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Method for collecting high-quality coal gas in process of producing reduced iron powder by means of microwave heating

A technology of reducing iron powder and microwave heating, applied in furnaces, furnace types, fluidized bed furnaces, etc., can solve the problems of low reuse value and high CO2 content, and achieve the effect of uniform product quality and short production cycle

Inactive Publication Date: 2014-07-30
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The main feature of this method is that the reduction of iron oxides is indirect reduction, and the CO in the tail gas 2 High content, low reuse value

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] (1) Raw material preparation: powdered iron scale (T Fe ≥71%), charcoal with a volatile content of ≥21%, and coal with a volatile content of ≥21% are crushed to 150 mesh;

[0016] (2) Fabric: Layer the materials prepared in step (1): the bottom layer is coal, which is 10% of the mass of iron-containing raw materials; the middle layer is a mixture of charcoal and iron-containing raw materials, and the amount of charcoal is the mass of iron-containing raw materials 15%; the upper layer is coal, and the amount of coal in this layer is 1% of the mixture mass in the middle layer;

[0017] (3) Heating: Put the material laid out in step (2) into a microwave reactor and heat it to 1000°C and keep it warm for 60 minutes. 83.142%, H 2 10.31%, CH 4 0.991%, CO 2 Accounting for 5.556%. ).

[0018] The resulting reduced charge is cooled, crushed, sieved, wet magnetic separation, and dried to obtain high-quality primary reduced iron powder (T Fe =98.99%).

Embodiment 2

[0020] (1) Raw material preparation: powdered iron scale (T Fe 74%), charcoal with a volatile content of 25%, and coal with a volatile content of 26% are pulverized to 100 mesh;

[0021] (2) Cloth: Layer the materials prepared in step (1): the bottom layer is charcoal, which is 8% of the mass of iron-containing raw materials; the middle layer is a mixture of charcoal and iron-containing raw materials, and the amount of charcoal is the mass of iron-containing raw materials 11%; the upper layer is coal, and the amount of coal in this layer is 2% of the mass of the mixture in the middle layer;

[0022] (3) Heating: Put the material laid out in step (2) into a microwave reactor and heat it to 1100°C, and keep it warm for 40 minutes. 83.637%, H 2 9.722%, CH 4 0.994%, CO 2 Accounting for 5.532%. ).

[0023] The resulting reduced charge is cooled, crushed, sieved, wet magnetic separation, and dried to obtain high-quality primary reduced iron powder (T Fe =98.47%).

Embodiment 3

[0025] (1) Raw material preparation: powdered iron scale (T Fe 74%), charcoal with a volatile content of 25%, and coal with a volatile content of 26% are pulverized to 200 mesh;

[0026] (2) Fabric: Layer the materials prepared in step (1): the bottom layer is coal, which is 5% of the mass of iron-containing raw materials; the middle layer is a mixture of charcoal and iron-containing raw materials, and the amount of charcoal is the mass of iron-containing raw materials 17%; the upper layer is coal, and the amount of coal in this layer is 1.5% of the mass of the mixture in the middle layer;

[0027] (3) Heating: Put the material laid out in step (2) into a microwave reactor and heat it to 1200°C, and keep it warm for 5 minutes. 82.985%, H 2 10.551%, CH 4 Accounted for 0.978%, CO 2 Accounting for 5.479%. ).

[0028] The resulting reduced charge is cooled, crushed, sieved, wet magnetic separation, and dried to obtain high-quality primary reduced iron powder (T Fe =98.94%)....

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Abstract

The invention provides a method for simultaneously collecting high-quality gas during the production of reduced iron powder by microwave heating. The iron-containing raw materials, charcoal and coal are pulverized; ~10%; the middle layer is a mixture of charcoal and iron-containing raw materials, and the amount of charcoal is 11-17% of the mass of the iron-containing raw materials; the upper layer is coal, and the amount of coal in this layer is 1-2% of the mass of the middle layer mixture; The clothed material is placed in a microwave reactor and heated to 1000-1200°C, and kept for 5-60 minutes. During this period, the exhaust gas is collected to obtain high-quality gas. Through the unique bottom cloth and microwave heating, it can produce reduced iron powder and high-quality gas at the same time. The production cycle is short and the product quality is uniform, achieving comprehensive and efficient utilization of resources, and achieving the production goal of zero discharge of waste water, waste gas, and waste residue. The volume fraction of combustible gas in the produced high-quality gas is 91 to 95%, of which CO accounts for 80 to 86% and H2 accounts for 8 to 11%.

Description

technical field [0001] The invention relates to a method for simultaneously collecting high-quality coal gas during microwave heating to produce reduced iron powder, and belongs to the technical fields of microwave metallurgy and coal chemical industry. Background technique [0002] Traditional production of direct reduced iron or gas production in coal chemical plants has a single purpose and low comprehensive utilization of resources. Microwave heating has the advantages of volumetric heating, fast heating speed, instant heat supply / stop, high heating efficiency, no pollution to products and less auxiliary equipment for iron-containing materials; in industrial production, microwave heating plays an important role in drying. The field of low temperature has been widely used (it can be traced back to 1962, US19620225218), and the application research in the field of pyrometallurgy is very extensive, but the microwave pyrometallurgy applied to industrial production is still i...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21B13/00B22F9/20
Inventor 朱红波叶乾旭彭金辉张利波张世敏代林晴陈建普靖忠
Owner KUNMING UNIV OF SCI & TECH