The invention provides a laminated
cell and a preparation method thereof, and the laminated
cell comprises a bottom
cell which at least comprises a substrate and a
back reflector structure located at one side of the substrate, the
back reflector structure comprises a first transparent conductive layer, a
barrier layer, a first anti-reflection layer and a first
metal layer, the
barrier layer is located at one side, far away from the substrate, of the first transparent conductive layer, and the first anti-reflection layer is located at the other side of the first transparent conductive layer; the first anti-reflection layer is located on the side, away from the first transparent conductive layer, of the
barrier layer, and the first
metal layer is located on the side, away from the substrate, of the first anti-reflection layer and / or the side, away from the substrate, of the first transparent conductive layer and makes contact with the first transparent conductive layer. The middle layer is located on the side, away from the
back reflector structure, of the substrate; and the
perovskite top cell is positioned on one side, far away from the bottom cell, of the middle layer. The stability of the laminated cell can be improved.