Carboxyl butyronitrile/polyvinyl chloride alloy rubber and plastic particles and preparation method thereof
A carboxylated nitrile and polyvinyl chloride technology, which is applied in the field of carboxylated nitrile/polyvinyl chloride alloy rubber and plastic particles and its preparation, can solve the problems of PVC not expanded, increased energy consumption, dullness, etc., and achieve labor saving and Energy consumption, avoiding physical process, good light perception and hand feeling effect
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[0021] A preparation method of carboxylated nitrile / polyvinyl chloride alloy rubber and plastic particles, comprising the following steps:
[0022] (a) Co-emulsification of polyvinyl chloride paste resin or suspension vinyl resin and dioctyl phthalate;
[0023] (b) adding carboxylated nitrile latex to the emulsified liquid obtained in step (a) for blending;
[0024] (c) Add anti-aging agent and heat stabilizer to the blended liquid obtained in step (b) and mix evenly, heat up to 55-70 degrees, add coagulant, and dehydrate to obtain carboxylated nitrile / polyvinyl chloride co-precipitated rubber powder product;
[0025] (d) Add vulcanizing agent to the co-precipitated rubber product obtained in step (c), pre-vulcanize on a twin-screw extruder at 80-120 degrees, and extrude to granulate.
[0026] In the step (b), the coagulant is any one of the mixtures of industrial salt, alum, magnesium sulfate and sulfuric acid in any ratio.
[0027] The preparation method of the carboxylat...
Embodiment 1
[0042] 30 Kg of polyvinyl chloride resin and 20 Kg of dioctyl phthalate are co-emulsified; 50 Kg of carboxylated nitrile latex is added to the emulsified liquid for blending; anti-aging agent and heat stabilizer are added to the obtained blended liquid to mix Evenly, heat up to 55-70 degrees, add coagulant, dehydrate to obtain carboxylated nitrile / polyvinyl chloride co-precipitated rubber powder product; add vulcanizing agent, pre-vulcanize on twin-screw extruder at 80-120 degrees, extrude and granulate , the properties of the prepared particles were tested, and the results are shown in Table 2.
[0043] Table 2: Performance parameters of co-precipitation glue
[0044] Tensile strength / MPa
Embodiment 2
[0046] 20 Kg of polyvinyl chloride resin and 10 Kg of dioctyl phthalate are co-emulsified; 70 Kg of carboxylated nitrile latex is added to the emulsified liquid for blending; anti-aging agent and heat stabilizer are added to the obtained blended liquid to mix Evenly, heat up to 55-70 degrees, add coagulant, dehydrate to obtain carboxylated nitrile / polyvinyl chloride co-precipitated rubber powder product; add vulcanizing agent, pre-vulcanize on twin-screw extruder at 80-120 degrees, extrude and granulate , the properties of the prepared particles were tested, and the results are shown in Table 3.
[0047] Table 3: Performance parameters of co-precipitation glue
[0048] Tensile strength / MPa
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