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Method for preparing lithium battery negative electrode material, and lithium battery negative electrode sheet

A negative electrode material, lithium battery technology, applied in the direction of battery electrodes, electrode collector coatings, negative electrodes, etc., can solve the problems of large irreversible capacity loss, high initial charge and discharge efficiency, low specific capacity, etc., and achieve cycle stability Improvement, specific capacity improvement, and the effect of high specific capacity

Active Publication Date: 2014-06-04
DONGGUAN KAIJIN NEW ENERGY TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The primary purpose of the present invention is to provide a preparation method of lithium battery negative electrode material, the first efficiency of this artificial graphite negative electrode material is as high as 93% and the first specific capacity reaches 355mAh / g, its first charge and discharge efficiency is high, the specific capacity is high, and it solves the problem of man-made Graphite materials have the problems of large irreversible capacity loss and low specific capacity in the actual preparation of lithium battery negative electrodes.

Method used

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  • Method for preparing lithium battery negative electrode material, and lithium battery negative electrode sheet
  • Method for preparing lithium battery negative electrode material, and lithium battery negative electrode sheet
  • Method for preparing lithium battery negative electrode material, and lithium battery negative electrode sheet

Examples

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Effect test

Embodiment 1

[0031] (1) Preparation of artificial graphite anode materials for lithium batteries:

[0032] (1) The petroleum coke is mechanically crushed, and then the powder is mechanically ball-milled to obtain fine powder, and the fine powder is classified;

[0033] (2) Mix the classified fine powder with an appropriate amount (5%) of asphalt powder, and then put the evenly mixed powder into a medium-temperature reactor for reaction (the temperature in the reactor is 500℃, and the stirring speed in the reactor is 40r / min, the reaction time is 8h), and finally the material is discharged.

[0034] (3) Pass the discharged powder through the shaping classifier again for shaping and classifying treatment;

[0035] (4) The product obtained above is subjected to high temperature graphitization treatment (at 2500°C for 36 hours), and then subjected to classification treatment to obtain artificial graphite material A (D 50 =10um).

[0036] (5) Add the A prepared in step 1 to a beaker containing ...

Embodiment 2

[0044] (1) Preparation of anode materials for lithium batteries:

[0045] (1) The petroleum coke is mechanically crushed, and then the powder is mechanically ball-milled to obtain fine powder, and the fine powder is classified;

[0046] (2) Mix the classified fine powder with an appropriate amount (5%) of asphalt powder, and then put the evenly mixed powder into the medium temperature reactor for reaction (the temperature in the reactor is 500°C, and the stirring speed in the kettle is 40r / min, the reaction time is 8h), and finally the material is discharged.

[0047] (3) Pass the discharged powder through the shaping classifier again for shaping and classifying treatment;

[0048] (4) The product obtained above is subjected to high temperature graphitization treatment (at 2500°C for 36 hours), and then subjected to classification treatment to obtain artificial graphite material A (D 50 =10um).

[0049] (5) Add the A prepared in step 1 to a beaker containing a certain amount o...

Embodiment 3

[0056] (1) Preparation of anode materials for lithium batteries:

[0057] (1) The petroleum coke is mechanically crushed, and then the powder is mechanically ball-milled to obtain fine powder, and the fine powder is classified;

[0058] (2) Mix the classified fine powder with an appropriate amount (5%) of asphalt powder, and then put the evenly mixed powder into the medium temperature reactor for reaction (the temperature in the reactor is 500°C, and the stirring speed in the kettle is 40r / min, the reaction time is 8h), and finally the material is discharged.

[0059] (3) Pass the discharged powder through the shaping classifier again for shaping and classifying treatment;

[0060] (4) The product obtained above is subjected to high temperature graphitization treatment (at 2500°C for 36 hours), and then subjected to classification treatment to obtain artificial graphite material A (D 50 =10um).

[0061] (5) Add the A prepared in step 1 to a beaker containing a certain amount o...

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Abstract

The invention discloses a method for preparing a lithium battery negative electrode material, and a lithium battery negative electrode sheet. The method comprises the steps of subjecting raw materials to mechanical smashing and grading treatment, mixing the raw materials with asphalt powder, reacting for 6-10 h in a middle temperature reaction kettle at a temperature of 500-650 DEG C; carrying out shaping and grading treatment again; then carrying out high temperature graphitization treatment and finally obtaining modified artificial graphite material after the grading treatment; further dissolving the modified artificial graphite material and the asphalt in a dispersant; stirring to obtain a uniformly mixed solution; passing the uniformly mixed solution to a closed cycle drier to prepare composite powder; heating for 1-5 h at a temperature of 700-1,100 DEG C; and finally obtaining an asphalt liquid phase coated modified artificial graphite material. The asphalt liquid phase coated modified artificial graphite material prepared by the method exhibits excellent electrochemical performances such as high initial charge and discharge efficiency, high specific capacity and good cycle performance, after being applied in lithium battery.

Description

technical field [0001] The invention relates to the field of preparation of lithium battery electrode materials, in particular to a method for preparing lithium battery negative electrode materials by asphalt liquid phase coating. Background technique [0002] Compared with other secondary batteries, lithium batteries have the advantages of high working voltage, high energy density, stable discharge voltage, long cycle life, and environmental friendliness. They have been widely used in portable electronic products and power tools, and are expected to become the future hybrid One of the main energy supplies for power vehicles and pure power vehicles. Anode materials are one of the key factors to evaluate the overall performance of lithium batteries. At present, the anode materials for lithium batteries commercially used are mainly carbon materials, including easily graphitizable carbon, difficult graphitizable carbon and graphite. Graphite material has good electrical condu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/583H01M4/62H01M4/1393
CPCY02E60/122H01M4/0404H01M4/133H01M4/1393H01M4/366H01M4/583H01M10/0525H01M2004/027Y02E60/10
Inventor 晏荦李敏
Owner DONGGUAN KAIJIN NEW ENERGY TECH