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Back reflector for photovoltaic devices

A technology of back reflection layer and thin film photovoltaic cell is applied in the fields of improved back reflection layer structure, thin film silicon-based photovoltaic device, and reinforced back reflection layer, and can solve the problems of mutual diffusion between silicon layer and aluminum layer.

Inactive Publication Date: 2013-02-13
XUNLIGHT CORPORATION
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, when thin-film silicon material is deposited directly on the aluminum metal layer, interdiffusion between the silicon layer and the aluminum layer may occur

Method used

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  • Back reflector for photovoltaic devices
  • Back reflector for photovoltaic devices
  • Back reflector for photovoltaic devices

Examples

Experimental program
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Effect test

example 1

[0032] A back reflection layer 302 made on a stainless steel (SS) foil substrate 301 has such image 3 The structure shown comprises (i) a 300 nm thick first metal layer 303 with a textured aluminum layer having a randomly textured surface, the layer having a root mean square (RMS) surface roughness R of 240 nm rms , and a maximum peak-to-valley R of 480nm p-v (ii) a first barrier layer 304 of ZnO layer with a thickness of 30nm; (iii) a second metal layer 305 of highly reflective silver layer with a thickness of 50nm formed on the first barrier layer; (iv) a A second TCO barrier layer 306 of ZnO layer with a thickness of 650 nm is formed on the second metal layer. Figure 4 The total reflectance spectrum (curve 4a) and the diffuse reflectance spectrum (curve 4b) of a BR are shown, wherein the BR has the above structure SS / 300nm-Al / 30nm-ZnO / 50nm-Ag. Curve 4a shows a high total reflectance of 80% to 88% in the wavelength range of 500nm to 1000nm, while curve 4b shows a high di...

example 2

[0035] A back reflection layer 302 made on the SS foil substrate 301 has such image 3 The structure shown comprises: (i) a first metal layer 303 with a thickness of 300 nm with a textured aluminum layer having a textured surface with a randomly textured surface identical to the Al-layer in Example 1; (ii) a The first barrier layer 304 of ZnO layer, thickness is 30nm; (iii) the second metal layer 305 of a highly reflective silver layer, thickness is 100nm, and it is formed on the first barrier layer; (iv) the second metal layer 305 of a ZnO layer A TCO barrier layer 306, with a thickness of 650 nm, is formed on the second metal layer. Figure 6 The total reflectance spectrum (curve 6a) and the diffuse reflectance spectrum (curve 6b) of a BR are shown, wherein the BR has the above structure SS / 300nm-Al / 30nm-ZnO / 150nm-Ag. Curve 6a shows a very high total reflectance of 90% to 98% in the wavelength range of 500nm to 1000nm, while curve 6b shows a high diffuse reflectance of 88% ...

example 3

[0037] A back reflection layer 302 made on the SS foil substrate 301 has such image 3 The structure shown comprises: (i) a first metal layer 303 with a thickness of 300 nm with a textured aluminum layer having a textured surface with a randomly textured surface identical to the Al-layer in Example 1; (ii) a The first barrier layer 304 of ZnO layer, thickness is 30nm; (iii) the second metal layer 305 of a highly reflective silver layer, thickness is 200nm, and it is formed on the first barrier layer; (iv) the second metal layer 305 of a ZnO layer A TCO barrier layer 306, with a thickness of 650 nm, is formed on the second metal layer. Figure 7 The total reflectance spectrum (curve 7a) and the diffuse reflectance spectrum (curve 7b) of a BR having the above structure SS / 300nm-Al / 30nm-ZnO / 200nm-Ag are shown. Curve 7a shows an excellent total reflectance of 92% to 98% in the wavelength range of 500nm to 1000nm, while curve 7b shows a very high diffuse reflectance of 92% to 88% ...

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Abstract

This invention relates to an improved back reflector structure of multiple material layers for being used in thin-film photovoltaic devices. The invention provides an enhanced back reflector having a texture, a high reflectivity, a high yield, and a long lifetime stability which can be applied into thin-film silicon based photovoltaic devices. The back reflector structure consists of (i) a first textured metal or alloy layer, such as aluminum (Al), formed on a metal (such as stainless steel) or polymer (such as Kapton) substrate, (ii) a thin oxide or nitride first barrier layer such as zinc oxide (ZnO), formed on the first metal layer, (iii) a second reflective metal or alloy layer, such as silver (Ag), formed on the first barrier layer, (iv) a transparent oxide or nitride second barrier layer, such as zinc oxide, formed on the second metal layer.

Description

[0001] This application claims the benefit of Provisional Patent Application Serial No. 61 / 270,503, filed July 9, 2009. technical field [0002] The invention mainly relates to thin-film photovoltaic devices, in particular to an improved back reflection layer structure for multi-material layers of thin-film photovoltaic devices. More specifically, the present invention provides a reinforced back reflection layer, which has a suede texture and has high reflectivity, high yield and long-life stability, and can be applied to thin-film silicon-based photovoltaic devices. Background technique [0003] In recent years, thin-film photovoltaic devices have been in-depth research and development, which can be achieved by adding layers such as thin-film silicon-based a-Si, a-SiGe, nc-Si or μ-Si, CdS / CdTe and CdS / CulnSe 2 Layers, etc., of so-called thin-film semiconductor solar cell materials are formed on low-cost substrates such as glass, stainless steel, etc. to produce them. Typic...

Claims

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Application Information

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IPC IPC(8): H02N6/00
CPCY02E10/52H01L31/0527H01L31/03762H01L31/075H01L31/02366H01L31/03921Y02E10/548H01L31/206H01L31/056Y02P70/50
Inventor 曹新民
Owner XUNLIGHT CORPORATION
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