Electrolyte and preparation method thereof
A preparation method and electrolyte technology, applied in the field of electrolyte, can solve problems such as easy pyrolysis, reduced stability of electric double-layer capacitors, unstable acetate radicals, etc.
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Embodiment 1
[0058] The electrolyte solution can be obtained by adding the fluoroalkyl phosphite into the acetate-based ionic liquid and stirring until dissolved.
[0059] In this embodiment, the fluoroalkyl phosphite is tris(2,2,2-trifluoroethyl) phosphite, and the acetate-based ionic liquid is 1-ethyl-3-methylimidazole acetate, The mass ratio of acetate-based ionic liquid to tris(2,2,2-trifluoroethyl)phosphite is 1:0.03.
[0060] In this embodiment, when preparing the electrolyte, it is carried out in a glove box, and tris(2,2,2-trifluoroethyl)phosphite is added to 1-ethyl-3-methylimidazole acetate and stirred for 10 ~60 minutes to dissolve tris(2,2,2-trifluoroethyl)phosphite in 1-ethyl-3-methylimidazole acetate.
[0061] The above electrolytic solution was applied to a double layer capacitor and the stability of the double layer capacitor was measured.
[0062] When testing the stability, use graphene as the electrode material, use the electrolyte prepared in Example 1, assemble it in...
Embodiment 2 18
[0065] In Examples 2 to 18, the fluoroalkyl phosphite is added into the acetate-based ionic liquid, and stirred until dissolved to obtain an electrolyte. When preparing the electrolyte, it was carried out in a glove box.
[0066] In Examples 2 to 18, the ratio of fluoroalkyl phosphite, acetate ionic liquid, acetate ionic liquid to fluoroalkyl phosphite, stirring time, and specific capacitance retention after 1000 cycles See Table 1 for the rate and ratio of specific capacitance retention.
[0067] Electrolyte formula and test data in table 1 embodiment two to eighteen
[0068]
[0069]
[0070]
[0071] In embodiment two to eighteen, the specific capacitance retention ratio measurement condition is identical with embodiment one; The obtained use of the corresponding acetate-based ionic liquid without adding fluoroalkyl phosphite as the percentage of the increase in the specific capacitance retention of the double-layer capacitor as the electrolyte.
[0072] As can ...
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