Physically functional flame-retardant polymer member and chemically functional flame-retardant polymer member
A flame retardant polymer and functional technology, applied in the field of functional flame retardant polymer components, can solve the problems of wrinkling or blistering, surface corrosion, wrinkling, etc., and achieve excellent alkali resistance, excellent acid resistance, excellent The effect of solvent resistance
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[0482] Hereinafter, the present invention is described in more detail by means of examples, but the present invention is not limited to these examples.
[0483] It should be noted that a biaxially stretched polyethylene terephthalate film (trade name: "MRN38", manufactured by Mitsubishi Chemical Polyester Film) having a thickness of 38 μm on which a silicone-based release treatment was performed was used Each cover film and substrate film were used for each of the following examples.
[0484]
[0485] The following flame retardancy of the polymer sheet was evaluated.
[0486] pass figure 2 The evaluation of flame retardancy was carried out in the horizontal burning test shown in. figure 2 The measurement method is shown. Each polymer sheet was cut into a piece having a size of 5 cm x 12 cm, which was then evaluated. Care should be taken to peel off the cover films on both sides of each polymer sheet.
[0487] In each physical functional flame-retardant polymer sheet a...
Synthetic example 1
[0546] (Synthesis Example 1) (Preparation of Slurry (b-1))
[0547] 50 parts by weight of isobornyl acrylate, 50 parts by weight of lauryl acrylate, 0.1 part by weight of a photopolymerization initiator (trade name: "IRGACURE651", manufactured by Ciba Specialty Chemicals Inc.) and 0.1 part by weight of a photopolymerization initiator (trade name : "IRGACURE184", manufactured by Ciba Specialty Chemicals Inc.) was stirred in a four-necked separable flask equipped with a stirrer, a thermometer, a nitrogen gas introduction tube, and a cooling tube until the mixture became homogeneous. Thereafter, bubbling with nitrogen gas was performed for 1 hour to remove dissolved oxygen. Thereafter, UV light was applied from outside the flask by using a black light lamp to perform polymerization. At the point when a moderate viscosity is obtained, the lights are turned off and nitrogen sparging is stopped. Thus, a partially polymerized slurry composition having a polymerization rate of 7% wa...
Synthetic example 2
[0548] (Synthesis Example 2) (Preparation of Slurry (a-1) Containing Layered Inorganic Compound)
[0549] 30 parts by weight of layered clay mineral (trade name: "LUCENTITE SPN", manufactured by Co-op Chemical Co., Ltd., shape: flat plate) was added to 100 parts by weight of cyclohexyl acrylate, 0.2 parts by weight of 1, 6-hexanediol diacrylate, 0.2 parts by weight of a photopolymerization initiator (trade name: "IRGACURE651", manufactured by Ciba Specialty Chemicals Inc.), and 0.2 parts by weight of a photopolymerization initiator (trade name: "IRGACURE184", manufactured by Ciba Specialty Chemicals Inc.), and then the whole was allowed to stand at room temperature (25° C.) for 24 hours. Thus, a monomer mixture (cloudy) to which layered clay minerals have been added is obtained. Thereafter, the layered clay mineral-added monomer mixture was irradiated with ultrasonic waves from an ultrasonic disperser (manufactured by NIPPON SEIKI CO., LTD.) at an irradiation intensity of 500...
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