A method for reducing sizing amount of melamine-modified urea-formaldehyde resin wood adhesive
A wood adhesive, melamine technology, applied in the direction of adhesives, aldehyde/ketone condensation polymer adhesives, adhesive types, etc., can solve the problems of difficult large-scale industrial application, large investment, and rising adhesive costs. , to achieve the effect of simple method, guaranteed physical and mechanical properties, and cost saving
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Embodiment 1
[0012] The melamine-modified urea-formaldehyde resin was prepared by alkali-acid-alkali process, the final molar ratio of formaldehyde to urea was 1.1, the content of melamine was 6% (by weight), and the viscosity was 68 mPa. s, add 0.3 times the water of the glue solution at the completion of the glue making stage, stir at high speed for 0.5 hours, adjust the glue, apply the glue to the surface of the shavings with a suitable moisture content, the glue amount is 9%, pave and enter the press Hot pressed into particleboard. 11mm thick and 750 kg / m density 3 The properties are: elastic modulus 2000MPa, static bending strength 16 MPa, internal bonding strength 0.50 MPa, formaldehyde emission 7.1mg / 100g. Compared with the performance of the particleboard prepared by undiluted glue, the amount of glue applied is reduced by 16%, the elastic modulus is increased by 20%, the static bending strength is 30%, and the internal bond strength is increased by 8%.
Embodiment 2
[0014] The melamine-modified urea-formaldehyde resin was prepared by alkali-acid-alkali process, the final molar ratio of formaldehyde to urea was 1.2, the content of melamine was 7% (by weight), and the viscosity was 76 mPa. s, add 0.8 times the water of the glue solution at the completion of the glue making stage, stir at high speed for 0.5 hours, adjust the glue, apply the glue to the surface of the shavings with a suitable moisture content, the glue amount is 10%, pave and enter the press Hot pressed into particleboard. 16mm thick and 750 kg / m density 3 The properties are: elastic modulus 1800MPa, static bending strength 14 MPa, internal bonding strength 0.40 MPa, formaldehyde emission 6.3 mg / 100g. Compared with the performance of particleboard prepared with undiluted glue, the amount of glue applied is reduced by 18%, the elastic modulus is increased by 5%, the static bending strength is 10%, and the internal bond strength is increased by 5%.
Embodiment 3
[0016] The melamine-modified urea-formaldehyde resin was prepared by alkali-acid-alkali process, the final molar ratio of formaldehyde and urea was 1.05, the content of melamine was 8% (by weight), and the viscosity was 85 mPa. s, add 0.5 times the water of the glue solution at the completion of the glue making stage, stir at high speed for 0.5 hours, adjust the glue, apply the glue to the surface of the shavings with a suitable moisture content, the glue amount is 9%, pave and enter the press Hot pressed into particleboard. 11mm thick and 750 kg / m density 3 The properties are: elastic modulus 1900 MPa, static bending strength 15 MPa, internal bond strength 0.43 MPa, formaldehyde emission 5.6 mg / 100g. Compared with the performance of the particleboard prepared by undiluted glue, the amount of glue applied was reduced by 14%, the elastic modulus was increased by 18%, the static bending strength was 15%, and the internal bonding strength was increased by 10%.
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