Amorphous copolyester, soft substrate and optical film
A copolyester and amorphous technology, applied in the field of optical films, can solve the problems of inability to improve physical properties and reduce the excellent characteristics of raw materials
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Embodiment 1
[0077] With 166 grams of terephthalic acid (TPA) as the di-acid monomer, 49.6 grams of ethylene glycol (EG, 50mol%) and 98 grams of tricyclodecane dimethanol (TCD, 50mole%) as the diol monomer, After two-stage esterification and polycondensation, a plastic of amorphous polyester (A=0.5, B=0.5) having 0.5 mole fraction of the repeating unit of formula 1 and 0.5 mole fraction of the repeating unit of formula 2 is synthesized Granules, and the intrinsic viscosity measured by Ubbelohde's viscometer was 0.71.
Embodiment 2
[0079] With 166 grams of terephthalic acid (TPA) as the di-acid monomer, 37.2 grams of ethylene glycol (EG, 30mol%) and 137.2 grams of tricyclodecanedimethanol (TCD, 70mole%) as the diol monomer, After two-stage esterification and polycondensation, a plastic of amorphous polyester (A=0.3, B=0.7) having 0.3 mole fraction of the repeating unit of formula 1 and 0.7 mole fraction of the repeating unit of formula 2 is synthesized Granules, and the intrinsic viscosity measured by Ubbelohde's viscometer was 0.70.
Embodiment 3
[0081] With 166 grams of terephthalic acid (TPA) as the di-acid monomer, 21.7 grams of ethylene glycol (EG, 5mol%) and 186.2 grams of tricyclodecanedimethanol (TCD, 95mole%) as the diol monomer, After two-stage esterification and polycondensation, a plastic of amorphous polyester (A=0.05, B=0.95) having 0.05 mole fraction of the repeating unit of formula 1 and 0.95 mole fraction of the repeating unit of formula 2 is synthesized Granules, and the intrinsic viscosity measured by Ubbelohde's viscometer was 0.68.
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