Forming method for variable resistance non-volatile memory element and variable resistance non-volatile memory device
A non-volatile storage and resistance change technology, which is applied to the shaping of resistance change type non-volatile memory elements and the fields of resistance change type non-volatile memory devices, can solve the problem of increasing the shaping voltage of resistance change elements and shaping the voltage. deviations, etc.
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[0117] First, for Figure 29 The shown 1T1R type memory cell composed of a variable resistance element shows molding characteristics for the case where Pt (platinum) is used in the upper electrode 100c and the case where Ir (iridium) is used for the upper electrode 100c, And explain its technical problems, wherein the variable resistance element is composed of the first transition metal oxide layer 100b-1 (here, TaO x , 0y , x<y) to form.
[0118] Here, in the sample used in the experiment, the area of the variable resistance layer 100b is 0.25 μm 2 (=0.5μm×0.5μm), having a first transition metal oxide layer 100b-1 (here, TaO x : X=1.54, film thickness: 44.5nm), and the second transition metal oxide layer 100b-2 (here, TaO y : y=2.47, film thickness: 5.5 nm). The NMOS transistor serving as a switching element has a gate width W: 0.44 μm, a gate length L: 0.18 μm, and a gate insulating film thickness Tox: 3.5 nm.
[0119] The second transition metal oxide layer 100b-2 (h...
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