feal3 (po4) 4‑sds flame retardant and its composite flame retardant material and preparation method
A composite flame retardant and flame retardant technology, applied in the field of composite flame retardant materials and preparation, FeAl34-SDS flame retardant, can solve the problems of large amount of metal hydroxide addition, complicated synthesis process, hindering lifesaving and escape, etc. Achieve the effect of good mechanical and mechanical properties and simple preparation process
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Embodiment 1
[0031] FeAl 3 (PO 4 ) 4 - Preparation of SDS flame retardant
[0032] Weigh Fe(NO 3 ) 3 9H 2 O and Al(NO 3 ) 3 9H 2 O in a ceramic mortar, grind for 15min, grind and mix the two reagents, add SDS (the amount is 20% of the total molar amount of metal ions), grind for 30min, let stand for 1h, add (NH 4 )H 2 PO 4 (n P2O5 =n Fe3+ +n Al3+ ), grind for 30min, let stand for reaction for 1h, transfer the reacted solid to a beaker, put it in an oven and dry it at 60°C for 3h, grind it, then put it in an oven at 80°C for 2h, grind it, put it in a vacuum oven for 110 ℃ reaction 5h. Prepare FeAl 3 (PO 4 ) 4 -SDS flame retardant.
[0033] Contains FeAl 3 (PO 4 ) 4- Preparation of SDS flame retardant composite flame retardant material:
[0034] According to a certain proportion, polyethylene (PE), FeAl 3 (PO 4 ) 4 -SDS and PE-g-MAH (calculated according to the amount of substance, polyethylene: PE-g-MAH: flame retardant is 90: 5: 5) carry out melt intercalation on t...
Embodiment 2
[0036] FeAl 3 (PO 4 ) 4 - Preparation of SDS flame retardant
[0037] Weigh Fe(NO 3 ) 3 9H 2 O and Al(NO 3 ) 3 9H 2 O was ground in a ceramic mortar for 10 min, and the two reagents were ground and mixed evenly, and SDS was added (the amount was 15% of the total molar amount of metal ions), ground for 25 min, left to stand for 0.5 h, and (NH 4 )H 2 PO 4 (n P2O5 =n Fe3+ +n Al3+ ), grind for 25min, let it stand for 0.5h, transfer the reacted solid to a beaker, put it in an oven and bake it at 50°C for 2h, grind it, then put it in an oven and bake it at 70°C for 1h, grind it, and put it in a vacuum drying oven Reaction at 100°C for 4h. Prepare FeAl 3 (PO 4 ) 4 -SDS flame retardant.
[0038] Contains FeAl 3 (PO 4 ) 4 - Preparation of SDS flame retardant composite flame retardant material:
[0039] According to a certain proportion, PP, FeAl 3 (PO 4 ) 4 -SDS and PE-g-MAH (calculated according to the amount of substances, PP: PE-g-MAH: flame retardant is 90:...
Embodiment 3
[0041] FeAl 3 (PO 4 ) 4 - Preparation of SDS flame retardant
[0042] Weigh Fe(NO 3 ) 3 9H 2 O and Al(NO 3 ) 3 9H 2 O in a ceramic mortar, grind for 20min, grind and mix the two reagents, add SDS (the amount is 30% of the total molar amount of metal ions), grind for 40min, let stand for 1.5h, add (NH 4 )H 2 PO 4 (n P2O5 =n Fe3+ +n Al3+ ), grind for 40min, let it stand for 1.5h, transfer the reacted solid to a beaker, put it in an oven and dry it at 70°C for 4h, grind it, then put it in an oven and bake it at 90°C for 3h, grind it, and put it in a vacuum oven Reaction at 120°C for 6h. Prepare FeAl 3 (PO 4 ) 4 -SDS flame retardant.
[0043] Contains FeAl 3 (PO 4 ) 4 - Preparation of SDS flame retardant composite flame retardant material:
[0044] According to a certain proportion, PS, FeAl 3 (PO 4 ) 4 -SDS and PE-g-MAH (calculated according to the amount of substance, PS: PE-g-MAH: flame retardant is 90:5:5) are melt intercalated on a twin-screw extruder...
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