Low-alloy heat-resisting cast iron and preparation method thereof

A heat-resistant cast iron and low-alloy technology, applied in the field of heat-resistant metal materials, can solve the problems of large volume and quality of the crucible, unsatisfactory heat-resistant performance, low alloying degree, etc., to achieve difficult cracking and peeling, excellent oxidation resistance , the effect of improving the anti-oxidation performance

Active Publication Date: 2012-02-01
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The alloying degree of this kind of conventional cast iron material is low, but its heat resistance is not ideal. The crucible for smelting non-ferrous metals cast with this kind of cast iron is often gradually thinned due to high temperature oxidation, and then cracks, resulting in The crucible is scrapped, which may even cause production accidents. Through actual production verification, its service life is only about 15 days
The crucibles used in factories generally have large volume and quality, and it takes time and effort to replace them, and production needs to be suspended, which seriously affects the efficiency of production and increases the cost of production

Method used

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  • Low-alloy heat-resisting cast iron and preparation method thereof
  • Low-alloy heat-resisting cast iron and preparation method thereof
  • Low-alloy heat-resisting cast iron and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0081] Embodiment 1: A low-alloyed heat-resistant cast iron material provided by the present invention contains the following chemical components and mass percentages: C: 3.5%; Si: 3.5%; Cr: 1.0%; Mn: 0.4%; P : 0.1%; S: 0.02%; Al: 4.0%; Sr: 0.1%; the balance is Fe. Mix steel scrap, ferrochrome, pig iron, ferrosilicon, pure aluminum, aluminum-strontium master alloy (Al-10Sr master alloy) according to the mass percentage of the chemical composition in the target product, and bake at 150-200°C for 0.5-1.5h to remove The surface water vapor is smelted in a cupola furnace. Among them, the prepared pure aluminum is placed on the bottom of the ladle in advance, and then the molten iron is put into the ladle. After the aluminum block is melted, the block-shaped aluminum-strontium master alloy is added, and then the 75SiFe inoculant with a particle size of 3-10 mm is washed in with the flow. Then quickly and fully stir the ferroalloy liquid in the ladle for about 1 min to make the Al ...

Embodiment 2

[0082] Embodiment 2: A low-alloyed heat-resistant cast iron material provided by the present invention contains the following chemical components and mass percentages: C: 2.7%; Si: 2.9%; Cr: 0.3%; Mn: 0.4; P: 0.1%; S: 0.02%; Al: 3.0%; Sr: 0.075%; the balance is Fe. Mix steel scrap, ferrochrome, pig iron, ferrosilicon, pure aluminum, aluminum-strontium master alloy (Al-10Sr master alloy) according to the mass percentage of the chemical composition in the target product, and bake at 150-200°C for 0.5-1.5h to remove The surface water vapor is smelted in a cupola furnace. Among them, the prepared pure aluminum is placed on the bottom of the ladle in advance, and then the molten iron is put into the ladle. After the aluminum block is melted, the block-shaped aluminum-strontium master alloy is added, and then the 75SiFe inoculant with a particle size of 3-10 mm is washed in with the flow. Then quickly and fully stir the ferroalloy liquid in the ladle for about 1 min to make the Al ...

Embodiment 3

[0083]Embodiment 3: A low-alloyed heat-resistant cast iron material, which contains chemical components and mass percentages: C: 2.5%; Si: 2.5%; Cr: 0.1%; Mn: 0.4%; P: 0.1%; S: 0.02%; Al: 1.8%; Sr: 0.05%; the balance is Fe. Mix steel scrap, ferrochrome, pig iron, ferrosilicon, pure aluminum, aluminum-strontium master alloy (Al-10Sr master alloy) according to the mass percentage of the chemical composition in the target product, and bake at 150-200°C for 0.5-1.5h to remove The surface water vapor is smelted in a cupola furnace. Among them, the prepared pure aluminum is placed on the bottom of the ladle in advance, and then the molten iron is put into the ladle. After the aluminum block is melted, the block-shaped aluminum-strontium master alloy is added, and then the 75SiFe inoculant with a particle size of 3-10 mm is washed in with the flow. Then quickly and fully stir the ferroalloy liquid in the ladle for about 1 min to make the Al and Sr elements diffuse evenly. After sla...

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Abstract

The invention relates to low-alloy heat-resisting cast iron, which comprises the ingredients of 2.5 to 3.5 percent of C, 2.5 to 3.5 percent of Si, 0.1 to 1.0 percent of Cr, less than 1.0 percent of Mn, less than 0.3 percent of P, less than 0.1 percent of S, 1.8 to 4.0 percent of Al, 0.05 to 0.1 percent of Sr and the balance of Fe. The preparation method comprises the steps that: scrap steel, chromium iron, pig iron, silicon iron, pure aluminum and aluminum-strontium intermediate alloy are mixed and smelted according to the mass percentage of the chemical ingredients in the target product, wherein the pure aluminum is placed at the bottom of a casting ladle in advance, after an aluminum block is smelted, the aluminum-strontium intermediate alloy is added, 75SiFe nucleating agents are filled along with flows, and the drossing and the casting are carried out after stirring; in the preparation method, the aluminum content is low, the aluminum-strontium intermediate alloy is matched for carrying out spheroidisation on molten iron; and a protecting film is promoted to be formed on the surface of the cast iron at a high temperature. The low-alloy heat-resisting cast iron has the advantages that the process method is simple, the operation is convenient, the production cost is low, the comprehensive mechanical performance is good, the inoxidizability is high, and the low-alloy heat-resisting cast iron adapts to various application processes requiring repeated heating and cooling, such as crucibles, fire grates and the like for nonferrous metal smelting. The low-alloy heat-resistingcast iron is suitable for industrial production.

Description

technical field [0001] The invention relates to a low-alloy heat-resistant cast iron and a preparation method thereof. It belongs to the technical field of heat-resistant metal materials. technical background [0002] Heat-resistant cast iron refers to cast iron that can be used at high temperatures and whose anti-oxidation or anti-growth performance meets the requirements of use. Because cast iron has excellent casting performance and easy processing performance, cheap price and convenient manufacture, it is widely used in the manufacture of crucibles, glass molds, grate bars, heating furnace accessories, such as furnace bottom plates and heat exchangers for non-ferrous metal smelting. Wait. According to the difference of main components, at present, heat-resistant cast iron is mainly divided into silicon-based heat-resistant cast iron, chromium-based heat-resistant cast iron, aluminum-based heat-resistant cast iron and nickel-based heat-resistant cast iron. [0003] The...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C37/10C22C33/08
Inventor 李慧中曾敏梁霄鹏李立宋阳
Owner CENT SOUTH UNIV
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