High-temperature resistant polyvinyl chloride-polycarbonate composite material and preparation method thereof

A technology of polyvinyl chloride and polycarbonate, applied in the field of polymer materials, can solve the problems of reducing degradation, poor stability of PVC, etc., and achieve good mechanical properties and high temperature resistance

Inactive Publication Date: 2013-12-11
WUJIANG YINGLIDA PLASTIC PACKAGING
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the side reactions (dehydrochlorination, oxidation reaction) in the polymerization process, there are head-to-head unsaturated bonds, tertiary carbon atoms with c

Method used

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  • High-temperature resistant polyvinyl chloride-polycarbonate composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Weigh the raw materials with the following weights:

[0025] 160Kg polyvinyl chloride, 20Kg polycarbonate, 5Kg carbon black, 10Kg calcium carbonate, 5Kg zinc acetate, 2Kg zinc stearate, 10Kg paraffin, 5Kg titanate coupling agent, 2,6-di-tert-butyl-4- 5Kg methyl phenol, 10Kg polyvinyl alcohol, 2Kg ethylene glycol monobutyl ether, 4Kg triethanolamine, 3Kg diacetone alcohol, 4Kg maleic anhydride resin, 2Kg amino acetic acid, 4Kg sorbitol, 2Kg tributyl phosphate , carnauba wax 3Kg, trimethylol melamine 6Kg, lead stearate 3Kg.

[0026] The degree of polymerization of the above-mentioned polyvinyl chloride is 1,000.

[0027] The above paraffin has a melting point of 65°C.

[0028] The above-mentioned titanate coupling agent is NDZ-105, which is available from Foshan Qibang Chemical Co., Ltd.

[0029] Preparation:

[0030] S1: Polyvinyl chloride, polycarbonate, carbon black, calcium carbonate, zinc acetate, zinc stearate, paraffin, polyvinyl alcohol, ethylene glycol monob...

Embodiment 2

[0036] Weigh the raw materials with the following weights:

[0037] 200Kg polyvinyl chloride, 40Kg polycarbonate, 10Kg carbon black, 20Kg calcium carbonate, 10Kg zinc acetate, 4Kg zinc stearate, 30Kg paraffin, 10Kg titanate coupling agent, 2,6-di-tert-butyl-4- 10Kg methyl phenol, 20Kg polyvinyl alcohol, 4Kg ethylene glycol monobutyl ether, 8Kg triethanolamine, 6Kg diacetone alcohol, 10Kg maleic anhydride resin, 4Kg amino acetic acid, 10Kg sorbitol, 5Kg tributyl phosphate , carnauba wax 5Kg, trimethylol melamine 10Kg, lead stearate 5Kg.

[0038] The degree of polymerization of the above polyvinyl chloride is 1500.

[0039] The above paraffin has a melting point of 66°C.

[0040] The above-mentioned titanate coupling agent is NDZ-105, which is available from Foshan Qibang Chemical Co., Ltd.

[0041] Preparation:

[0042] S1: Polyvinyl chloride, polycarbonate, carbon black, calcium carbonate, zinc acetate, zinc stearate, paraffin, polyvinyl alcohol, ethylene glycol monobutyl...

Embodiment 3

[0048] Weigh the raw materials with the following weights:

[0049] 180Kg polyvinyl chloride, 30Kg polycarbonate, 7Kg carbon black, 15Kg calcium carbonate, 6Kg zinc acetate, 3Kg zinc stearate, 20Kg paraffin, 7Kg titanate coupling agent, 2,6-di-tert-butyl-4- 7Kg of methyl phenol, 15Kg of polyvinyl alcohol, 3Kg of ethylene glycol monobutyl ether, 7Kg of triethanolamine, 4Kg of diacetone alcohol, 7Kg of maleic anhydride resin, 3Kg of amino acetic acid, 8Kg of sorbitol, and 3Kg of tributyl phosphate , carnauba wax 4Kg, trimethylol melamine 8Kg, lead stearate 4Kg.

[0050] The degree of polymerization of the above polyvinyl chloride is 1200.

[0051] The above paraffin has a melting point of 65°C.

[0052] The above-mentioned titanate coupling agent is NDZ-105, which is available from Foshan Qibang Chemical Co., Ltd.

[0053] Preparation:

[0054] S1: Polyvinyl chloride, polycarbonate, carbon black, calcium carbonate, zinc acetate, zinc stearate, paraffin, polyvinyl alcohol, e...

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Abstract

The invention provides a polymer composite material, particularly relates to a polyvinyl chloride-polycarbonate composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The polyvinyl chloride-polycarbonate composite material comprises the following components in parts by weight: polyvinyl chloride, polycarbonate, carbon black, calcium carbonate, zinc acetate, zinc stearate, paraffin, titanate coupling agent, 2,6-di-tert-butyl-4-methylphenol, polyvinyl alcohol, ethylene glycol monobutyl ether, triethanolamine, diacetone alcohol, maleic anhydride resin, aminoacetic acid, sorbitol, tributyl phosphate ester, carnauba wax, trimethylol melamine and lead stearate. The polyvinyl chloride-polycarbonate composite material has the advantages that the mechanical property and the high-temperature-resistant property are good, the tensile strength is larger than 15 MPa, the breakage elongation is larger than 200%, and the vicat softening temperature is higher than 100 DEG C.

Description

[0001] technical field [0002] The invention provides a polymer composite material, in particular relates to a polyvinyl chloride-polycarbonate composite material and a preparation method thereof, belonging to the technical field of polymer materials. [0003] Background technique [0004] At present, the annual production capacity of PVC pipes in my country is more than 2 million tons. Despite fierce competition with other polymers, PVC still dominates the global plastic pipe market. The advantage is obtained through continuous improvement and development of the processing process of PVC pipes, including the production of PVC resin and the application of innovative technologies for PVC pipes, especially the innovation of PVC pipe processing technology and technology, which has obviously improved the economy of PVC pipes and opened up new fields of application. [0005] The chemical structure of polyvinyl chloride is [CH 2 -CHCl 〕n, its main chain is connected by C-C, l...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L69/00C08K13/02C08K3/04C08K3/26C08K5/098
Inventor 倪迪
Owner WUJIANG YINGLIDA PLASTIC PACKAGING
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