The invention discloses a preparation method of a coated
graphite negative
electrode material. The preparation method comprises the steps of mixing, granulating and
coating, graphitizing and the like. Pelleting and
coating are carried out before the graphitization process, unstable components in
asphalt are decomposed and release small molecules in the
asphalt in the hot
atmosphere of
oxygen, oxidative
dehydrogenation is carried out at the same time,
oxygen molecules in the
oxygen and
asphalt molecules are crosslinked to form stable macromolecules in a mode of forming C = O bonds and C-O-C bonds, the asphalt molecules are difficult to graphitize, and the graphitization performance of the asphalt is improved. An ordered structure is not easy to form in the graphitization process, the hard carbon characteristic is achieved, a
coating layer formed after coating is of a two-layer structure, the coating layer is composed of a hard carbon outer layer and a hard carbon-
graphite transition phase, the
binding force between a
graphite inner core and the hard
carbon coating layer can be improved due to the existence of the hard carbon-graphite transition phase, the hard carbon-
graphite composite material is more suitable for high-rate charging and discharging, and meanwhile, the hard carbon-
graphite composite material has a good application prospect. And coating and
carbonization are not needed after graphitization, so that the preparation time is shortened, the preparation efficiency is improved, the preparation
energy consumption is greatly reduced, and the preparation cost is effectively reduced.