Photoelectrode for a dye-sensitized solar cell, method for manufacturing the photoelectrode, and dye-sensitized solar cell using the photoelectrode

A solar cell and dye-sensitized technology, applied in the field of photoelectrode for dye-sensitized solar cell and its manufacture, and the field of dye-sensitized solar cell using the photoelectrode, which can solve the problem of structural damage of photosensitive material and easy generation of cracks , Electrode peeling and other problems, to achieve excellent durability, enhance adhesion, and maintain the effect of electrical characteristics

Inactive Publication Date: 2014-07-09
KOREA INST OF SCI & TECH
View PDF4 Cites 13 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, semiconductor electrodes (i.e., photoelectrodes) conventionally used in dye-sensitized solar cells have the following problems due to external stimuli (ultraviolet rays, chemical, heat, shock): structural destruction of photosensitive substances (ultraviolet rays, heat); The connection between the photosensitive substance and the metal nano-oxide is disconnected (chemical); or due to the structural characteristics of the interconnection between metal oxides, cracks are easily generated when subjected to external force (shock)
In addition, conventional photoelectrodes have many problems such as delamination of the electrodes from the substrate.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Photoelectrode for a dye-sensitized solar cell, method for manufacturing the photoelectrode, and dye-sensitized solar cell using the photoelectrode
  • Photoelectrode for a dye-sensitized solar cell, method for manufacturing the photoelectrode, and dye-sensitized solar cell using the photoelectrode
  • Photoelectrode for a dye-sensitized solar cell, method for manufacturing the photoelectrode, and dye-sensitized solar cell using the photoelectrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0127] (manufacturing of photoelectrodes)

[0128] Prepare a conductive glass substrate (Philkington company, material: conductive glass (FTO), thickness 2.2cm, 8Ω / sq, image 3 including substrates 101 and 102).

[0129] After that, metal oxide nanoparticles containing 18.5 wt% of titanium oxide nanoparticles (average particle size: 20nm), 0.05 wt% of binder polymer (ethyl cellulose) and the balance of solvent (Terpineol) After the slurry was coated on the glass substrate (using doctor blade coating method), the substrate was heat-treated at a temperature of 500° C. for 30 minutes, thereby forming a porous film including metal oxide nanoparticles ( Thickness: 10 μm). Next, the composite electrode was impregnated with 0.5 mM ruthenium (Ru) photosensitive dye N719 (bis(tetrabutylammonium)-cis-(dithiocyano-N,N'-bis(4-carboxylic acid) Base-4'-carboxylic acid-2,2'-bipyridine)ruthenium(II), bis(tetrabutylammonium)-cis-(dithiocyanato-N,N'-bis(4-carboxylato-4'-carboxylic acid-2, 2...

Embodiment 2

[0136] (manufacturing of photoelectrodes)

[0137] Prepare a conductive glass substrate (Philkington company, material FTO, thickness 2.2cm, 8Ω / sq, image 3 including substrates 101 and 102).

[0138] After that, metal oxide nanoparticles containing 18.5 wt% of titanium oxide nanoparticles (average particle size: 20nm), 0.05 wt% of binder polymer (ethyl cellulose) and the balance of solvent (Terpineol) After the slurry was coated on the glass substrate (by the doctor blade method), the substrate was subjected to heat treatment at a temperature of 500° C. for 30 minutes, thereby forming a porous film (thickness: 10 μm) including metal oxide nanoparticles . Next, the composite electrode was impregnated with 0.5 mM ruthenium (Ru) photosensitive dye N719 (bis(tetrabutylammonium)-cis-(dithiocyano-N,N'-bis(4-carboxylic acid) Base-4'-carboxylic acid-2,2'-bipyridine)ruthenium(II), bis(tetrabutylammonium)-cis-(dithiocyanato-N,N'-bis(4-carboxylato-4'-carboxylic acid-2, 2'-bipyridine...

Embodiment 3

[0145] (manufacturing of photoelectrodes)

[0146] Prepare a conductive glass substrate (Philkington company, material FTO, thickness 2.2cm, 8Ω / sq, image 3 including substrates 101 and 102).

[0147] After that, metal oxide nanoparticles containing 18.5 wt% of titanium oxide nanoparticles (average particle size: 20nm), 0.05 wt% of binder polymer (ethyl cellulose) and the balance of solvent (Terpineol) After the slurry was coated on the glass substrate (by the doctor blade method), the substrate was heat-treated at a temperature of 500° C. for 30 minutes, thereby forming a porous film (thickness: 10 μm) including metal oxide nanoparticles . Next, the composite electrode was impregnated with 0.5 mM ruthenium (Ru) photosensitive dye N719 (bis(tetrabutylammonium)-cis-(dithiocyano-N,N'-bis(4-carboxylic acid) Base-4'-carboxylic acid-2,2'-bipyridine)ruthenium(II), bis(tetrabutylammonium)-cis-(dithiocyanato-N,N'-bis(4-carboxylato-4'-carboxylic acid-2, 2'-bipyridine) ruthenium (II...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
diameteraaaaaaaaaa
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to view more

Abstract

The present invention relates to a photoelectrode for a dye-sensitized solar cell, to a method for manufacturing the photoelectrode, and to a dye-sensitized solar cell using the photoelectrode. More particularly, provided are a photoelectrode for a dye-sensitized solar cell and a method for manufacturing the photoelectrode, wherein the photoelectrode comprises a porous film (a nanoparticle metal oxide layer), which is formed on a conductive substrate and consists of a nanoparticle metal oxide-photosensitive material-polymer layer, thus achieving superior durability against external stimulation, superior mechanical strength, and superior electrical characteristics.

Description

technical field [0001] The present invention relates to a photoelectrode for a dye-sensitized solar cell and a manufacturing method thereof, a dye-sensitized solar cell using the photoelectrode, and in more detail to a photoelectrode for external stimuli (ultraviolet rays, chemical, heat and impact) has excellent durability and mechanical strength, and is also very excellent in electrical characteristics, including a porous film composed of metal oxide nanoparticles-photosensitive material-polymer and a photoelectrode for a dye-sensitized solar cell and its production method and a dye-sensitized solar cell using the method. Background technique [0002] A typical dye-sensitized solar cell (dye-sensitized solar cell) is a photoelectrochemical solar cell published by Gratzel in Switzerland in 1991. Dye-sensitized solar cells are generally composed of photosensitive dyes that absorb visible light, Metal oxide nanoparticles having wide bandgap energy, a counter electrode (count...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/20
CPCB82Y30/00H01G9/2031H01G9/2095Y02E10/542Y02P70/50H01L31/0224H01L31/04H01L31/18
Inventor 高敏宰李都权金奉帅金弘坤崔仁硕刘基天李真娥金庆坤
Owner KOREA INST OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap