production efficiency; a large amount of hydrogen sulfide and carbon disulfide can be avoided from generating in the yellowing process when the traditional viscose process is adopted; the environment pollution is reduced; the damage on the health of operation personnel is lightened; the ionic liquid is adopted to serve as a coagulating bath solution so as to guarantee that the effective components in the calamine are not damaged; the functional index of the finished product fiber is enhanced; the wet-dry strength and the dry extension are obviously enhanced; and the bleaching process in the course of preparing the conventional spinning solution fiber in the postprocessing process is omitted so as to avoid the damage of bleaching substances on the calamine and antibiosis active substances in the calamine.

Description

technical field [0001] The invention relates to a cellulose fiber and a preparation method thereof, in particular to a calamine cellulose fiber and a preparation method thereof. Background technique [0002] Cellulose is a renewable resource that is ubiquitous in nature. It contains a lot of cellulose in trees, cotton, rice stalks, corn and other plants and some bacterial secretions, and has become a viable alternative to petroleum cracking fiber products. recycled resources. The main components of calamine are zinc carbonate, hydrated zinc carbonate, and zinc oxide. It can be used for the treatment of various contact dermatitis and other skin diseases, especially for ulcers, pus dripping, eczema, eczema, and itchy skin. good curative effect. The main components of calamine are zinc carbonate, hydrous zinc carbonate, and zinc oxide. It can be used not only for the treatment of various contact dermatitis and other skin diseases, but also for ulcers, dripping pus, eczema, an...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D5/12D01D1/02D01F2/02D01D1/10D01F2/00D01F1/10D01D5/06
Inventor 逄奉建张志鸿曹其贵刘建华姜明亮王东秦翠梅马峰刚
Owner 潍坊欣龙生物材料有限公司
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