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Degradable PP-EVOH high-barrier composite thin film

A technology of PP-EVOH and composite film, which is applied in the direction of synthetic resin layered products, chemical instruments and methods, layered products, etc., and can solve problems such as environmental load and no related reports.

Active Publication Date: 2015-02-25
J&A IND (SUZHOU) CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, some traditional methods for dealing with composite film waste, such as incineration, landfill, recycling, etc., have defects, and have certain limitations that bring serious load to the environment. Therefore, the development of biodegradable composite films that reduce environmental pollution is a solution to the environment. important way of pollution
[0004] As far as the applicant knows, the biodegradation technology and application technology of the composite film with the same degradation rate is still a blank, and there are no relevant reports at home and abroad.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Embodiment one: (the example of the first technical solution)

[0057] A kind of degradable PP-EVOH high barrier composite film, the structure of this composite film is as follows:

[0058] PP / PP-TIE / PA / EVOH / PA / PE-TIE / PE formula (1)

[0059] In formula (1), the meanings expressed from left to right are:

[0060] PP means the outer layer, its function is a protective layer or a display layer, its material is polypropylene, and its monomer molecular formula is -[CH 2 -CH(CH 3 )] n -, polypropylene does not contain hydrophilic groups;

[0061] PP-TIE means the first adhesive layer, and its material is a polypropylene copolymer grafted with maleic anhydride, which is formed by mixing 95% by weight of polypropylene and 5% by weight of maleic anhydride, and its monomer molecular formula is -[CH 2 -CH(CH 3 )] n -[C 4 h 2 o 3 ] m , the hydrophilic group contained in the polypropylene copolymer grafted with maleic anhydride is acid anhydride—OC-O-CO—;

[0062] PA / EVO...

Embodiment 2

[0318] Embodiment two: (an example of the second technical solution)

[0319] A kind of degradable PP-EVOH high barrier composite film, the structure of this composite film is as follows:

[0320] PP / PP-TIE / EVOH / PE-TIE / PE formula (2)

[0321] In formula (2), the meanings expressed from left to right are:

[0322] PP means the outer layer, its function is a protective layer or a display layer, its material is polypropylene, and its monomer molecular formula is -[CH 2 -CH(CH 3 )] n -, polypropylene does not contain hydrophilic groups;

[0323] PP-TIE means the first adhesive layer, and its material is a polypropylene copolymer grafted with maleic anhydride, which is formed by mixing 95% by weight of polypropylene and 5% by weight of maleic anhydride, and its monomer molecular formula is -[CH 2 -CH(CH 3 )] n -[C 4 h 2 o 3 ] m , the hydrophilic group contained in the polypropylene copolymer grafted with maleic anhydride is acid anhydride—OC-O-CO—;

[0324] EVOH means ...

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Abstract

The invention discloses a degradable PP-EVOH high-barrier composite thin film. The composite thin film is characterized in that biodegradability of materials in the composite thin film tends to be uniform by introducing a biologic base, adding amount of adding-type master batch in each material is controlled within a range of being 0.3-15% of total mass of the corresponding material; hydrophilic activity of hydrophilic group in the adding-type master batch should be larger than or equal to that of hydrophilic group in each material. By adding the adding-type master batch, mole ratio of the hydrophilic group and carbon atom of each material tends to be uniform, in other words, bioactivity tends to be uniform, so that degrading rate of each layer of the composite thin film tends to be uniform. By balancing the mole ratio of the hydrophilic group and the carbon atom in each layer, bioactivity and biodegradability which tend to be uniform are acquired, and appearance, function and physical and mechanical performance of the composite thin film remain unchanged.

Description

technical field [0001] The invention relates to the technical field of multilayer composite films, in particular to a biodegradable PP-EVOH high barrier composite film. Background technique [0002] Multi-layer co-extruded composite film refers to a film compounded by a variety of different polymers by co-extrusion blow molding, co-extrusion casting or co-extrusion stretching. As a plastic packaging material, this film is widely used in food, processed meat products, daily necessities, cosmetics, chemical products, pesticides, military products, etc. Packaging function, with various barrier properties such as high moisture resistance, oxygen resistance, oil resistance, and fragrance retention in various environments. [0003] With the use of a large number of composite films in various fields, the pollution of composite films to the environment is increasing day by day. Because it is difficult to degrade, the pollution caused by the composite film has become a worldwide pu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/08B32B27/18B32B27/32B32B27/34B32B27/30B32B7/12
CPCB32B7/12B32B27/08B32B27/18B32B27/30B32B27/32B32B27/34B32B2323/04B32B2323/10B32B2377/00
Inventor 高学文夏嘉良俞晓琴夏瑜唐敏艳
Owner J&A IND (SUZHOU) CO LTD